Citation: CHEN Dan-Dan, LI Guang-She, FAN Jian-Ming, LI Bao-Yun, ZHANG Dan, FENG Tao, LI Guo-Hua, LI Li-Ping. Differentiating the Integrated Structure from Lithium Rich Layer Oxide by ex situ Raman Spectroscopy: an Effective Method to Predict the Activation of Li₂MnO₃[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 703-711. doi: 10.11862/CJIC.2018.093 shu

Differentiating the Integrated Structure from Lithium Rich Layer Oxide by ex situ Raman Spectroscopy: an Effective Method to Predict the Activation of Li₂MnO₃

1.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China
2.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: LI Li-Ping, lipingli@jlu.edu.cn
Received Date: 14 November 2017
Revised Date: 25 January 2018

Figures(6)

The Li_1.2Mn_0.6Ni_0.2O₂ cathode was prepared by five synthesis routes:sol-gel, high temperature solid, coprecipitation, hydrothermal and solvothermal method. The analysis of Raman spectrum shows that the co-precipitation sample is solid solution structure, while the other four samples are composite structures formed at different scales. The results of electrochemical tests for as-prepared samples show obviously different performance, especially the capacity from the activation of Li₂MnO₃ during the first charging process (> 4.5 V). The co-precipitation sample with solid solution structure shows the highest capacity from the activation of Li₂MnO₃. Therefore, we can establish the connection between electrochemical performance and two-phase integration modes. Different integration modes affect the activation capacity of Li₂MnO₃, leading to different electrochemical properties.
- lithium ion battery,
- Li-rich cathode material,
- Raman spectrosopy,
- activation degree
1. [1]
  Choi N S, Chen Z, Freunberger S A, et al. Angew. Chem. Int. Ed., 2012, 51(40):9994-10024 doi: 10.1002/anie.201201429
2. [2]
  Santhanam R, Rambabu B. J. Power Sources, 2010, 195(17):5442-5451 doi: 10.1016/j.jpowsour.2010.03.067
3. [3]
  Dunn B, Kamath H, Tarascon J M. Science, 2011, 334(6058):928-935 doi: 10.1126/science.1212741
4. [4]
  Zhang X H, Luo D, Li G S, et al. J. Mater. Chem. A, 2013, 1(34):9721-9729 doi: 10.1039/c3ta11040k
5. [5]
  Goodenough J B, Kim Y. Chem. Mater., 2010, 22(3):587-603 doi: 10.1021/cm901452z
6. [6]
  Yu H, Ishikawa R, So Y G, et al. Angew. Chem. Int. Ed., 2013, 52(23):5969-5973 doi: 10.1002/anie.201301236
7. [7]
  Zhao X, Reddy M V, Liu H, et al. RSC Adv., 2014, 4(47):24538-24543 doi: 10.1039/c3ra45484c
8. [8]
  Yu H, Kim H, Wang Y, et al. Phys. Chem. Chem. Phys., 2012, 14(18):6584-6595 doi: 10.1039/c2cp40745k
9. [9]
  WANG Hai-Yan, TANG Ai-Dong, HUANG Ke-Long, et al. Chinese J. Inorg. Chem., 2008, 24(4):593-599
10. [10]
  Wei W F, Chen L B, Pan A Q, et al. Nano Energy, 2016, 30:580-662 doi: 10.1016/j.nanoen.2016.10.066
11. [11]
  WEI Xuan-Ni, LAI Qiong-Jie, GAO Yuan, et al. Chinese J. Inorg. Chem., 2005, 21(7):999-1003
12. [12]
  Ohzuku T, Nagayama M, Tsuji K, et al. J. Mater. Chem., 2011, 21(27):10179-10188 doi: 10.1039/c0jm04325g
13. [13]
  Thackeray M M, Kang S H, Johnson C S, et al. J. Mater. Chem., 2007, 17(30):3112-3125 doi: 10.1039/b702425h
14. [14]
