Citation: DONG Xiu-Yan, GAO Lei, WANG Fei, ZHANG Yang, DONG Wen-Kui. Tetranuclear Copper(Ⅱ) and Zinc(Ⅱ) Complexes Constructed from an Asymmetrical Salamo-Type N₂O₃ Donor Ligand: Syntheses, Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 739-749. doi: 10.11862/CJIC.2018.070 shu

Tetranuclear Copper(Ⅱ) and Zinc(Ⅱ) Complexes Constructed from an Asymmetrical Salamo-Type N₂O₃ Donor Ligand: Syntheses, Structures and Fluorescence Properties

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: DONG Wen-Kui, dongwk@126.com
Received Date: 30 August 2017
Revised Date: 15 December 2017

Figures(8)

Two newly designed tetranuclear complexes, {Cu(L)(OAc)Cu(H₂O)}₂ (1) and {Zn(L)(OAc)Zn(H₂O)}₂ (2) derived from an Salamo-type N₂O₃ donor ligand (H₃L) were synthesized and characterized by elemental analyses, IR and UV-Vis spectra, fluorescence spectra and X-ray crystallography. Complex 1 is made up of four Cu(Ⅱ) ions, two deprotonated L^3- moieties, two coordinated water molecules and two μ₂-acetate ions. All of the Cu(Ⅱ) ions in 1 are penta-coordinated with slightly distorted tetragonal pyramidal and trigonal bipyramidal symmetries. Complex 1 forms an infinite 1D chain supramolecular structure via C-H…π interactions. Complex 2 reveals an asymmetrical tetranuclear structure, and consists of four Zn(Ⅱ) ions, two completely deprotonated L^3- units, two μ₂-acetate ions and two coordinated water molecules, which possesses an infinite 3D supramolecular structure. The fluorescent properties of H₃L and complexes 1 and 2 have also been discussed.
- Salamo-type N₂O₃ donor ligand,
- complex,
- synthesis,
- crystal structure,
- fluorescence property
1. [1]
  Dong W K, Lan P F, Zhou W M, et al. J. Coord. Chem., 2016, 65:1272-1283
2. [2]
  Dong X Y, Akogun S F, Zhou W M, et al. J. Chin. Chem. Soc., 2017, 64:412-419 doi: 10.1002/jccs.2017.64.issue-4
3. [3]
  Tao C H, Ma J C, Zhu L C, et al. Polyhedron, 2017, 128:38-45 doi: 10.1016/j.poly.2017.02.040
4. [4]
  Dong Y J, Dong X Y, Dong W K, et al. Polyhedron, 2017, 123:305-315 doi: 10.1016/j.poly.2016.12.010
5. [5]
  Dong W K, Ma J C, Dong Y J, et al. J. Coord. Chem., 2016, 69:3231-3241 doi: 10.1080/00958972.2016.1231302
6. [6]
  Wu H L, Wang C P, Wang F, et al. J. Chin. Chem. Soc., 2015, 62:1028-1034 doi: 10.1002/jccs.v62.11
7. [7]
  Wu H L, Bai Y C, Zhang Y H, et al. J. Coord. Chem., 2014, 67:3054-3066 doi: 10.1080/00958972.2014.959507
8. [8]
  Wu H L, Bai Y, Yuan J K, et al. J. Coord. Chem., 2012, 65:2839-2851 doi: 10.1080/00958972.2012.707314
9. [9]
  Wu H L, Pan G L, Bai Y C, et al. J. Photochem. Photobiol. B, 2014, 135:33-43 doi: 10.1016/j.jphotobiol.2014.04.005
10. [10]
  Wu H L, Bai Y C, Zhang Y H, et al. Z. Anorg. Allg. Chem., 2014, 640:2062-2071 doi: 10.1002/zaac.v640.10
11. [11]
  Wu H L, Pan G L, Bai Y C, et al. J. Chem. Res., 2014, 38:211-217 doi: 10.3184/174751914X13933417974082
12. [12]
  Wu H L, Pan G L, Bai Y C, et al. Res. Chem. Intermed., 2015, 41:3375-3388 doi: 10.1007/s11164-013-1440-5
13. [13]
  Chen C Y, Zhang J W, Zhang Y H, et al. J. Coord. Chem., 2015, 68:1054-1071 doi: 10.1080/00958972.2015.1007965
14. [14]
  Dong W K, Ma J C, Zhu L C, et al. Inorg. Chim. Acta, 2016, 445:140-148 doi: 10.1016/j.ica.2016.02.043
15. [15]
  Chai L Q, Zhang K Y, Tang L J, et al. Polyhedron, 2017, 130:100-107 doi: 10.1016/j.poly.2017.04.010
