Citation: ZHANG Yang, WANG Jian. Construction of Two Coordination Polymers Based on 5-Methoxyisophthalic Acid Ligand: Structures, Luminescence and Catalytic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 589-596. doi: 10.11862/CJIC.2018.073 shu

Construction of Two Coordination Polymers Based on 5-Methoxyisophthalic Acid Ligand: Structures, Luminescence and Catalytic Properties

ZHANG Yang ^, ,
WANG Jian

College of Chemical Engineering, Guangdong University of Petrochemical Technology, Maoming, Guangdong 525000, China

Corresponding author: ZHANG Yang, yangzhang79@126.com
Received Date: 11 October 2017
Revised Date: 20 November 2017

Figures(8)

Two new 1D cadmium/cobalt-based coordination polymers, {[Cd₂(CH₃O-ip)₂(ethanol)₂(H₂O)₄]·3H₂O}_n (1) and {[Co₂(CH₃O-ip)₂(dmbpy)(H₂O)₄]·H₂O·C₂H₃N}_n (2) (CH₃O-H₂ip=5-methoxyisophthalic acid, dmbpy=2, 2'-dimethyl -4, 4'-bipyridine, C₂H₃N=acetonitrile), were synthesized in mixed solvent and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis (TGA), powder X-ray diffraction and single-crystal X-ray diffraction. Both complexes are synthesized using dual linkers (CH₃O-H₂ip and dmbpy). Complex 1 is a wave-like chain and further connected into 2D network through O-H…O hydrogen bonds, whereas 2 shows a ladder chain and further linked into 3D supramolecular framework by O-H…O, O-H…N and C-H…O hydrogen bonds. Furthermore, the luminescence property of 1 and the catalytic degradation of methyl orange in a Fenton-like process of 1~2 are also investigated.
- coordination polymers,
- transition metals,
- crystal structure,
- hydrogen bonds,
- luminescent property,
- catalytic property
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