Home

Citation: LI Hui-Hua, GE You, ZHU Hong-Li, FENG Xiao-Miao, LIU Yu-Ge. Preparation by Electro-Deposition Method and Application in Flexible All-Solid-State Supercapacitors of Poly(3, 4-ethylenedioxythiophene) Microtubes[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1799-1807. doi: 10.11862/CJIC.2018.231 shu

Preparation by Electro-Deposition Method and Application in Flexible All-Solid-State Supercapacitors of Poly(3, 4-ethylenedioxythiophene) Microtubes

LI Hui-Hua ¹ ,
GE You ¹ ,
ZHU Hong-Li ¹ ,
FENG Xiao-Miao ^1,, ,
LIU Yu-Ge ^2,,

1.
Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials(IAM); Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM); Nanjing University of Posts & Telecommunications, Nanjing 210023, China
2.
School of Chemistry and Chemical Engineering, Lingnan Normal University, Zhanjiang, Guangdong 524000, China

Corresponding author: FENG Xiao-Miao, iamxmfeng@njupt.edu.cn LIU Yu-Ge, liuyugehb@126.com
Received Date: 16 April 2018
Revised Date: 14 July 2018

Figures(8)

Poly(3, 4-ethylenedioxythiophene) (PEDOT) microtube electrodes doped with different acids and surfactants were obtained by one-step electrochemical deposition method and could be used for flexible and all-solid-state supercapacitors (SCs). We also investigated the effect of deposition time on the capacitance performance of PEDOT microtubes doped with the same acid medium and surfactant. The structures of the final product were characterized by different characterization techniques including scanning electron microscopy (SEM) and FT-IR spectra. The electrochemical results showed that the capacitance of PEDOT microtubes doped with sulfuric acid (H₂SO₄) and sodium dodecyl sulfate (SDS) could be improved significantly. The areal capacitance of the prepared supercapacitor with deposition time of 600 s could achieve to 113.5 mF·cm^-2 at the scan rate of 10 mV·s^-1. The areal capacitances under the different bending angles remained at 93% of initial capacitive value revealing that the supercapacitor had highly mechanical stability. In addition, it remained 95.5% of the initial capacitive value after 2 000 cycles at a current density of 0.6 mA·cm^-2 showing its superior cycling stability. The prepared flexible all-solid-state supercapacitor can power a light-emitting-diode (LED) which meets the practical applications of micro-power supplies.
- electro-deposition,
- solid-state,
- flexible,
- supercapacitor
1. [1]
  Aricò A S, Bruce P, Scrosati B, et al. Nat. Mater., 2005, 4(5):366-377 doi: 10.1038/nmat1368
2. [2]
  Lu Q Q, Wang X Y, Cao J, et al. Energy Storage Mater., 2017, 8:77-84 doi: 10.1016/j.ensm.2017.05.001
3. [3]
  Simon P, Gogotsi Y. Nat. Mater., 2008, 7(11):845-854 doi: 10.1038/nmat2297
4. [4]
  Miller J R, Simon P. Science, 2008, 321(5889):651-652 doi: 10.1126/science.1158736
5. [5]
  Pushparaj V L, Shaijumon M M, Kumar A, et al. Proc. Natl.Acad. Sci., 2007, 104(34):13574-13577 doi: 10.1073/pnas.0706508104
6. [6]
  Shi S, Xu C J, Yang C, et al. Sci. Rep., 2013, 3:2598-2604 doi: 10.1038/srep02598
7. [7]
  Chen T, Dai L M. J. Mater. Chem. A, 2014, 2(28):10756-10775 doi: 10.1039/c4ta00567h
8. [8]
  D′Arcy J M, El-Kady M F, Khine P P, et al. ACS Nano, 2014, 8(2):1500-1510 doi: 10.1021/nn405595r
9. [9]
  Österholm A M, Shen D E, Dyer A L, et al. ACS Appl. Mater.Interfaces, 2013, 5(24):13432-13440 doi: 10.1021/am4043454
10. [10]
  Pandey G, Rastogi A, Westgate C R. J. Power Sources, 2014, 245:857-865 doi: 10.1016/j.jpowsour.2013.07.017
11. [11]
  Hsu Y K, Chen Y C, Lin Y G, et al. J. Power Sources, 2013, 242:718-724 doi: 10.1016/j.jpowsour.2013.05.153
12. [12]
  Tsakova V, Winkels S, Schultze J. Electrochim. Acta, 2001, 46(5):759-768 doi: 10.1016/S0013-4686(00)00643-5
13. [13]
  Patra S, Munichandraiah N. J. Appl. Polym. Sci., 2007, 106(2):1160-1171 doi: 10.1002/(ISSN)1097-4628
14. [14]
  Li W K, Chen J, Zhao J J, et al. Mater. Lett., 2005, 59:800-803 doi: 10.1016/j.matlet.2004.11.024
15. [15]
  Anothumakkool B, Bhange S N, Badiger M V, et al.Nanoscale, 2014, 6(11):5944-5952 doi: 10.1039/c4nr00659c
16. [16]
  Wang Z L, He X J, Ye S H, et al. ACS Appl. Mater.Interfaces, 2014, 6(1):642-647 doi: 10.1021/am404751k
17. [17]
  Selvaganesh S V, Mathiyarasu J, Phani K L N, et al.Nanoscale Res. Lett., 2007, 2(11):546-549 doi: 10.1007/s11671-007-9100-6
18. [18]
  Xu H H, Hu X L, Sun Y M, et al. Nano Res., 2014, 8(4):1148-1158
19. [19]
  Chen Y Q, Zhang X N, Xie Z P. ACS Nano, 2015, 9(8):8054-8063 doi: 10.1021/acsnano.5b01784
20. [20]
  Chen S, Zhu J W, Wang X. ACS Nano, 2010, 4(10):6212-6218 doi: 10.1021/nn101857y
21. [21]
  Wu L X, Li R Z, Guo J L, et al. AIP Adv., 2013, 3(8):082129-082133 doi: 10.1063/1.4820353
22. [22]
  Chen W, Rakhi R B, Hu L B, et al. Nano Lett., 2011, 11(12):5165-5172 doi: 10.1021/nl2023433
23. [23]
  Hu H B, Zhang K, Li S X, et al. J. Mater. Chem. A, 2014, 2(48):20916-20922 doi: 10.1039/C4TA05345A
24. [24]
  Zhao J, Lai H W, Lyu Z Y, et al. Adv. Mater., 2015, 27(23):3541-3545 doi: 10.1002/adma.v27.23
25. [25]
  Xie Y B, Du H X, Xia C. Microporous Mesoporous Mater., 2015, 204:163-172 doi: 10.1016/j.micromeso.2014.11.021
26. [26]
  Yang H L, Xu H H, Li M, et al. ACS Appl. Mater. Interfaces, 2016, 8(3):1774-1779 doi: 10.1021/acsami.5b09526
27. [27]
  Sun J F, Huang Y, Fu C X, et al. J. Mater. Chem. A, 2016, 4(38):14877-14883 doi: 10.1039/C6TA05898A
28. [28]
  Lee J A, Shin M K, Kim S H, et al. Nat. Commun., 2013, 4:1970-1977 doi: 10.1038/ncomms2970
1. [1]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
2. [2]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
3. [3]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
4. [4]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
5. [5]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
6. [6]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
7. [7]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
8. [8]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(2003)
HTML views(327)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

