Citation: WANG Yu-Fang, TAI Jun-Hui, YAN Xiao-Wei, ZHAO Meng-Yun, WANG Li-Ya. Crystal Structures and Magnetic Properties of Two Isomorphic Frameworks Based on 3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1, 2, 4-triazole and 1, 2, 4, 5-Benzenetetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(6): 1121-1126. doi: 10.11862/CJIC.2018.135 shu

Crystal Structures and Magnetic Properties of Two Isomorphic Frameworks Based on 3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1, 2, 4-triazole and 1, 2, 4, 5-Benzenetetracarboxylic Acid

1.
College of Chemistry and Chemical Engineering, Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang, Henan 471934, China
2.
College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473000, China

Corresponding author: WANG Yu-Fang, wangyf78@163.com
Received Date: 19 October 2017
Revised Date: 27 March 2018

Figures(5)

Two new isomorphic coordination polymers, [M(btec)_0.5(H₂L)]_n (M=Co(Ⅱ) (1), Cu(Ⅱ) (2); H₄btec=1, 2, 4, 5-benzenetetracarboxylic acid; H₂L=3-(1H-pyrazol-4-yl)-5-(pyridin-2-yl)-1, 2, 4-triazole), have been synthesized under hydrothermal conditions. Compounds 1 and 2 were structurally characterized by elemental analysis, single crystal X-ray diffraction analysis, infrared spectroscopy and powder X-ray diffraction analysis. Single crystal X-ray diffraction measurement reveals that compounds 1 and 2 are isostructural structure and all crystallize in the orthorhombic system, space group Pbca. Compounds 1 and 2 have same 2D structure, which are connected by N…H…O hydrogen bonds to generate 3D frameworks. In addition, magnetic studies indicate that 1 show weak ferromagnetic exchange through carboxylate bridges between metal ions, and there is typical paramagnetic behavior in 2.
- isomorphic,
- crystal structure,
- magnetic property
1. [1]
  Cowan M G, Miller R G, Southon P D, et al. Inorg. Chem., 2014, 53:12076-12083 doi: 10.1021/ic501876m
2. [2]
  Goswami S, Adhikary A, Jena H S, et al. Inorg. Chem., 2013, 52:12064-12069 doi: 10.1021/ic401886f
3. [3]
  Zhang X, Sun M L, Huang Y Y, et al. Inorg. Chem. Commun., 201, 37:155-157
4. [4]
  Feng X, Liu J, Chen J L, et al. Inorg. Chem. Commun., 2014, 50:42-47
5. [5]
  Feng X, Chen J L, Li R F, et al. Inorg. Chem. Commun., 2016, 66:41-46
6. [6]
  Huang Y M, Zhang B G, Duan J G, et al. Cryst. Growth Des., 2014, 14:2866-2872 doi: 10.1021/cg500175k
7. [7]
  Ward M D, Raithby P R. Chem. Soc. Rev., 2013, 42:1619-1636
8. [8]
  Du M, Li C P, Liu C S, et al. Coord. Chem. Rev., 2013, 257:1282-1305
9. [9]
  TANG Hui, GUO Yan-Hong, SHENG Jun-Feng, et al. Chinese J. Inorg. Chem., 2017, 33(1):134-142 doi: 10.11862/CJIC.2017.012
10. [10]
  Wang Y F, Li S H, Ma L F, et al. Inorg. Chem. Commun., 2015, 62:42-46
11. [11]
  Guo X G, Yang W, Wu X, et al. Dalton Trans., 2013, 42:15106-15112 doi: 10.1039/c3dt51574e
12. [12]
  Colombo V, Galli S, Choi H J, et al. Chem. Sci., 2011, 2:1311-1319 doi: 10.1039/c1sc00136a
13. [13]
  Ganguly S, Mondal R. Cryst. Growth Des., 2015, 15:2211-2222 doi: 10.1021/cg5018592
14. [14]
  Ma L, Yu N Q, Chen S S, et al. CrystEngComm, 2013, 15:1352-1364 doi: 10.1039/c2ce26323h
15. [15]
  Chen K J, Lin R B, Liao P Q, et al. Cryst. Growth Des., 2013, 13:2118-2123 doi: 10.1021/cg400183s
16. [16]
  Sheldrick G M. Acta Crystallogr. Sect. A:Found. Crystallogr., 2008, A64:112-122
17. [17]
  Wang Y F, Li Z, Sun Y C, et al. Inorg. Chem. Commun., 2014, 44:25-28 doi: 10.1016/j.inoche.2014.02.043
18. [18]
  Fisher M E. Am. J. Phys., 1964, 32:343-346 doi: 10.1119/1.1970340
19. [19]
  Ma L F, Wang Y Y, Wang L Y, et al. Eur. J. Inorg. Chem., 2008:693-703
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2. [2]
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17. [17]
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18. [18]
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20. [20]
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142