Citation: LIN Yu-Qing, GAO Min, ZHANG Hui, PENG Xue, GU Wen, LIU Xin, LIAO Sheng-Yun. Syntheses, Structures and Luminescent Properties of 3D Ni(Ⅱ)-Ln(Ⅲ) Heterometallic Coordination Polymers Constructed from the Triazol-Based Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1600-1609. doi: 10.11862/CJIC.2018.194 shu

Syntheses, Structures and Luminescent Properties of 3D Ni(Ⅱ)-Ln(Ⅲ) Heterometallic Coordination Polymers Constructed from the Triazol-Based Ligand

LIN Yu-Qing ¹ ,
GAO Min ¹ ,
ZHANG Hui ¹ ,
PENG Xue ¹ ,
GU Wen ² ,
LIU Xin ² ,
LIAO Sheng-Yun ^1,,

1.
Tianjin Key Laboratory of Organic Solar Cells and Photochemical Conversion, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, China
2.
Department of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: LIAO Sheng-Yun, 18202587221@163.com
Received Date: 3 May 2018
Revised Date: 21 May 2018

Figures(14)

A series of Ni(Ⅱ)-Ln(Ⅲ) heterometallic isomers[Ln₂Ni(tia)₄(H₂O)₄]_n (Ln=La (1), Ce (2), Pr (3), Nd (4), Sm (5), Eu (6), Gd (7), Tb (8) and Dy (9)), and {[Yb₂Ni(tia)₄(H₂O)₂]·2H₂O}_n (10) (tia=5-(1H-1, 2, 3-triazol-1-yl)isophthalate) have been constructed from the tritopic 1, 2, 3-trazol-based aromatic heterocyclic carboxylic ligand H₃ctia (H₃ctia=5-(4-carboxyl-1H-1, 2, 3-triazol-1-yl) isophthalic acid). The results of single crystal X-ray diffraction show that all of these complexes possess 3D microporous frameworks. Complexes 1~9 are isomorphic. The chemical composition of complex 10 is the same as those of 1~9, but the crystallographic structure is totally different from 1~9. In the visible region, complexes 5, 6, 8 and 9 exhibit the characteristic luminescent emissions of Sm(Ⅲ), Eu(Ⅲ), Tb(Ⅲ) and Dy(Ⅲ) with the long luminescent lifetime (234 μs for 6, 598 μs for 8 and 2.96 μs for 9). Complexes 4, 9 and 10 show characteristic emissions of Nd(Ⅲ), Dy(Ⅲ), and Yb(Ⅲ) in the near infrared region with the average lifetime of 4.25, 3.42 and 5.66 μs, respectively.
- coordination polymer,
- heterometallic complex,
- crystal structure,
- luminescent property,
- triazol-based ligand
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