Citation: WANG Peng-Fei. Assembly and Properties of a 2D Layer Coordination Polymer Containing Linear Tetranuclear Cobalt-Cluster Unit Bridged by Tricarboxylic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1747-1752. doi: 10.11862/CJIC.2018.207 shu

Assembly and Properties of a 2D Layer Coordination Polymer Containing Linear Tetranuclear Cobalt-Cluster Unit Bridged by Tricarboxylic Acid Ligand

WANG Peng-Fei ^1,2,,

1.
School of Chemistry and Material Engineering, Chizhou University, Chizhou, Anhui 247000, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: WANG Peng-Fei, njuwangpf@163.com
Received Date: 3 May 2018
Revised Date: 8 June 2018

Figures(7)

The hydrothermal reaction of cobalt(Ⅱ) salts with 2-hydroxyl-1, 3, 5-benzenetricarboxylic acid (OH-H₃BTC) in the presence of sodium hydroxide afforded a cobalt(Ⅱ) coordination polymer, namely[Co₂(O-BTC)(H₂O)₅]_n (1), which has been characterized by powder and single-crystal X-ray diffraction, infrared spectroscopy, elemental analysis, and thermogravimetric analysis. Compound 1 contains a linear tetranuclear unit[Co₄O₇] through the carboxylate oxygen and hydroxyl atoms, which are further linked to form a two-dimensional (2D) layered structure in the ab plane by the O-BTC^4- organic ligands. Adjacent layers are packed along the c-axis with the hydrogen bond interactions dominating between the layers to form a three-dimensional (3D) supramolecular structure. Thermal analysis reveals that 1 begins to lose weight at ca. 100℃. Magnetic studies reveal that dominant antiferromagnetic interactions are dominated between the magnetic centers in 1.
- coordination polymer,
- magnetic properties,
- tetranuclear cobalt(Ⅱ)-cluster
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沈阳化工大学材料科学与工程学院沈阳 110142