Citation: YANG Yu-Hua, ZHANG Yu, YU Meng, ZHENG Shan-Shan, DONG Wen-Kui. Heterobimetallic Cu(Ⅱ)-Nd(Ⅲ) and Zn(Ⅱ)-Ce(Ⅲ) Salamo-Type Complexes: Syntheses, Crystal Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 997-1006. doi: 10.11862/CJIC.2018.125 shu

Heterobimetallic Cu(Ⅱ)-Nd(Ⅲ) and Zn(Ⅱ)-Ce(Ⅲ) Salamo-Type Complexes: Syntheses, Crystal Structures and Fluorescence Properties

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: DONG Wen-Kui, dongwk@126.com
Received Date: 10 January 2018
Revised Date: 16 March 2018

Figures(9)

Heterobinuclear 3d-4f complexes having chemical formulae[Cu(L)Nd(NO₃)₃(C₂H₅OH)] (1) and[Zn(L)(OAc)Ce(NO₃)₂(CH₃OH)] (2) with a Salamo-type ligand O, O'-(ethane-1, 2-diyl)bis(1-(3-ethoxy-2-hydroxyphenyl)-3-ethoxy-2-hydroxybenzaldehyde oxime) (H₂L)were synthesized, and characterized by elemental analyses, IR, UV-Vis, fluorescence spectra and X-ray crystallography. Complex 1 is an asymmetrical dinuclear complex, the pentacoordinate Cu(Ⅱ) ion has a slightly distorted square pyramidal geometry, and deca-coordinated Nd(Ⅲ) ion possesses a distorted bicapped twelve surface geometry. Complex 2 is also an asymmetrical dinuclear complex, the penta-coordinate Zn(Ⅱ) ion bears a distorted square pyramidal geometry too, and deca-coordinated Ce(Ⅲ) ion adopts a distorted bicapped twelve surface geometry. Compared with the ligand H₂L, complex 1 showed fluorescence quenching, while complex 2 exhibited the fluorescence enhancement when the excitation wavelength is 318 nm.
- Salamo-type ligand,
- 3d-4f complex,
- synthesis,
- crystal structure,
- fluorescence property
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