16. [16]
  Yu T Z, Zhang K, Zhao Y L, et al. Inorg. Chim. Acta, 2008, 361:233-240 doi: 10.1016/j.ica.2007.07.012
17. [17]
  Dong Y J, Ma J C, Zhu L C, et al. J. Coord. Chem., 2017, 70:103-115 doi: 10.1080/00958972.2016.1262537
18. [18]
  Wang L, Ma J C, Dong W K, et al. Z. Anorg. Allg. Chem., 2016, 642:834-839 doi: 10.1002/zaac.v642.15
19. [19]
  Dong W K, Chen X, Sun Y X, et al. Spectrochim. Acta Part A, 2009, 74:719-725 doi: 10.1016/j.saa.2009.08.037
20. [20]
  Dong W K, Li G, Wang Z K, et al. Spectrochim. Acta Part A, 2014, 133:340-347 doi: 10.1016/j.saa.2014.04.190
21. [21]
  Liu Y A, Wang C Y, Zhang M, et al. Polyhedron, 2017, 127:278-286 doi: 10.1016/j.poly.2017.02.007
22. [22]
  Dong W K, Ma J C, Dong Y J, et al. Polyhedron, 2016, 115:228-235 doi: 10.1016/j.poly.2016.05.017
23. [23]
  Song X Q, Liu P P, Xiao Z R, et al. Inorg. Chim. Acta, 2015, 438:232-244 doi: 10.1016/j.ica.2015.09.022
24. [24]
  Liu P P, Wang C Y, Zhang M, et al. Polyhedron, 2017, 129:133-140 doi: 10.1016/j.poly.2017.03.019
25. [25]
  Dong W K, Ma J C, Zhu L C, et al. New J. Chem., 2016, 40:6998-7010 doi: 10.1039/C6NJ00855K
26. [26]
  Dong W K, Ma J C, Zhu L C, et al. Cryst. Growth Des., 2016, 16:6903-6914 doi: 10.1021/acs.cgd.6b01067
27. [27]
  Chen L, Dong W K, Zhang H, et al. Cryst. Growth Des., 2017, 17:3636-3648 doi: 10.1021/acs.cgd.6b01860
28. [28]
  Song X Q, Peng Y J, Chen G Q, et al. Inorg. Chim. Acta, 2015, 427:13-21 doi: 10.1016/j.ica.2014.12.008
29. [29]
  Dong W K, Zhang J, Zhang Y, et al. Inorg. Chem. Acta, 2016, 444:95-102 doi: 10.1016/j.ica.2016.01.034
30. [30]
  Dong W K, Akogun S F, Zhang Y, et al. Sens. Actuators B:Chem., 2017, 238:723-734 doi: 10.1016/j.snb.2016.07.047
31. [31]
  Dong Y J, Li X L, Zhang Y, et al. Supramol. Chem., 2017, 29:518-527 doi: 10.1080/10610278.2017.1285031
32. [32]
  Dong W K, Li X L, Wang L, et al. Sens. Actuators B:Chem., 2016, 229:370-378 doi: 10.1016/j.snb.2016.01.139
33. [33]
  Zhao L, Dang X T, Chen Q, et al. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2013, 43:1241-1246 doi: 10.1080/15533174.2012.757236
34. [34]
  Sun Y X, Xu L, Zhao T H, et al. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2013, 43:509-513 doi: 10.1080/15533174.2012.740756
35. [35]
  SUN Yin-Xia, DONG Wen-Kui, WANG Li, et al. Chinese J. Inorg. Chem., 2009, 25:1478-1482 doi: 10.3321/j.issn:1001-4861.2009.08.028
36. [36]
  Sun Y X, Zhang S T, Ren Z L, et al. Synth. React. Inorg. Met.-Org. Nano-Met Chem., 2013, 43:995-1000 doi: 10.1080/15533174.2012.753614
37. [37]
  DONG Wen-Kui, ZHANG Xin-Ying, ZHAO Meng-Meng, et al. Chinese J. Inorg. Chem., 2014, 30:710-716
38. [38]
  Dong W K, Duan J G, Guan Y H, et al. Inorg. Chim. Acta, 2009, 362:1129-1134 doi: 10.1016/j.ica.2008.05.028
39. [39]
  Dong W K, Sun Y X, Zhang Y P, et al. Inorg. Chim. Acta, 2009, 362:117-124 doi: 10.1016/j.ica.2008.03.128
40. [40]
  Dong W K, He X N, Yan H B, et al. Polyhedron, 2009, 28:1419-1428 doi: 10.1016/j.poly.2009.03.017
41. [41]
  Dong W K, Zhu L C, Dong Y J, et al. Polyhedron, 2016, 117:148-154 doi: 10.1016/j.poly.2016.05.055
42. [42]
  Dong W K, Zhang X Y, Sun Y X, et al. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2015, 45:956-962 doi: 10.1080/15533174.2013.862814
43. [43]
