Synthesis, Crystal Structure and DNA Interaction of a Cu(Ⅱ) Complex with Bis-hydrazone Ligand Bearing Pyrazine Unit
- Corresponding author: ZHAO Xiao-Lei, zhaoxiaolei@hpu.edu.cn WU Wei-Na, wuwn08@hpu.edu.cn
Citation: WU Hao, ZHAO Xiao-Lei, ZHONG Run-Bin, DAI Geng-Geng, WU Wei-Na, WANG Yuan. Synthesis, Crystal Structure and DNA Interaction of a Cu(Ⅱ) Complex with Bis-hydrazone Ligand Bearing Pyrazine Unit[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1917-1922. doi: 10.11862/CJIC.2018.215
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H atoms are omitted for clarity in (a) and (b); H atoms of C-H bonds and disordered methanol molecules are omitted for clarity in (c); Symmetry codes: ⅰ-x+0.5, y, -z; ⅱ x+2, y+1, z; ⅲ x+2, y+1, z+1; ⅳ x, y, z+1
Arrow shows the fluorescence intensities change of EB-DNA system upon increasing tested complex concentration; Inset: plot of I0/I versus r