Citation: GU Zhen-Yi, GUO Jin-Zhi, Yang YANG, LÜ Hong-Yan, ZHAO Xin-Xin, XI Xiao-Tong, HE Xiao-Yan, WU Xing-Long. Controlled Preparation and Performance Optimization of Na₃V₂(PO₄)₂O₂F as Cathode Material for Sodium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1641-1648. doi: 10.11862/CJIC.2018.204 shu

Controlled Preparation and Performance Optimization of Na₃V₂(PO₄)₂O₂F as Cathode Material for Sodium Ion Batteries

1.
College of Chemistry and Environmental Science, Yili Normal University, Yining, Xinjiang 835000, China
2.
National & Local United Engineering Laboratory for Power Batteries, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

Corresponding author: HE Xiao-Yan, hexy856@sina.com WU Xing-Long, xinglong@nenu.edu.cn
Received Date: 3 May 2018
Revised Date: 20 June 2018

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A simple hydrothermal preparation method was developed to prepare sodium fluoride phosphate vanadium oxide (Na₃V₂(PO₄)₂O₂F, abbreviated as NVPOF) material, regulating the morphology and size of the NVPOF by adjusting the key parameters including the pH value and hydrothermal temperature. The optimized NVPOF material exhibits the highest particle-size uniformity and thereby the best electrochemical properties. The pH value is 7.00±0.05 and the hydrothermal temperature is 170℃, which is the optimized parameters for the NVPOF preparation. The NVPOF material prepared at this condition delivers the specific capacity of 123.2 mAh·g^-1 at 0.1C (1C=130 mAh·g^-1) and 85.9 mAh·g^-1 at a high rate of 20C. The capacity retention is 96.2% after 200 cycles at 1C. All of the results indicate its high capacity, excellent rate and long cycle stability for Na storage. This is mainly attributed to the nanometer size and high uniformity of the NVPOF particles, which can provide the short Na⁺ transport path and hence shorten the time. Combining with the high stability of crystal structure, the optimized NVPOF material exhibits excellent performance as practical cathode for SIBs.
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Controlled Preparation and Performance Optimization of Na₃V₂(PO₄)₂O₂F as Cathode Material for Sodium Ion Batteries