Citation: YANG Ming-Xing, LIU Yu-Qing, CEN Fu-Yan, CHEN Li-Juan, LIN Shen. Syntheses, Structures and Properties of 2D Metal-Organic Coordination Polymers Constructed from 5-Substituted Isophthalic Acid and Bis(imidazole) Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 569-578. doi: 10.11862/CJIC.2018.071 shu

Syntheses, Structures and Properties of 2D Metal-Organic Coordination Polymers Constructed from 5-Substituted Isophthalic Acid and Bis(imidazole) Ligands

College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

Corresponding author: LIN Shen, shenlin@fjnu.edu.cn
Received Date: 28 September 2017
Revised Date: 5 December 2017

Figures(16)

Two new metal-organic coordination polymers, [Co₂(1, 4-bib)₂(5-hipa)₂]_n (1) (5-H₂hipa=5-hydroxyisophth-alic acid, 1, 4-bib=1, 4-bis(1-imidazolyl)benzene), [Co(Hbpt)(4, 4'-bidpe)]_n (2) (H₃bpt=biphenyl-3, 4', 5-tricarboxylic acid, 4, 4'-bidpe=4, 4'-bis(imidazol-1-yl)diphenyl ether) were obtained under solvothermal conditions and chara-cterized structurally. The meta benzenedicarboxylates in 5-hipa^2- and Hbpt^2- connect the Co(Ⅱ) ions into 1D carboxylate-cobalt chain structures with 8-membered ring Co₂O₄C₂ and 16-membered Co₂O₄C₁₀ ring alternately. And the bis(imidazole) ligands further link the adjacent 1D carboxylate-cobalt chains to construct an interesting two-dimensional layered structure, respectively. The adjacent layers[Co₂(1, 4-bib)₂(5-hipa)₂] in complex 1 are linked with each other by hydrogen bonding to generate an interesting 3D supramolecular framework. While the hydrogen bonding only exits within the layers of 2. Furthermore, the complex 1/Vulcan XC-72R composite can catalyze the oxygen reduction reaction through a 2e/4e mixed reduction pathway.
- cobalt (Ⅱ) complex,
- 2D framework,
- ORR catalyst
1. [1]
  (a) Luo F, Yan C S, Dang L L, et al. J. Am. Chem. Soc., 2016, 138(17): 5678-5684
  (b)Suh M P, Park H J, Prasad T K, et al. Chem. Rev., 2012, 112(2): 782-835
  (c)Levine D J, Runčevski T, Kapelewski M T, et al. J. Am. Chem. Soc., 2016, 138(32): 10143-10150
2. [2]
  (a) Qin L, Chen H Z, Lei J, et al. Cryst. Growth Des., 2017, 17(3): 1293-1298
  (b)Jiang M, Li L J, Zhu D D, et al. J. Mater. Chem. A, 2014, 2(15): 5323-5329
3. [3]
  (a) Kreno L E, Leong K, Farha O K, et al. Chem. Rev., 2012, 112(2): 1105-1125
  (b)Lu Z Z, Zhang R, Li Y Z, et al. J. Am. Chem. Soc., 2011, 133(12): 4172-4174
4. [4]
  (a) Zeng M H, Yin Z, Tan Y X, et al. J. Am. Chem. Soc., 2014, 136(12): 4680-4688
  (b)DeGayner J A, Jeon I R, Sun L, et al. J. Am. Chem. Soc., 2017, 139(11): 4175-4184
5. [5]
  (a) Li Y L, Zhao Y, Kang Y S, et al. Cryst. Growth Des., 2016, 16(12): 7112-7123
  (b)Zhang X T, Fan L M, Zhang W, et al. CrystEngComm., 2014, 16(15): 3203-3213
  (c)Hu J S, Huang L F, Yao X Q, et al. Inorg. Chem., 2011, 50(6): 2404-2414
  (d)Zhao J, Dong W W, Wu Y P, et al. J. Mater. Chem. A, 2015, 3(13): 6962-6969
6. [6]
  (a) Hu J S, Shang Y J, Yao X Q, et al. Cryst. Growth Des., 2010, 10(9): 4135-4142
  (b)Yang G S, Lan Y Q, Zang H Y, et al. CrystEngComm, 2009, 11(2): 274-277
7. [7]
  Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement, Göttingen University, Germany, 1997.
8. [8]
  Ye L, Chai G L, Wen Z H. Adv. Funct. Mater., 2017, 27(14): 1606190 doi: 10.1002/adfm.v27.14