Figure 1. SEM images of the samples

(A) PEDOT/HClO₄, (B) PEDOT/PSS/HClO₄, (C) PEDOT/SDS/HClO₄, (D) PEDOT /H₂SO₄, (E) PEDOT/PSS/H₂SO₄ and (F) PEDOT/SDS/H₂SO₄

Figure 2. SEM images for PEDOT/SDS/H₂SO₄ deposited on Au/PC membrane with different deposition times

(A) 500 s, (B) 600 s, (C) 700 s

Figure 3. (A) FTIR spectra of PEDOT/SDS/HClO₄, PEDOT/PSS/HClO₄ and PEDOT/HClO₄, and (B) PEDOT/SDS/H₂SO₄, PEDOT/PSS/H₂SO₄ and PEDOT/H₂SO₄

Figure 4. (A) Cyclic voltammetry curves and (B) areal capacitances of PEDOT/HClO₄, PEDOT/PSS/HClO₄ and PEDOT/SDS/HClO₄ at a scan rate of 500 mV·s^-1; (C) Galvanostatic charge-discharge curves and (D) areal capacitances of PEDOT/HClO₄, PEDOT/PSS/HClO₄ and PEDOT/SDS/HClO₄ at a current density of 0.1 mA·cm^-2

Figure 5. (A) Cyclic voltammetry curves and (B) areal capacitances of PEDOT/H₂SO₄, PEDOT/PSS/H₂SO₄ and PEDOT/SDS/H₂SO₄ at a scan rate of 500 mV·s^-1; (C) Galvanostatic charge-discharge curves and (D) areal capacitances of PEDOT/H₂SO₄, PEDOT/PSS/H₂SO₄ and PEDOT/SDS/H₂SO₄ at a current density of 0.1 mA·cm^-2

Figure 6. (A) Cyclic voltammetry curves at a scan rate of 500 mV·s^-1; (B) Galvanostatic charge-discharge curves at a current density of 0.1 mA·cm^-2; (C) Nyquist plots

PEDOT/SDS/HClO₄(a), PEDOT/SDS/H₂SO₄(b)

Figure 7. (A) Cyclic voltammetry curves and (B) areal capacitances with respect to different deposition times of 500, 600 and 700 s at a scan rate of 500 mV·s^-1; (C) Galvanostatic charge-discharge curves and (D) real capacitances of the PEDOT/SDS/H₂SO₄ nanotubes-based electrode at a current density of 0.1 mA·cm^-2 with different deposition times of 500, 600 and 700 s

Figure 8. (A) CV curves (B) areal capacitance of the PEDOT/SDS/H₂SO₄-600 under different bending states (0°, 60°, 120° and 180°) collected at a scan rate of 500 mV·s^-1, (C₀ is the initial areal capacitance, C is the areal capacitances under different bending condition); (C) Cycling stability of the PEDOT/SDS/H₂SO₄-600 upon charging/discharging at a current density of 0.6 mA·cm^-1, inset is an LED driven by the tandem PEDOT/SDS/H₂SO₄-600 nanotubes; (D) Ragone graph of PEDOT/SDS/H₂SO₄-600