Citation: WANG Dan, LIU Li-Lai, LI Ming-Xian, PAN Xiao-Na, ZHAO Yan-Hong, ZHANG Jin-Qiu, AN Mao-Zhong, YANG Pei-Xia. Preparation of Platinum Nanoparticles via Electrochemical Method in N, N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate Ionic Liquid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 409-414. doi: 10.11862/CJIC.2018.045 shu

Preparation of Platinum Nanoparticles via Electrochemical Method in N, N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate Ionic Liquid

1.
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
2.
College of Environmental and Chemical Engineering, Heilongjiang University of Science and Technology, Harbin 150022, China
3.
Shenzhen BAK Power Battery Co., Ltd., Shenzhen, Guangdong 518119, China

Corresponding author: YANG Pei-Xia, yangpeixia@hit.edu.cn
Received Date: 12 September 2017
Revised Date: 5 November 2017

Figures(7)

Platinum nanoparticles were prepared via a potentiostatic electrodeposition method on a glassy carbon electrode from N, N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium tetrafluoroborate ([DEME] [BF₄]) ionic liquid. At first, the effects of different deposition potentials and deposition times on the micromorphology of platinum nanoparticles were investigated. It has been found that the mean size of Pt nanoparticles obtained at -2.5 V for 480 s was estimated to be ca. 2.38 nm from the SEM and TEM images. Its face-centered cubic (fcc) crystal structure was confirmed by high-resolution transmission electron microscopy (HRTEM) and electron diffraction (SAED). At the same time, Platinum nanoparticles exposed significant (110) and (100) planes in sulfuric acid. Further study of the deposition behavior of platinum reveals that the diffusion process and the electrochemical process controll the two-step reduction of Pt(Ⅳ) together.
- ionic liquid,
- Pt,
- electrodeposition,
- fuel cell
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1.
沈阳化工大学材料科学与工程学院沈阳 110142