Citation: YANG Long, WANG Qin, DENG Yong-Jun, WANG Xiao-Yuan, HE Ren, YI Zhi-Yong, JIANG Long, QIU Yong. Effect of Metal Exchange on the Light-Absorbing and Band-Gap Properties of Nanoporous Zn-Cu based MOFs[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(7): 1199-1208. doi: 10.11862/CJIC.2018.117 shu

Effect of Metal Exchange on the Light-Absorbing and Band-Gap Properties of Nanoporous Zn-Cu based MOFs

YANG Long ^1,, ,
WANG Qin ² ,
DENG Yong-Jun ³ ,
WANG Xiao-Yuan ¹ ,
HE Ren ¹ ,
YI Zhi-Yong ¹ ,
JIANG Long ² ,
QIU Yong ^1,,

1.
Institute of Systems Engineering, China Academy of Engineering Physics, Mianyang, Sichuan 621999, China
2.
State Key Laboratory of Polymer Materials Engineering of China, Polymer Research Institute of Sichuan University, Chengdu 610065, China
3.
Shock and Vibration of Engineering Materials and Structures Key Laboratory of Sichuan Province, Mianyang, Sichuan 621000, China

Corresponding author: YANG Long, rjcyangl@caep.cn QIU Yong, qiuy@caep.cn
Received Date: 20 December 2017
Revised Date: 20 March 2018

Figures(8)

Cu(Ⅱ) and Zn(Ⅱ) ions were selected as the basic mixed metal nodes connected by organic ligand 1, 4-benzenedicarboxylic acid (BDC) and synthesized nanoporous Zn-Cu based mixed-metal MOFs Zn(BDC)-Cu, Cu(BDC)-Zn and Zn-Cu-BDC through different synthetic routes. Through characterization of PXRD, SEM, UV-Vis DRS, FT-IR, XPS and UPS and systematic analysis, it is found that the solar light absorbing range of Zn(BDC) is located in UV band (< 400 nm), while Cu(BDC) mainly absorbs the whole visible light (500~1 000 nm). Additionally, the Zn-Cu ions uniformly-dispersed product Zn-Cu-BDC performs better in light-absorption and exhibits lower photo band-gap and HOMO level than the other bi-metallic products Zn(BDC)-Cu and Cu(BDC)-Zn. The investigation might inspire the design of heterogeneous photocatalysts and organic-inorganic hybrids in the aspects of light-absorption and charge transfer and construction methods on metal exchange due to different routes leading to different properties despite of the same components.
- metal-organic frameworks (MOFs),
- Zn-Cu,
- metal exchange,
- light-absorption,
- band gap
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