Citation: KUANG Xiao-Nan, WANG Yu, ZHU Ning, LIU Min, YANG Yu-Ping, LI Zhong-Feng, HAN Hong-Liang, JIN Qiong-Hua. Syntheses, Characterization and Luminescent Properties of Two Silver(Ⅰ) Complexes Based on N-donor and P-donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(9): 1733-1738. doi: 10.11862/CJIC.2018.193 shu

Syntheses, Characterization and Luminescent Properties of Two Silver(Ⅰ) Complexes Based on N-donor and P-donor Ligands

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
3.
School of Science, Minzu University of China, Beijing 100081, China

Corresponding author: JIN Qiong-Hua, jinqh@cnu.edu.cn
Received Date: 22 April 2018
Revised Date: 11 May 2018

Figures(6)

Two novel silver(Ⅰ) complexes, [Ag₂(dppp)₂(phen)₂](CF₃SO₃)₂ (1) and[Ag₂(dppm)₂(dpq)₂](CF₃SO₃)₂·3CH₃OH (2) (dppp=bis(diphenylphosphino)propane, dppm=bis(diphenylphosphino)methane, phen=1, 10-phenan-throline, dpq=pyrazino[2, 3-f][1, 10]phenanthroline), have been synthesized in mixed solvent CH₃OH and CH₂Cl₂ and characterized by IR, single-crystal X-ray diffraction, ¹H NMR spectroscopy, fluorescence spectra and THz time domain spectroscopy (THz-TDS). Complex 1 is of a binuclear complex, which was generated by the reaction of AgCF₃SO₃ and dppp with phen in 1:1:1 molar ratio. In complex 1, the central Ag(Ⅰ) ion forms a ring by the bridging bisphosphine ligand (dppp) and chelating N-donor ligand (phen). Like 1, 2 is of a binuclear complex, which was obtained by the reaction of AgCF₃SO₃ and dppm with dpq in 1:1:1 molar ratio. The luminescent spectra show that all these emissions are assigned to ligand centered π-π^* transition.
- silver(Ⅰ) complex,
- fluorescence,
- terahertz spectra
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沈阳化工大学材料科学与工程学院沈阳 110142