Citation: ZHANG Ming, LI Tao, WANG Juan, PAN Yi, MA Shi-Jie, ZHU Han, DU Ming-Liang. Honeycomb-like Structured and Co-Mn Incorporated Carbon Materials Derived from Bombyx mori Cocoons Act as a Bifunctional Catalyst for Water Splitting[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 942-950. doi: 10.11862/CJIC.2018.122 shu

Honeycomb-like Structured and Co-Mn Incorporated Carbon Materials Derived from Bombyx mori Cocoons Act as a Bifunctional Catalyst for Water Splitting

ZHANG Ming ^1,, ,
LI Tao ¹ ,
WANG Juan ¹ ,
PAN Yi ¹ ,
MA Shi-Jie ¹ ,
ZHU Han ² ,
DU Ming-Liang ²

1.
Key Laboratory of Advanced Textile Materials and Manufacturing Technology of the Ministry of Education, College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China
2.
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China

Corresponding author: ZHANG Ming, zhangming@zstu.edu.cn
Received Date: 13 November 2017
Revised Date: 17 March 2018

Figures(5)

Porous and graphene-type honeycomb-like structured N-doped and Co-Mn incorporated carbon materials derived from Bombyx mori silk cocoons were synthesized via one-step thermal carbonization and graphitization process. Due to the high specific surface area of honeycomb-like structure, the exposed Co-Mn active sites and the pyridine-N and graphitic-N, the prepared 3% Co-Mn/silk cocoon carbon materials (3% Co-Mn/SCC) exhibits good hydrogen evolution reaction (HER) performance with a low onset potential of 121 mV, a low overpotential of 155 mV at 10 mA·cm^-2 and a Tafel slope of 130 mV·dec^-1 as well as a long-term stability in acidic electrolyte. Meanwhile, the 2% Co-Mn/SCC also shows great oxygen evolution reaction (OER) performance in 1 mol·L^-1 KOH with the lowest onset potential 1.5 mV and a Tafel slope of 143 mV·dec^-1. This result demonstrates that MCo-Mn/SCC (M is the mass fraction of Co and Mn) possess both HER and OER catalytic activity and can act as a bifunctional catalyst for water electrolysis.
- carbon materials,
- Bombyx mori silk cocoons,
- bifunctional catalyst,
- water splitting
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