Citation: CHENG Lin, LIU Qi, YANG Jing-Hua, ZHANG Qing-Song. Anion-Induced Chiral Cu(Ⅱ) Coordination Polymers: Reversible Structural Transformation, CD Spectra and SHG Response[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(6): 1018-1027. doi: 10.11862/CJIC.2018.134 shu

Anion-Induced Chiral Cu(Ⅱ) Coordination Polymers: Reversible Structural Transformation, CD Spectra and SHG Response

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: CHENG Lin, lcheng@seu.edu.cn
Received Date: 11 January 2018
Revised Date: 31 January 2018

Figures(10)

Two new chiral Cu(Ⅱ) coordination polymers, {[Cu((1R, 2R)-3-bcpb)]Cl₂}_n (1) and {[Cu((1R, 2R)-3-bcpb)₂](ClO₄)₂·2H₂O·2CH₃OH}_n (2) ((1R, 2R)-3-bcpb=N, N'-((1R, 2R)-cyclohexane-1, 2-diyl)bis(N-(pyridin-3-ylmethyl)benz-amide)), have been assembled with a chiral V-shaped bidentate ligand and different Cu(Ⅱ) salts, in which 1 is a 1D linear chain, while 2 displays a 2D (4, 4) topology. 1 can be directly transformed to 2 by the introduction of AgClO₄, and 2 can also be directly converted to 1 by the addition of NaCl in methanol under solvothermal conditions. CD spectra and SHG response of the complexes confirm that their bulk samples are both of structural chirality.
- chiral coordination polymers,
- reversible structural transformation,
- chiral 1, 2-diaminocyclohexane,
- anion-induced
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