Citation: YAO Yu-Han, YUAN Zhen-Tao, ZHANG Yan-Nan, YU Xiao-Hua, RONG Ju, MENG Kun, ZHAN Zhao-Lin. Surface Modification and Electrochemical Lithium Storage Performance of TiO₂-Anatase Nanotube Arrays with CuO[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 662-668. doi: 10.11862/CJIC.2018.079 shu

Surface Modification and Electrochemical Lithium Storage Performance of TiO₂-Anatase Nanotube Arrays with CuO

YAO Yu-Han ^1,2 ,
YUAN Zhen-Tao ² ,
ZHANG Yan-Nan ² ,
YU Xiao-Hua ^1,2,, ,
RONG Ju ^2,3 ,
MENG Kun ² ,
ZHAN Zhao-Lin ²

1.
National Engineering Research Center of Solid Waste Resource, Kunming University of Science and Technology, Kunming 650093, China
2.
Faculty of Materials Science & Engineering, Kunming University of Science and Technology, Kunming 650093, China
3.
Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

Corresponding author: YU Xiao-Hua, xiaohua_y@163.com
Received Date: 1 November 2017
Revised Date: 9 January 2018

Figures(8)

Anodic oxidation and hydrothermal method were jointly used to prepare CuO/TiO₂ negative material which was synthesized from ethylene glycol, ammonium fluoride, hydrochloric acid, cupric chloride and sodium nitrate. Morphology, element distribution, valence state, microcosmic phase composition of the samples were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD). Furthermore, the electrochemical lithium insertion properties of CuO/TiO₂ were tested by the use of battery charge and discharge testing system and electrochemical workstation. The results show that there are particulates arrange the surface of the anatase TiO₂ nanotube. The nanometer size was 4 nm×10 nm. The as prepared CuO/TiO₂ displays plummy electric properties of initial discharge and charge capacities of 550 and 490 mAh·g^-1 at the rate of 0.3C. respectively. After 50 cycles the reserve capacities is 320 mAh·g^-1.
- surface modification,
- TiO₂-anatase nanotube array,
- CuO,
- electrochemical performance,
- microscopic structure
1. [1]
  Seh Z W, Li W, Cha J J, et al. Nat. Commun., 2013, 4(4):1331(6 Pages)
2. [2]
  Ren Y, Liu Z, Pourpoint F, et al. Angew. Chem. Int. Ed., 2012, 124(9):2206-2209
3. [3]
  Kim J, Cho J. J. Electrochem. Soc., 2007, 154(6):A542-A546 doi: 10.1149/1.2724756
4. [4]
  Li X F, Liu J, Zhang Y, et al. J. Power Sources, 2012, 197(1):238-245
5. [5]
  Augustyn V, Come J. Nat. Mater., 2013, 12(6):518-522 doi: 10.1038/nmat3601
6. [6]
  ZHANG Jing-Chang, LI Qing, CAO Wei-Liang. Chinese J. Inorg. Chem., 2004, 20(6):725-730
7. [7]
  Shenouda A Y, Liu H K. J. Alloys Compd., 2009, 477(1):498-503
8. [8]
  Panda S K, Yoon Y, Jung H S, et al. J. Power Sources, 2012, 204(1):162-167
9. [9]
  Yu X H, Zhan Z L, Rong J, et al. Chem. Phys. Lett., 2014, 600(600):43-45
10. [10]
  Yu X H, Zhan Z L. Nanoscale Res. Lett., 2014, 9(1):516(6 Pages)
11. [11]
  Yu X H, Rong J, Zhan Z L, et al. Mater. Des., 2015, 83(1):159-163
12. [12]