  Dong Y, Li F J, Jiang X X, et al. Org. Lett., 2011, 9:2252-2255
44. [44]
  Dong W K, Wang Z K, Li G, et al. Z. Anorg. Allg. Chem., 2013, 639:2263-2268 doi: 10.1002/zaac.v639.12/13
45. [45]
  Dong W K, Feng J H, Yang X Q, et al. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2007, 37:189-192 doi: 10.1080/15533170701301587
46. [46]
  Ma J C, Dong X Y, Dong W K, et al. J. Coord. Chem., 2016, 69:149-159 doi: 10.1080/00958972.2015.1108410
47. [47]
  SAINT-Plus, Ver. 6. 02, Bruker Analytical X-ray System, Madison, WI, 1999.
48. [48]
  Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Detector Data, University of Göttingen, Germany, 1996.
49. [49]
  Sheldrick G M. Acta Crystallogr. Sect. C:Cryst. Struct. Commun., 2015, C71:3-8
50. [50]
  Addison A W, Rao T N, Reedijk J, et al. J. Chem. Soc. Dalton Trans., 1984:1349-1356
51. [51]
  Konno T, Tokuda K, Sakurai J, et al. Bull. Chem. Soc. Jpn., 2000, 73:2767-2773 doi: 10.1246/bcsj.73.2767
52. [52]
  Chai L Q, Tang L J, Chen L C, et al. Polyhedron, 2017, 122:228-240 doi: 10.1016/j.poly.2016.11.032
53. [53]
  Xu L, Zhu L C, Ma J C, et al. Z. Anorg. Allg. Chem., 2015, 641:2520-2524 doi: 10.1002/zaac.201500619
54. [54]
  Wang P, Zhao L. Synth. React. Inorg. Met-Org. Nano-Met Chem., 2016, 46:1095-1101 doi: 10.1080/15533174.2015.1004416
55. [55]
  Wang P, Zhao L. Spectrochim. Acta Part A, 2015, 135:342-350 doi: 10.1016/j.saa.2014.06.129
56. [56]
  Sun Y X, Gao X H. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2011, 41:973-978 doi: 10.1080/15533174.2011.591329
57. [57]
  Chai L Q, Liu G, Zhang Y L, et al. J. Coord. Chem., 2013, 66:3926-3938 doi: 10.1080/00958972.2013.857016
58. [58]
  Chai L Q, Huang J J, Zhang J Y, et al. J. Coord. Chem., 2015, 68:1224-1237 doi: 10.1080/00958972.2015.1019875
59. [59]
  Sun Y X, Wang L, Dong X Y, et al. Synth. React. Inorg. Met-Org. Nano-Met Chem., 2013, 43:599-603 doi: 10.1080/15533174.2012.751424
60. [60]
  Wang P, Zhao L. Asian J. Chem., 2015, 4:1424-1426
61. [61]
  Song X Q, Cheng G Q, Liu Y A. Inorg. Chim. Acta, 2016, 450:386-394 doi: 10.1016/j.ica.2016.06.028
62. [62]
  Liu P P, Sheng L, Song X Q, et al. Inorg. Chim. Acta, 2015, 434:252-257 doi: 10.1016/j.ica.2015.05.026
63. [63]
  Dong W K, Zhang F, Li N. Z. Anorg. Allg. Chem., 2016, 642:532-538 doi: 10.1002/zaac.v642.7
64. [64]
  Dong W K, Zhang L S, Sun Y X, et al. Spectrochim. Acta Part A, 2014, 121:324-329 doi: 10.1016/j.saa.2013.10.072
65. [65]
  Hao J, Li L H, Zhang J T, et al. Polyhedron, 2017, 134:1-10 doi: 10.1016/j.poly.2017.05.060
66. [66]
  Li L H, Dong W K, Zhang Y, et al. Appl. Organomet. Chem., 2013, 27:337-340 doi: 10.1002/aoc.v27.6
67. [67]
  Wang B J, Dong W K, Zhang Y, et al. Sens. Actuators B:Chem., 2017, 247:254-264 doi: 10.1016/j.snb.2017.02.154
68. [68]
  Akine S, Morita Y, Utsuno F, et al. Inorg. Chem., 2009, 48:10670-10678 doi: 10.1021/ic901372k
69. [69]
  Song X Q, Liu P P, Liu Y A, et al. Dalton Trans., 2016, 45:8154-8163 doi: 10.1039/C6DT00212A
70. [70]
  Guo C Y, Wang Y Y, Xu K Z, et al. Polyhedron, 2008, 27:3529-3536 doi: 10.1016/j.poly.2008.08.018
71. [71]
  Che G B, Liu C B, Liu B, et al. CrystEngCommun, 2008, 10:184-191 doi: 10.1039/B712015J
1. [1]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
2. [2]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
3. [3]
