Citation: WANG Rui, GONG Yong, XU Hai-Juan, WEI Shi-Yong, WU De-Yong. Characteristics and Adsorption Properties of Se(Ⅳ) for MOF-Fe Prepared with Different Conditioning Agents[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 906-916. doi: 10.11862/CJIC.2018.110 shu

Characteristics and Adsorption Properties of Se(Ⅳ) for MOF-Fe Prepared with Different Conditioning Agents

WANG Rui ¹ ,
GONG Yong ² ,
XU Hai-Juan ¹ ,
WEI Shi-Yong ^1,3,, ,
WU De-Yong ^1,3

1.
Department of Chemistry and Environmental Engineering, Hubei University for Nationalities, Enshi, Hubei 445000, China
2.
Hubei Polytechnic Institute, Wuhan 432000, China
3.
Key Laboratory of Biologic Resource Protection and Utilization of Hubei Province, Enshi, Hubei 445000, China

Corresponding author: WEI Shi-Yong, weishiyong2007@126.com
Received Date: 6 December 2017
Revised Date: 28 January 2018

Figures(7)

MOF-Fe samples were prepared with HF, HCl, H₂O and NaAc as conditioning agents by hydrothermal method. The characteristics of the samples were studied by X-ray diffraction (XRD), Transmission electron microscope (TEM), N₂ adsorption/desorption, thermal analysis (TG/DTG and DTA) and proton potentiometric titration. Isothermal adsorption experiments of selenite (Se(Ⅳ)) on the samples were carried out. Crystal structure of all samples are same as MIL-100(Fe), and the morphology are octahedral, while the crystallinities and crystal orientations are different. The BET surface area are 1 683, 1 517, 1 641 and 1 734 m²·g^-1, respectively, and total pore volumes of the samples are decreased orderly. The micropore diameter are 1.27, 1.22, 1.22 and 1.17 nm for MOF-Fe(HF), MOF-Fe(HCl), MOF-Fe(H₂O) and MOF-Fe(NaAc). The temperature of decarboxylation of MOF-Fe(HF) is highest (415℃), while its carbonization temperature for benzene ring is lowest (462℃) compared with the others. A weight loss caused by redox between iron oxide and carbon appears in MOF-Fe(HCl), MOF-Fe(H₂O) and MOF-Fe(NaAc). The sequence of H⁺ consumed during the process of proton potentiometric titrations for samples is MOF-Fe(H₂O) > MOF-Fe(HCl) > MOF-Fe(HF)=MOF-Fe(NaAc), and pH value of zero point charge (pH_ZPC) are 3.1, 3.5, 3.6 and 3.5 accordingly. The sequence about the affinity of adsorption for Se(Ⅳ) on samples is MOF-Fe(NaAc) > MOF-Fe(HCl) > MOF-Fe(H₂O) > MOF-Fe(HF), and the maximum adsorption capacities (Q_m) are 77.69, 107.07, 117.40 and 87.15 mg·g^-1 correspondingly. The Q_m of Se(Ⅳ) on samples have positive correlation with density of hydroxyl for samples observably. This study reveals that the thermostability and density of active site of MOF-Fe are influenced by the conditioning agent when MOF-Fe was prepared. The HF could increase the strength of C-C between carboxyl and benzene ring, decrease carbonization temperature of benzene ring of MOF-Fe, and improve the thermostability of iron oxides after heating. While HCl and H₂O could improve the density of active site in samples, then the Q_m of Se(Ⅳ) adsorbed on MOF-Fe could be increased.
- MOF-Fe,
- conditioning agent,
- surface properties,
- adsorption,
- selenite
1. [1]
  Ju W, Li W, Li Z, et al. J. Trace Elem. Med. Biol., 2017, 44:8-16 doi: 10.1016/j.jtemb.2017.04.009
2. [2]
  Winkel L H, Johnson C A, Lenz M, et al. Environ. Sci. Technol., 2011, 46(2):571-579
3. [3]
  Fernández-Martínez A, Charlet L. Rev. Environ. Sci. Biote-chnol., 2009, 8(1):81-110 doi: 10.1007/s11157-009-9145-3
4. [4]
5. [5]
  ZHU Jian-Ming, QIN Hai-Bo, LI Lu, et al. Acta Scientiae Circumstantiae, 2008, 28(4):772-777
6. [6]
