Citation: WANG Yong, LIU Wen, GUO Rui, LUO Ying, LI Yong, PEI Hai-Juan, XIE Jing-Ying. Mechanism on Capacity Fading at Higher Charging Potential of NaNi_1/3Co_1/3Mn_1/3O₂ for Sodium Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 750-756. doi: 10.11862/CJIC.2018.074 shu

Mechanism on Capacity Fading at Higher Charging Potential of NaNi_1/3Co_1/3Mn_1/3O₂ for Sodium Ion Batteries

WANG Yong ¹ ,
LIU Wen ¹ ,
GUO Rui ¹ ,
LUO Ying ² ,
LI Yong ¹ ,
PEI Hai-Juan ¹ ,
XIE Jing-Ying ^1,2,,

1.
State Key Laboratory of Space Power-Sources Technology, Shanghai Institute of Space Power-Sources, Shanghai 200245, China
2.
Shanghai Power Energy Storage Battery System Engineering Technology Co., Ltd., Shanghai 200241, China

Corresponding author: XIE Jing-Ying, jyxie@mail.sim.ac.cn
Received Date: 23 October 2017
Revised Date: 17 December 2017

Figures(4)

NaNi_1/3Co_1/3Mn_1/3O₂ material was synthesized by a facile method, and the suitable working voltages (3.75 V, 4 V) are investigated afterwards. The mechanisms of capacity fading when charging to 4 V are studied by ex-situ XRD and EIS measurements, which revealed a collective effect between the thicker of the SEI layer and the irreversible variation of the material structure.
- sodium ion battery,
- cathode material,
- mechanism,
- capacity fading,
- high charge voltage
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Mechanism on Capacity Fading at Higher Charging Potential of NaNi1/3Co1/3Mn1/3O2 for Sodium Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Mechanism on Capacity Fading at Higher Charging Potential of NaNi_1/3Co_1/3Mn_1/3O₂ for Sodium Ion Batteries