Citation: WANG Li-Wen, SHANG Qi-Gao, ZHOU Jing-Jing, ZHOU Hong, PAN Zhi-Quan, CHENG Qing-Rong. Crystal Structures and Properties of Two Linear Trinuclear Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(5): 957-966. doi: 10.11862/CJIC.2018.105 shu

Crystal Structures and Properties of Two Linear Trinuclear Complexes

Wuhan Institute of Technology, Wuhan 430074, China

Corresponding author: CHENG Qing-Rong, chengqr383121@sina.com
Received Date: 29 September 2017
Revised Date: 4 February 2018

Figures(11)

Two new trinuclear complexes, [Co₂^ⅢCo^ⅡL₂(μ-OAc)₄] (1) and[Ni₃L₂(μ-OAc)₂(CH₃OH)₂]·2H₂O (2), were obtained and fully characterized, where L was the condensation product between 2-hydroxy-1, 3-propane diamine and 5-fluorosalicylaldehyde. The interaction of complex 1 with DNA has been investigated by spectroscopy, viscosity measurements and electrochemical studies. Absorption spectroscopic investigation reveals intercalative binding of Co complex with DNA, with a binding constant of 2.43×10⁵ L·mol^-1. Fluorescence spectroscopy shows that complex 1 can displace ethidium bromide and bind to DNA, with a quenching constant of 4.92×10³ L·mol^-1. The variable-temperature magnetisms of complexes 1 and 2 show that there are antiferromagnetic couplings among the three metal centers in both complexes. CCDC: 1587441, 1; 1587442, 2.
- linear trinuclear complex,
- crystal structure,
- DNA cleavage activity,
- magnetism
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