  Luo Y S, Luo J S, Jiang J, et al. Energy Environ. Sci., 2012, 5(4):6559-6566 doi: 10.1039/c2ee03396h
13. [13]
  Wu Z S, Ren W, Wen L, et al. ACS Nano, 2010, 4(6):3187-3194 doi: 10.1021/nn100740x
14. [14]
  Yan J Y, Song H H, Yang S B, et al. Electrochim. Acta, 2008, 53(22):6351-6355 doi: 10.1016/j.electacta.2008.04.048
15. [15]
  Reddy M V, Yu T, Sow C H, et al. Adv. Funct. Mater., 2007, 17(15):2792-2799 doi: 10.1002/(ISSN)1616-3028
16. [16]
  Li Y G, Tan B, Wu Y Y. Nano Lett., 2008, 8(1):265-270 doi: 10.1021/nl0725906
17. [17]
  ZHENG Jia-Fei, ZHENG Ming-Bo, LI Nian-Wu, et al. Chinese J. Inorg. Chem., 2013, 29(7):1355-1360
18. [18]
  Fu L J, Gao J, Zhang T, et al. J. Power Sources, 2007, 171(2):904-907 doi: 10.1016/j.jpowsour.2007.05.099
19. [19]
  Shao X, Zhang T, Wen Z Y. Chin. J. Chem., 2017, 35(1):35-40 doi: 10.1002/cjoc.v35.1
20. [20]
  Park J C, Kim J, Kwon H, et al. Adv. Mater., 2009, 21(7):803-807 doi: 10.1002/adma.v21:7
21. [21]
  Wang L L, Gong H X, Wang C, et al. Nanoscale, 2012, 4(21):6850-6855 doi: 10.1039/c2nr31898a
22. [22]
  Huang Q, Kang F, Xiao X D, et al. J. Mater. Chem. A, 2013, 1(7):2418-2425 doi: 10.1039/C2TA00918H
23. [23]
  Sheng P T, Li W L, Du P W, et al. Talanta, 2016, 160(1):537-546
24. [24]
  Juodkazyt J, Šebeka B, Savickaja I, et al. Electrochim. Acta, 2014, 137(6):363-371
25. [25]
  WU Yu-Cheng, LIU Xiao-Lu, YE Min, et al. Acta Phys.-Chim. Sin., 2008, 24(1):97-102
26. [26]
  Xue L G, Wei Z, Li R S, et al. J. Mater. Chem. A, 2011, 21(9):3216-3220 doi: 10.1039/c0jm03819a
27. [27]
  Zhu Y Z, He X F, Mo Y F. ACS Appl. Mater. Interface, 2015, 7(42):23685-23693 doi: 10.1021/acsami.5b07517
28. [28]
  Liu J, Song K, van Aken P A, et al. Nano Lett., 2014, 14(5):2597-2603 doi: 10.1021/nl5004174
29. [29]
  Klein F, Pinedo R, Hering P, et al. J. Phys. Chem. C, 2016, 120(3):1400-1414 doi: 10.1021/acs.jpcc.5b10642
30. [30]
  Svintsitskiy D A, Kardash T Y, Stonkus O A, et al. J. Phys. Chem. C, 2013, 117(28):14588-14599 doi: 10.1021/jp403339r
31. [31]
  Li A, Song H H, Wan W B, et al. Electrochim. Acta, 2014, 132(12):42-48
32. [32]
  Wang C, Higgins D, Wang F F, et al. Nano Energy, 2014, 9(2):334-344
33. [33]
  Xiang J Y, Tu J P, Zhang L, et al. J. Power Sources, 2010, 195(1):313-319 doi: 10.1016/j.jpowsour.2009.07.022
34. [34]
  Panda S K, Yoon Y, Jung H S, et al. J. Power Sources, 2012, 204(1):162-167
35. [35]
  Zu C X, Li H T. Energy Environ. Sci., 2011, 4(8):2614-2624 doi: 10.1039/c0ee00777c
36. [36]
  Zhang Y N, Dong P, Yu X H, et al. Int. J. Electrochem. Sci., 2017, 12(7):6853-6862
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沈阳化工大学材料科学与工程学院沈阳 110142

Surface Modification and Electrochemical Lithium Storage Performance of TiO2-Anatase Nanotube Arrays with CuO

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通讯作者: 陈斌, bchen63@163.com

Surface Modification and Electrochemical Lithium Storage Performance of TiO₂-Anatase Nanotube Arrays with CuO