Citation: CAO Jiao-Lan, WANG Xi-Gui. Preparation and Luminescent Properties of Eu³⁺ Doped B₂O₃-CaO Luminescent Materials[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 325-330. doi: 10.11862/CJIC.2018.066 shu

Preparation and Luminescent Properties of Eu³⁺ Doped B₂O₃-CaO Luminescent Materials

CAO Jiao-Lan ,
WANG Xi-Gui ^,

College of Chemistry and Environment Science, Inner Mongolia Normal University, Hohhot 010022, China

Corresponding author: WANG Xi-Gui, wangxg@imnu.edu.cn
Received Date: 31 July 2017
Revised Date: 29 November 2017

Figures(6)

The high pure B₂O₃-CaO:Eu³⁺ phosphor is prepared by sol-gel method. The structures of samples obtained at different annealing temperatures are characterized by XRD and IR. It is found that the borate matrix with different structures can be formed with the change of annealing temperature. Based on the analysis of the excitation spectrum, emission spectrum and fluorescence decay curves of borate phosphors with different structures, the luminescent properties and luminescent mechanism of the phosphors are investigated. The result indicate that Eu³⁺ ions occupy no inversion symmetry site with the dominant electric dipole transition in borate matrix of the different structure, and these phosphors give off red light under ultraviolet excitation. The high pure CaB₂O₄ matrix obtained by annealing at 900℃ is most favorable for luminescence and the B₂O₃-CaO:Eu³⁺ phosphor have the longest fluorescence decay time. These are attributed to the fact that Eu³⁺ in the matrix is more likely to replace Ca²⁺ to form relatively large numbers of p-n junctions and traps.
- sol-gel,
- Eu³⁺ doped B₂O₃-CaO,
- luminescent properties,
- luminescent mechanism
1. [1]
  XIA Li-Bin, XIAO Qing-Hui, LI Zi-Cheng, et al. Chinese J. Inorg. Chem., 2017, 33(5):753-760 doi: 10.11862/CJIC.2017.103
2. [2]
  FENG Yong-An, LEI Xiao-Hua, REN Lin-Jiao, et al. Chinese Journal of Luminescence, 2013, 34(3):303-307
3. [3]
  GU Lu-Shun, SHI Nan, ZHANG Le, et al. Chinese Journal of Luminescence, 2014, 35(8):897-904
4. [4]
  Yang H C, Lakshminarayana G, Zhou S F, et al. Opt. Exp., 2008, 16(9):6731-6735 doi: 10.1364/OE.16.006731
5. [5]
  Zhu Z F, Zhang Y B, Qiao Y P, et al. J. Non-Cryst. Solids, 2012, 358:1550-1553 doi: 10.1016/j.jnoncrysol.2012.04.015
6. [6]
  QI Shu-Yun. Thesis for the Master of Soochow University. 2016.
7. [7]
  Sun X Y, Zhang J C, Liu X G, et al. Physica B, 2011, 406:4089-4093 doi: 10.1016/j.physb.2011.07.057
8. [8]
  Huang J L, Zhou L Y, Pang Q, et al. Luminescence, 2009, 24:363-366 doi: 10.1002/bio.v24:6
9. [9]
  HUANG Hong-Sheng, JIN Hua-Feng, YUAN Guang-Hui, et al. Chinese Journal of Luminescence, 2014, 35(10):1176-1181
10. [10]
  Kindrat I I, Padlyak B V, Lisiecki R. Opt. Mater., 2015, 49:241-248 doi: 10.1016/j.optmat.2015.09.024
11. [11]
  WANG Hai-Ying, WANG Ru-Ji, ZHANG Yue, et al. J. Inorg. Mater., 2009, 19(6):1367-1372
12. [12]
  WANG Xiao-Fang, ZHANG Chi, DENG Chao -Yong. Chinese Journal of Luminescence, 2016, 37(9):1037-1042
13. [13]
  WANG Xi-Gui, BO Su-Ling, QI Xia, et al. Chinese J. Inorg. Chem., 2009, 25(2):350-353
14. [14]
  Qiao X, Seo H J. Mater. Res. Bull., 2014, 49(1):76-82
15. [15]
  WANG Xi-Gui, YU Zhen-You, NA Mi-La, et al. Chinese J. Inorg. Chem., 2008, 24(4):571-575
16. [16]
  WANG Ling-Li, WANG Yu-Hua. Journal of the Chinese Rare Earth Society, 2004, 22(6):863-866
17. [17]
  WANG Xi-Gui, BO Su-Ling, NA Mi-La, et al. Spectroscopy and Spectral Analysis, 2010, 30(1):22-25
18. [18]
  Zeng Q H, Pei Z W, Wang S B, et al. Spectrosc. Lett., 1999, 32(6):895-912 doi: 10.1080/00387019909350036
19. [19]
  Shi M M, Zhang D Y, Chang C K, et al. J. Alloys Compd., 2015, 639:168-172 doi: 10.1016/j.jallcom.2015.02.068
20. [20]
  Fujimoto Y, Yanagida T, Kawaguchi N, et al. Cryst. Growth Des., 2012, 12:142-146 doi: 10.1021/cg200885h
21. [21]
  Yang L, Wan Y P, Li Y Z, et al. J. Nanopart. Res., 2016, 18:94 doi: 10.1007/s11051-016-3372-7
22. [22]
  Manhas M, Kumar V, Agarwal G. Indian J. Phys., 2015, 89(9):899-906 doi: 10.1007/s12648-015-0657-0
23. [23]
  YANG Yang, CONG Yan, ZHU Zi-Mao, et al. Chinese J. Inorg. Chem., 2017, 33(10):1757-1762 doi: 10.11862/CJIC.2017.235
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Preparation and Luminescent Properties of Eu³⁺ Doped B₂O₃-CaO Luminescent Materials