Citation: MA Shi-Ping, CUI Yong-Li, ZHU Hong-Gang, ZUO Wen-Qing, SHI Yue-Li, ZHUANG Quan-Chao. Synthesis and Electrochemical Performance in Modified Electrolyte of Microspheres LiNi_0.8Co_0.1Mn_0.1O₂[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1303-1311. doi: 10.11862/CJIC.2018.158 shu

Synthesis and Electrochemical Performance in Modified Electrolyte of Microspheres LiNi_0.8Co_0.1Mn_0.1O₂

School of Materials Science and Engineering, China University of Mining & Technology, Xuzhou, Jiangsu 221116, China

Corresponding author: CUI Yong-Li, lilyshuoxu@163.com
Received Date: 30 January 2018
Revised Date: 12 April 2018

Figures(13)

Microsphere high-nickel ternary LiNi_0.8Mn_0.1Co_0.1O₂ (LNCM811) cathode was syntheisized by the chemical co-precipitation method with a simple solid-state reaction, and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscope (TEM). Electrochemical behavior of LNCM811 was investigated by electrochemical impedance spectroscopy (EIS), combining with cyclic voltammogram (CV) and charge/discharge test in the 1 mol·L^-1 LiPF₆EC:EMC electrolyte with 2% (w/w) ethylene sulfate (DTD) and 1% (w/w) methylene methanedisulfonate (MMDS) additives either singly or in combination at room temperature of 25℃ or elevated temperature of 60℃. It is found that compared with 1% MMDS, the 2% DTD can slightly improve the initial coulombic efficiency and initial discharge capacity of the LNCM811 at room temperature. Both 2% DTD and 1% MMDS can improve the long cycling performance of LNCM811, and the 2% DTD additive is better than the 1% MMDS additive at 25℃, however, the 1% MMDS is better than the 2% DTD at elevated temperature of 60℃. After long cycles, the LNCM811 cathode has the best cycling performance with additive combination 2% DTD+1% MMDS. EIS results reveal that the additive blend of 2% DTD+1% MMDS can drastically lower the kinetics impedances.
- lithium ion battery,
- LiNi_0.8Mn_0.1Co_0.1O₂ cathode,
- electrolyte additives,
- electrochemical performance
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Synthesis and Electrochemical Performance in Modified Electrolyte of Microspheres LiNi0.8Co0.1Mn0.1O2

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Synthesis and Electrochemical Performance in Modified Electrolyte of Microspheres LiNi_0.8Co_0.1Mn_0.1O₂