9. [9]
  Chen Y Z, Wang C M, Wu Z Y, et al. Adv. Mater., 2015, 27(34):5010-5016 doi: 10.1002/adma.201502315
10. [10]
  Xia W, Zhu J H, Guo W H, et al. J. Mater. Chem. A, 2014, 2(30):11606-11613 doi: 10.1039/C4TA01656D
11. [11]
  Wang X J, Fan X X, Lin H H, et al. RSC Adv., 2016, 6(44): 37965-37973 doi: 10.1039/C6RA04771H
12. [12]
  Xia W, Zou R Q, An L, et al. Energy Environ. Sci., 2015, 8(2):568-576 doi: 10.1039/C4EE02281E
13. [13]
  Wang X J, Zhou J W, Fu H, et al. J. Mater. Chem. A, 2014, 2(34):14064-14070 doi: 10.1039/C4TA01506A
14. [14]
  Song G Q, Wang Z Q, Wang L, et al. Chin. J. Catal., 2014, 35(2):185-195 doi: 10.1016/S1872-2067(12)60729-3
15. [15]
  Mao J J, Yang L F, Yu P, et al. Electrochem. Commun., 2012, 19:29-31 doi: 10.1016/j.elecom.2012.02.025
16. [16]
  Bard A J, Faulkner L R. Electrochemical Methods: Funda-mentals and Applications. New York: Wiley, 2001:341-342
17. [17]
  Su Y H, Jiang H L, Zhu Y H, et al J. Mater. Chem. A, 2014, 2(20):7281-7287 doi: 10.1039/C4TA00029C
18. [18]
  Su L, Jing Y, Zhou Z. Nanoscale, 2011, 3(10):3967-3983 doi: 10.1039/c1nr10550g
19. [19]
  Sun C W, Li F, Ma C, et al. J. Mater. Chem. A, 2014, 2(20): 7188-7196 doi: 10.1039/C4TA00802B
1. [1]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
2. [2]
  Lewang Yuan , Yaoyao Peng , Zong-Jie Guan , Yu Fang . Insights into the development of 2D covalent organic frameworks as photocatalysts in organic synthesis. Acta Physico-Chimica Sinica, 2025, 41(8): 100086-0. doi: 10.1016/j.actphy.2025.100086
3. [3]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
4. [4]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
5. [5]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . 缺陷态二维超薄材料用于光/电催化CO₂还原的基础与展望. Acta Physico-Chimica Sinica, 2025, 41(3): 2308052-. doi: 10.3866/PKU.WHXB202308052
6. [6]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
7. [7]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
8. [8]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
9. [9]
  Xichen YAO , Shuxian WANG , Yun WANG , Cheng WANG , Chuang ZHANG . Oxygen reduction performance of self?supported Fe/N/C three-dimensional aerogel catalyst layers. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1387-1396. doi: 10.11862/CJIC.20240384
10. [10]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
11. [11]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
12. [12]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
13. [13]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
14. [14]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
15. [15]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
16. [16]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
17. [17]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
18. [18]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
19. [19]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
20. [20]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(3079)
HTML views(865)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses, Structures and Properties of 2D Metal-Organic Coordination Polymers Constructed from 5-Substituted Isophthalic Acid and Bis(imidazole) Ligands

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com