Citation: MU Jin-Cheng, JIANG Sai, JI Sheng-Fu. Preparation and Properties for Aza-Micheal Addition Reaction of Magnetic Y-MOF@SiO₂@Fe₃O₄ Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1753-1760. doi: 10.11862/CJIC.2018.209 shu

Preparation and Properties for Aza-Micheal Addition Reaction of Magnetic Y-MOF@SiO₂@Fe₃O₄ Catalysts

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
2.
Engineering Laboratory of Chemical Resources Utilization in South Xinjiang of XPCC, Tarim University, Alar, Xinjiang 843300, China

Corresponding author: JI Sheng-Fu, jisf@mail.buct.edu.cn
Received Date: 11 May 2018
Revised Date: 27 June 2018

Figures(7)

The magnetic Y-MOF@SiO₂@Fe₃O₄ catalysts with different Y-MOF contents were synthesized by encapsulating magnetic SiO₂@Fe₃O₄ nanospheres into Y-MOF through an in-situ method. The structure of the catalyst was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), infrared spectroscopy (FT-IR), vibration sample magnetometer (VSM) and the N₂ adsorption-desorption test. The performance of the catalyst for Aza-Micheal addition reaction with aniline and methyl acrylate was evaluated. The results showed that Y-MOF was uniformly coated on the surface of the SiO₂@Fe₃O₄ nanospheres to form a core-shell magnetic Y-MOF@SiO₂@Fe₃O₄ catalyst. The catalysts exhibited good superparamagnetism. When Y-MOF content was 43.3% (w/w), the Y-MOF@SiO₂@Fe₃O₄ catalyst had better catalytic performance for the Aza-Micheal addition reaction. The conversion of methyl acrylate was 88.3% and the selectivity of N-(β-methoxycarbonylethyl) aniline was 99.8%. After reaction, the catalyst was recovered by magnetic recovery. It was reused five times, and still has high conversion and selectivity.
- magnetic,
- Y-MOF@SiO₂@Fe₃O₄,
- catalyst,
- Aza-Micheal reaction
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Properties for Aza-Micheal Addition Reaction of Magnetic Y-MOF@SiO2@Fe3O4 Catalysts

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通讯作者: 陈斌, bchen63@163.com

Preparation and Properties for Aza-Micheal Addition Reaction of Magnetic Y-MOF@SiO₂@Fe₃O₄ Catalysts