Citation: YANG Ming-Xing, LIU Yu-Qing, CEN Fu-Yan, CHEN Li-Juan, LIN Shen. Syntheses, Structures and Properties of 2D Metal-Organic Coordination Polymers Constructed from 5-Substituted Isophthalic Acid and Bis(imidazole) Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(3): 569-578. doi: 10.11862/CJIC.2018.071 shu

Syntheses, Structures and Properties of 2D Metal-Organic Coordination Polymers Constructed from 5-Substituted Isophthalic Acid and Bis(imidazole) Ligands

College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

Corresponding author: LIN Shen, shenlin@fjnu.edu.cn
Received Date: 28 September 2017
Revised Date: 5 December 2017

Figures(16)

Two new metal-organic coordination polymers, [Co₂(1, 4-bib)₂(5-hipa)₂]_n (1) (5-H₂hipa=5-hydroxyisophth-alic acid, 1, 4-bib=1, 4-bis(1-imidazolyl)benzene), [Co(Hbpt)(4, 4'-bidpe)]_n (2) (H₃bpt=biphenyl-3, 4', 5-tricarboxylic acid, 4, 4'-bidpe=4, 4'-bis(imidazol-1-yl)diphenyl ether) were obtained under solvothermal conditions and chara-cterized structurally. The meta benzenedicarboxylates in 5-hipa^2- and Hbpt^2- connect the Co(Ⅱ) ions into 1D carboxylate-cobalt chain structures with 8-membered ring Co₂O₄C₂ and 16-membered Co₂O₄C₁₀ ring alternately. And the bis(imidazole) ligands further link the adjacent 1D carboxylate-cobalt chains to construct an interesting two-dimensional layered structure, respectively. The adjacent layers[Co₂(1, 4-bib)₂(5-hipa)₂] in complex 1 are linked with each other by hydrogen bonding to generate an interesting 3D supramolecular framework. While the hydrogen bonding only exits within the layers of 2. Furthermore, the complex 1/Vulcan XC-72R composite can catalyze the oxygen reduction reaction through a 2e/4e mixed reduction pathway.
- cobalt (Ⅱ) complex,
- 2D framework,
- ORR catalyst
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