Citation: GE Jing-Yuan, CHEN Zhong-Yan, MA Jian-Ping, HUANG Shuai, DU Jia, WANG Hai-Ou, SU Kun-Peng, WANG Hai-Ying. Synthesis, Structure and Magnetic Property of Dysprosium(Ⅲ) Complex Based on β-Diketonate and Tetramethylimidazolium Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1761-1767. doi: 10.11862/CJIC.2018.202 shu

Synthesis, Structure and Magnetic Property of Dysprosium(Ⅲ) Complex Based on β-Diketonate and Tetramethylimidazolium Ligands

1.
College of Materials and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
3.
School of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China

Corresponding author: GE Jing-Yuan, gejingyuan@hdu.edu.cn
Received Date: 17 April 2018
Revised Date: 7 June 2018

Figures(8)

A mononuclear dysprosium(Ⅲ) complex, namely (Tmim)[Dy(thd)₄] (1), was synthesized by the combination of 2, 2, 6, 6-tetramethylheptanedione (thd^-) anion ligand and a 1, 3, 4, 5-tetramethylimidazolium (Tmim⁺) cation balancing the charge. Complex 1 was structurally and magnetically characterized. The coordination geometry of Dy(Ⅲ) ion is ascribed to approximately square antiprismatic (D_4d) symmetry with the SAPR-8 parameter of 0.316. In the solid state, every mononuclear[Dy(thd)₄]^- anion is separated by Tmim⁺ cations regularly and the shortest Dy…Dy distance is 1.229 8 nm. Magnetic studies suggest that complex 1 behaves as a single-ion magnet under 500 Oe dc-applied field with a high effective energy of 30.9 K.
- coordination chemistry,
- dysprosium complexes,
- crystal structure,
- magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142