  Liping GUO . Synthesis and crystal structure characterization of yttrium imido complex: The reactivity of 2-substituted-1-amino-o-carborane with yttrium dialkyl complex. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1409-1415. doi: 10.11862/CJIC.20250065
4. [4]
  Jiarong ZHU , Xiaohua ZHANG , Xinting XIONG , Xuliang NIE , Xiuying SONG , Miaomiao ZHANG , Dayong PENG , Xiuguang YI . Crystal structure, Hirshfeld surface analysis, and antifungal activity of five complexes based on 2,5-bis(carboxymethoxy)terephthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2358-2370. doi: 10.11862/CJIC.20250150
5. [5]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
6. [6]
  Zihe SONG , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Crystal structure, thermal analysis, and luminescence properties of six heterocyclic lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 181-192. doi: 10.11862/CJIC.20250126
7. [7]
  Xiaoling WANG , Hongwu ZHANG , Daofu LIU . Synthesis, structure, and magnetic property of a cobalt(Ⅱ) complex based on pyridyl-substituted imino nitroxide radical. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 407-412. doi: 10.11862/CJIC.20240214
8. [8]
  Yinxia SUN , Liping LIU , Xue BAI , Yu SUN , Wanhong SUN , Zhepeng DENG , Jianghai CHEN , Jianjun WANG , Li XU , Shuzhen ZHANG . Synthesis and crystal structures of Co(Ⅱ)/Cu(Ⅱ) coordination polymers based on solvent and ligand concentration regulation strategy. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 340-354. doi: 10.11862/CJIC.20250226
9. [9]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
10. [10]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
11. [11]
  Yingyue ZHANG , Liuqing KANG , Yating YANG , Xiaofen GUAN , Wenmin WANG . Crystal structure and antibacterial activity of two Gd₂ complexes based on polydentate Schiff-base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1867-1877. doi: 10.11862/CJIC.20250100
12. [12]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
13. [13]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
14. [14]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
15. [15]
  Ruiyan CHEN , Yanping HE , Jian ZHANG . Synthesis and third-order nonlinear optical property of Ti₄L₆ cage-based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2149-2156. doi: 10.11862/CJIC.20250177
16. [16]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
17. [17]
  Weizhong LING , Jingyi LIN , Jianglin ZHU , Yuyi LIANG , Shanshan DAI , Yu LI . Syntheses, structures, and catalytic performances of complexes with 4,4′-dihydroxy-[1,1′-biphenyl]-3,3′-dicarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 152-160. doi: 10.11862/CJIC.20250204
18. [18]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
19. [19]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
20. [20]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(682)
HTML views(97)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Tetranuclear Copper(Ⅱ) and Zinc(Ⅱ) Complexes Constructed from an Asymmetrical Salamo-Type N2O3 Donor Ligand: Syntheses, Structures and Fluorescence Properties

Metrics

通讯作者: 陈斌, bchen63@163.com

Tetranuclear Copper(Ⅱ) and Zinc(Ⅱ) Complexes Constructed from an Asymmetrical Salamo-Type N₂O₃ Donor Ligand: Syntheses, Structures and Fluorescence Properties