  Santos S, Ungureanu G, Boaventura R, et al. Sci. Total Environ., 2015, 521-522:246-260 doi: 10.1016/j.scitotenv.2015.03.107
7. [7]
  WANG Lin, SHI Yong-Sheng. Treatment of Waster Water Contain Selenium. Beijing:Chemistry Industry Press, 2005.
8. [8]
  Hu B W, Ye F, Jin C G, et al. Chemosphere, 2017, 184:408-416 doi: 10.1016/j.chemosphere.2017.05.179
9. [9]
  Xia X F, Ling L, Zhang W X. Chemosphere, 2017, 168:1597-1603 doi: 10.1016/j.chemosphere.2016.11.150
10. [10]
  Chan Y T, Kuan W H, Chen T Y, et al. Water Res., 2009, 43(17):4412-4420 doi: 10.1016/j.watres.2009.06.056
11. [11]
  Ma Z Y, Shan C, Liang J L, et al. Chemosphere, 2018, 193:134-141 doi: 10.1016/j.chemosphere.2017.11.005
12. [12]
  Rosi N L, Eckert J, Eddaoudi M, et al. Science, 2003, 300(5622):1127-1129 doi: 10.1126/science.1083440
13. [13]
  Sun J K, Xu Q. Energy Environ. Sci., 2014, 7(7):2071-2100 doi: 10.1039/c4ee00517a
14. [14]
  Alezi D, Belmabkhout Y, Suyetin M, et al. J. Am. Chem. Soc., 2015, 137(41):13308-13318 doi: 10.1021/jacs.5b07053
15. [15]
  Cao X H, Zheng B, Shi W H, et al. Adv. Mater., 2015, 27(32):4695-4701 doi: 10.1002/adma.v27.32
16. [16]
  Chen Q S, Sun J L, Li P, et al. J. Am. Chem. Soc., 2016, 138(43):14242-14245 doi: 10.1021/jacs.6b09880
17. [17]
  HUANG Gang, CHEN Yu-Zhen, JIANG Hai-Long. Acta Chim. Sinica, 2016, 74(02):113-129
18. [18]
  Guo H L, Zhu Y Z, Wang S, et al. Chem. Mater., 2012, 24(3):444-450 doi: 10.1021/cm202593h
19. [19]
  Cheng X Q, Zhang A F, Hou K K, et al. Dalton Trans., 2013, 42:13698-13705 doi: 10.1039/c3dt51322j
20. [20]
  Liu Y L, Gao P F, Huang C Z, et al. Sci. China Ser. B:Chem., 2015, 58(10):1553-1560 doi: 10.1007/s11426-015-5406-x
21. [21]
  Kumar P, Pournara A, Kim K H, et al. Prog. Mater. Sci., 2017, 86:25-74 doi: 10.1016/j.pmatsci.2017.01.002
22. [22]
  Patra S, Sene S, Mousty C, et al. ACS Appl. Mater. Interfaces, 2016, 8(31):20012-20022 doi: 10.1021/acsami.6b05289
23. [23]
  Bghadra B N, Jhung S H. ACS Appl. Mater. Interfaces, 2016, 8(10):6770-6777 doi: 10.1021/acsami.6b00608
24. [24]
  Zhu N N, Liu X H, Li T, et al. Inorg. Chem., 2017, 56(5):3414-3420
25. [25]
  Liu X C, Zhou Y Y, Zhang J C, et al. ACS Appl. Mater. Interfaces, 2017, 9(24):20255-20275 doi: 10.1021/acsami.7b02563
26. [26]
  Song G Q, Wang Z Q, Wang L, et al. Chin. J. Catal., 2014, 35(2):185-195 doi: 10.1016/S1872-2067(12)60729-3
27. [27]
  Lee Y R, Kim J, Ahn W S. Korean J. Chem. Eng., 2013, 30(9):1667-1680 doi: 10.1007/s11814-013-0140-6
28. [28]
  ZHANG Su, WANG Hai-Shui. Chinese J. Inorg. Chem., 2013, 29(1):31-35
29. [29]
  ZHAO Xin-Hua, CHEN Lin, CAO Yong-Ge, et al. Foundation of Solid-State Inorganic Chemistry and the Design Synthesis of Novel Materials. Beijing:Higher Education Press, 2012:128-131, 610-611
30. [30]
  Cornell R M, Schwertmann U. The Iron Oxides, Structure, Properties, Reactions Occurences, Uses. Weinheim: Wiley-VCH, 2003.
31. [31]
  Zhang L. Thesis for the Doctorate of Michigan Technological University. 2011.
32. [32]
  JIANG Wu-Feng, ZHAO Shuo, HAO Su-Ju, et al. Chinese Journal of Process Engineering, 2017, 17(2):362-366 doi: 10.12034/j.issn.1009-606X.216283
33. [33]
34. [34]
  Kuang L Y, Liu Y Y, Fu D D, et al. J. Colloid Interface Sci., 2017, 490:259-269 doi: 10.1016/j.jcis.2016.11.071
35. [35]
  Hajjaji W, Ganiyu S O, Tobaldi D M, et al. Appl. Clay Sci., 2013, 83-84:91-98 doi: 10.1016/j.clay.2013.08.013
36. [36]
  Chen L, Ji T, Mu L W, et al. J. Environ. Manage., 2017, 196:168-177 doi: 10.1016/j.jenvman.2017.03.013
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