  Song B, Lai M O, Liu Z, et al. J. Mater. Chem. A, 2013, 1(34):9954-9965 doi: 10.1039/c3ta11580a
15. [15]
  Lee S, Kim E Y, Lee H, et al. J. Power Sources, 2014, 269:418-423 doi: 10.1016/j.jpowsour.2014.06.167
16. [16]
  JIANG Yao-Xue, SHI Nan-Nan, ZHANG Yao-Ying, et al. Chem. J. Chinese Universities, 2015, 36(4):739-744
17. [17]
  Dixit H, Zhou W, Idrobo J, et al. ACS Nano, 2014, 8(12):12710-12716 doi: 10.1021/nn505740v
18. [18]
  Zhang X H, Yu C, Huang X D, et al. Electrochim. Acta, 2012, 81(30):233-238
19. [19]
  Zheng J X, Liu T C, Hu Z X, et al. J. Am. Chem. Soc., 2016, 138(40):13326-13334 doi: 10.1021/jacs.6b07771
20. [20]
  Ben-Kamel K, Amdouni N, Mauger A, et al. J. Alloys Compd., 2012, 528(5):91-98
21. [21]
  ZHENG Zhuo, HUA Wei-Bo, WU Zhen-Guo, et al. Chinese J. Inorg. Chem., 2017, 33(2):307-314
22. [22]
  Lu Z H, Chen Z H, Dahn J R, et al. Chem. Mater., 2013, 15(16):3214-3220
23. [23]
  Johnson C S, Kim J S, Lefief C, et al. Electrochem. Commun., 2004, 6(10):1085-1091 doi: 10.1016/j.elecom.2004.08.002
24. [24]
  Thackeray M M, Johnson C S, Vaughey J T, et al. J. Mater. Chem., 2005, 15(23):2257-2267 doi: 10.1039/b417616m
25. [25]
  Thackeray M M, Kang S H, Johnson C S, et al. J. Mater. Chem., 2007, 17(30):3112-3125 doi: 10.1039/b702425h
26. [26]
  Gu M, Genc A, Belharouak I, et al. Chem. Mater., 2013, 25(11):2319-2326 doi: 10.1021/cm4009392
27. [27]
  McCalla E, Li J, Rowe A W, et al. J. Electrochem. Soc., 2014, 161(4):A606-A613 doi: 10.1149/2.083404jes
28. [28]
  Li J, Camardese J, Glazier S, et al. Chem. Mater., 2014, 26(24):7059-7066 doi: 10.1021/cm503505b
29. [29]
  Tang D C, Liu D T, Liu Y Y, et al. Prog. Nat. Sci., 2014, 24(4):388-396 doi: 10.1016/j.pnsc.2014.07.005
30. [30]
  Fan J M, Li G S, Li G H, et al. Electrochim. Acta, 2017, 245(10):118-127
31. [31]
  Jarvis K A, Deng Z Q, Allard L F, et al. Chem. Mater., 2011, 23(16):3614-3621 doi: 10.1021/cm200831c
32. [32]
  Inaba M, Iriyama Y, Ogumi Z, et al. J. Raman Spectrosc., 1997, 28(8):613-617 doi: 10.1002/(ISSN)1097-4555
33. [33]
  Ammundsen B, Burns G R, Islam M S, et al. J. Phys. Chem. B, 1999, 103(25):5175-5180 doi: 10.1021/jp984398l
34. [34]
  Hwang S J, Park H S, Choy J H, et al. Electrochem. Solid-State Lett., 2001, 4(12):A213-A216 doi: 10.1149/1.1413704
35. [35]
  Ruther R E, Dixit H, Pezeshki A M, et al. J. Phys. Chem. C, 2015, 119(32):18022-18029 doi: 10.1021/acs.jpcc.5b03900
36. [36]
  Karan N K, Saavedra-Arias J J, Pradhan D K, et al. Electrochem. Solid-State Lett., 2008, 11(8):A135-A139 doi: 10.1149/1.2932052
37. [37]
  Jeong S K, Song C H, Nahm K S, et al. Electrochim. Acta, 2006, 52(3):885-891 doi: 10.1016/j.electacta.2006.06.024
38. [38]
  Julien C. Solid State Ionics, 2000, 136-137(2):887-896
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Differentiating the Integrated Structure from Lithium Rich Layer Oxide by ex situ Raman Spectroscopy: an Effective Method to Predict the Activation of Li2MnO3

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通讯作者: 陈斌, bchen63@163.com

Differentiating the Integrated Structure from Lithium Rich Layer Oxide by ex situ Raman Spectroscopy: an Effective Method to Predict the Activation of Li₂MnO₃