Citation: LI Yu, WEN Bing-Song, ZOU Xun-Zhong, HUANG Bin, QIU Wen-Da, ZHANG Ze-Min, YOU Ao, CHENG Xiao-Ling. Syntheses, Crystal Structures, and Magnetic Properties of 0D Tetranuclear Nickel(Ⅱ) Coordination Compound and 1D Manganese(Ⅱ) Coordination Polymer Constructed from Biphenyl Tricarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 981-988. doi: 10.11862/CJIC.2018.131 shu

Syntheses, Crystal Structures, and Magnetic Properties of 0D Tetranuclear Nickel(Ⅱ) Coordination Compound and 1D Manganese(Ⅱ) Coordination Polymer Constructed from Biphenyl Tricarboxylic Acid

LI Yu ^1,, ,
WEN Bing-Song ² ,
ZOU Xun-Zhong ¹ ,
HUANG Bin ¹ ,
QIU Wen-Da ¹ ,
ZHANG Ze-Min ¹ ,
YOU Ao ¹ ,
CHENG Xiao-Ling ^2,,

1.
School of Eco-Environmental Engineering, Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China
2.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China

Corresponding author: LI Yu, liyuletter@163.com CHENG Xiao-Ling, gcxl@163.com
Received Date: 1 December 2017
Revised Date: 17 March 2018

Figures(10)

A 0D tetranuclear nickel(Ⅱ) coordination compound and a 1D manganese(Ⅱ) coordination polymer, namely[Ni₂(μ₃-Hbptc) (Hbptc)(phen)₃(H₂O)]₂·4H₂O (1) and {[Mn₃(μ₄-cptc)₂(2, 2'-bipy)₂(H₂O)₄]·2H₂O}_n (2), have been constr-ucted hydrothermally using H₃bptc (H₃bptc=biphenyl-2, 5, 3'-tricarboxylate acid), H₃cptc (H₃cptc=2-(4-carboxypyri-din-3-yl)terephalic acid), phen (phen=1, 10-phenanthroline) or 2, 2'-bipy (2, 2'-bipy=2, 2'-bipyridine), and nickel or manganese chlorides. Single-crystal X-ray diffraction analyses revealed that both compounds crystallize in the triclinic system, space group P1. In compound 1, two μ₃-Hbptc^2- ligands bridge alternately neighboring Ni(Ⅱ) ions to form a discrete tetranuclear nickel(Ⅱ) structure. These Ni₄ units are assembled to a 3D supramolecular framework through O-H…O hydrogen bond. In compound 2, three neighboring Mn(Ⅱ) ions are bridged by four different μ₄-cptc^3- ligands, giving rise to a centrosymmetric trinuclear Mn(Ⅱ) subunit. The adjacent Mn₃ subunits are further linked by the cptc^3- blocks into a 1D chain. Magnetic studies for compounds 1 and 2 demonstrate an antiferro-magnetic coupling between the adjacent metal centers.
- coordination polymer,
- hydrogen bonding,
- tricarboxylic acid,
- magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142