Citation: DONG Xiu-Yan, GAO Lei, WANG Fei, ZHANG Yang, DONG Wen-Kui. Tetranuclear Copper(Ⅱ) and Zinc(Ⅱ) Complexes Constructed from an Asymmetrical Salamo-Type N₂O₃ Donor Ligand: Syntheses, Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(4): 739-749. doi: 10.11862/CJIC.2018.070 shu

Tetranuclear Copper(Ⅱ) and Zinc(Ⅱ) Complexes Constructed from an Asymmetrical Salamo-Type N₂O₃ Donor Ligand: Syntheses, Structures and Fluorescence Properties

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China

Corresponding author: DONG Wen-Kui, dongwk@126.com
Received Date: 30 August 2017
Revised Date: 15 December 2017

Figures(8)

Two newly designed tetranuclear complexes, {Cu(L)(OAc)Cu(H₂O)}₂ (1) and {Zn(L)(OAc)Zn(H₂O)}₂ (2) derived from an Salamo-type N₂O₃ donor ligand (H₃L) were synthesized and characterized by elemental analyses, IR and UV-Vis spectra, fluorescence spectra and X-ray crystallography. Complex 1 is made up of four Cu(Ⅱ) ions, two deprotonated L^3- moieties, two coordinated water molecules and two μ₂-acetate ions. All of the Cu(Ⅱ) ions in 1 are penta-coordinated with slightly distorted tetragonal pyramidal and trigonal bipyramidal symmetries. Complex 1 forms an infinite 1D chain supramolecular structure via C-H…π interactions. Complex 2 reveals an asymmetrical tetranuclear structure, and consists of four Zn(Ⅱ) ions, two completely deprotonated L^3- units, two μ₂-acetate ions and two coordinated water molecules, which possesses an infinite 3D supramolecular structure. The fluorescent properties of H₃L and complexes 1 and 2 have also been discussed.
- Salamo-type N₂O₃ donor ligand,
- complex,
- synthesis,
- crystal structure,
- fluorescence property
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Tetranuclear Copper(Ⅱ) and Zinc(Ⅱ) Complexes Constructed from an Asymmetrical Salamo-Type N2O3 Donor Ligand: Syntheses, Structures and Fluorescence Properties

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通讯作者: 陈斌, bchen63@163.com

Tetranuclear Copper(Ⅱ) and Zinc(Ⅱ) Complexes Constructed from an Asymmetrical Salamo-Type N₂O₃ Donor Ligand: Syntheses, Structures and Fluorescence Properties