Citation: CHENG Hao, XIE Jian, CHEN Zhen, TU Jian, CAO Gao-Shao, ZHAO Xin-Bing. Co₃O₄@δ-MnO₂/Pt Core-Shell Arrays as Efficient Catalytic Cathode for Lithium-Oxygen Cells[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(6): 1173-1182. doi: 10.11862/CJIC.2018.137 shu

Co₃O₄@δ-MnO₂/Pt Core-Shell Arrays as Efficient Catalytic Cathode for Lithium-Oxygen Cells

CHENG Hao ¹ ,
XIE Jian ^1,2,, ,
CHEN Zhen ³ ,
TU Jian ³ ,
CAO Gao-Shao ² ,
ZHAO Xin-Bing ^1,2

1.
School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
2.
Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, Hangzhou 310027, China
3.
LI-FUN Technology Corporation Limited, Zhuzhou, Hunan 412000, China

Corresponding author: XIE Jian, xiejian1977@zju.edu.cn
Received Date: 9 January 2018
Revised Date: 23 March 2018

Figures(6)

A unique core-shell Co₃O₄@δ-MnO₂/Pt arrays-type cathode on Ni foam has been fabricated by a facile, controlled hydrothermal approach. The array-type structure facilitates the electrode wetting and oxygen gas transport and supplies free volume for Li₂O₂ loading. The Co₃O₄@δ-MnO₂/Pt cathode exhibits high catalytic effect for ORR and OER, where thin-layered Li₂O₂ shows conformal growth along the surface of the Co₃O₄@δ-MnO₂/Pt arrays with the array-type structure remained. This growth behavior of Li₂O₂ renders easy decomposition of Li₂O₂ upon charge. Li-O₂ cells with Co₃O₄@δ-MnO₂/Pt delivers a high discharge capacity (2 480 mAh·g^-1 at 100 mA·g^-1) and long cycle life (65 cycles at 200 mA·g^-1 with a limited capacity of 500 mAh·g^-1), which are better than those with Co₃O₄ or Co₃O₄@δ-MnO₂ cathodes.
- Li-O₂ cells,
- electrocatalysis,
- core-shell array,
- Co₃O₄@δ-MnO₂/Pt
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Co3O4@δ-MnO2/Pt Core-Shell Arrays as Efficient Catalytic Cathode for Lithium-Oxygen Cells

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通讯作者: 陈斌, bchen63@163.com

Co₃O₄@δ-MnO₂/Pt Core-Shell Arrays as Efficient Catalytic Cathode for Lithium-Oxygen Cells