Citation: LIU Yang, WANG Zhen-Ping, WANG Qing-Lun, TONG Yu-Zhang, YANG Chun. Syntheses, Crystal Structures and Magnetic Properties of Two One-Dimensional Heterotrimetallic Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(8): 1448-1454. doi: 10.11862/CJIC.2018.179 shu

Syntheses, Crystal Structures and Magnetic Properties of Two One-Dimensional Heterotrimetallic Coordination Polymers

1.
School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China
2.
Department of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: WANG Qing-Lun, wangql@nankai.edu.cn YANG Chun, ychun@hebut.edu.cn
Received Date: 9 February 2018
Revised Date: 11 May 2018

Figures(6)

Two novel heterotrimetallic 1D zigzag chain coordination polymers, {[Cu(Me₂valpn)Dy(DMF)₂(H₂O)Fe(CN)₆]·1.5H₂O·0.5CH₃OH}_n (1) and {[Cu(Me₂valpn) Tb(DMF)₂(H₂O)Fe(CN)₆]·H₂O·CH₃OH}_n (2) (H₂Me₂valpn=N, N'-bis(3-methoxysalicylidene)-2, 2-dimethyl-1, 3-diaminopropane), were prepared by stepwise synthetic approach. Single -crystal X-ray diffraction analysis revealed that each[Fe(CN)₆]^3- is connected with two[Cu(Me₂valpn)]Ln(DMF)₂(H₂O)]³⁺ fragments in a cis-mode. Accordingly, there are two types of bent bridging linkages (Fe-C≡N-Cu and Fe-C≡N-Ln) in the chain besides the diphenoxo bridges between Cu(Ⅱ) and Ln(Ⅲ). In the temperature range of 9.5~300 K, the dc magnetic susceptibilities of complex 1 are consistent with the Curie-Weiss law and give positive Curie-Weiss constants (θ=13.17 K), indicating the presence of predominant ferromagnetic interactions. The AC magnetic measurements reveal that complex 1 shows no slow magnetization relaxation.
- compartmental Schiff base,
- heterotrimetallic complex,
- coordination polymer,
- crystal structure,
- magnetic property
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沈阳化工大学材料科学与工程学院沈阳 110142