Citation: ZHANG Shu-Quan, ZHANG Jian-Han, GU Jia-Fang. Four Cadmium-Organic Coordination Polymers: Influence of Secondary Ligands to Crystal Structure and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 237-246. doi: 10.11862/CJIC.2018.039 shu

Four Cadmium-Organic Coordination Polymers: Influence of Secondary Ligands to Crystal Structure and Luminescent Properties

1.
Zhicheng College, Fuzhou University, Fuzhou 350002, China
2.
School of Resources and Chemical Engineering, Sanming University, Sanming, Fujian 365004, China

Corresponding author: ZHANG Shu-Quan, sqzhang@fzu.edu.cn
Received Date: 7 August 2017
Revised Date: 30 November 2017

Figures(6)

Four cadmium-organic coordination polymers, namely[Cd(Hncpoi)(2, 2'-bpy)(H₂O)]_n (1), {[Cd₂(Hncpoi)₂(bpyp)(H₂O)₄]·3H₂O}_n (2), {[Cd₂(Hncpoi)₂(azpy)(H₂O)₂]·2H₂O}_n (3), {[Cd₂(Hncpoi)₂(dpe)(H₂O)₂]·2H₂O}_n (4), have been solvothermally constructed from multi-carboxylic organic ligand 5-(2-Nitro-4-carboxyphenoxy)-isophthalic acid(H₃ncpoi), Cd²⁺ ions, and different auxiliary ligands:2, 2'-bipyridyl(2, 2'-bpy), 1, 4-bis-(4-pyridylmethyl)piperazine(bpyp), 4, 4'-azopyridine (azpy) and 1, 2-di(4-pyridyl)ethylene(dpe), respectively. These complexes were further characterized by single-crystal X-ray diffraction, PXRD, elemental analysis, and TG. Single-crystal X-ray diffraction showed that complexes 1 and 2 exhibit 1D chain-like structure, and complexes 3 and 4 are 2D (4, 4) grid layered structure. 1D chains or 2D layers of these complexes further assemble to 3D supramolecular architectures via intermolecular interactions. The coordination modes and configurations of secondary ligands have a crucial influence to the crystal structures of these complexes. Meanwhile, the photoluminescent properties of these complexes were also studied. The results showed that there are close relationship between the secondary ligands and photoluminescence properties of these coordination polymers.
- coordination polymer,
- crystal structure,
- photoluminescence spectrum,
- secondary ligand
1. [1]
  Ma L, Falkowski J M, Abney C, et al. Nat. Chem., 2010, 2:838-846 doi: 10.1038/nchem.738
2. [2]
  Lu W, Wei Z, Gu Z Y, et al. Chem. Soc. Rev., 2014, 43:5561-5593 doi: 10.1039/C4CS00003J
3. [3]
  Hu T L, Wang H, Li B, et al. Nat. Commun., 2015, 6:7328 doi: 10.1038/ncomms8328
4. [4]
  Dau P V, Kim M, Cohen S M. Chem. Sci., 2013, 4:601-605 doi: 10.1039/C2SC21289G
5. [5]
  Liu J, Bao T Y, Yang X Y, et al. Chem. Commun., 2017, 53:7804-7807 doi: 10.1039/C7CC03673F
6. [6]
  Bobbitt N S, Mendonca M L, Howarth A J, et al. Chem. Soc. Rev., 2017, 46:3357-3385 doi: 10.1039/C7CS00108H
7. [7]
  Wang L, Han Y, Feng X, et al. Coord. Chem. Rev., 2016, 307:361-381 doi: 10.1016/j.ccr.2015.09.002
8. [8]
  Singh D, Nagaraja C M. Cryst. Growth Des., 2015, 15:3356-3365 doi: 10.1021/acs.cgd.5b00450
9. [9]
  Zhan G, Zhong W, Wei Z, et al. Dalton Trans., 2017, 46:8286-8297 doi: 10.1039/C7DT01716B
10. [10]
  Zhang J Y, Shi J X, Chen L Y, et al. CrystEngComm, 2017, 19:1738-1750 doi: 10.1039/C7CE00046D
11. [11]
  Farha O K, Malliakas C D, Kanatzidis M G, et al. J. Am. Chem. Soc., 2010, 132:950-952 doi: 10.1021/ja909519e
12. [12]
  Seo J, Matsuda R, Sakamoto H, et al. J. Am. Chem. Soc., 2009, 131:12792-12800 doi: 10.1021/ja904363b
13. [13]
  Maji T K, Uemura K, Chang H C, et al. Angew. Chem., 2004, 116:3331-3334 doi: 10.1002/(ISSN)1521-3757
14. [14]
  Su S, Wang S, Song X, et al. Dalton Trans., 2012, 41:4772-4779 doi: 10.1039/c2dt12346k
15. [15]
  Liu G Z, Li X L, Xin L Y, et al. CrystEngComm, 2012, 14:5315-5321 doi: 10.1039/c2ce25556a
16. [16]
  Zhao S N, Su S Q, Song X Z, et al. Cryst. Growth Des., 2013, 13:2756-2765 doi: 10.1021/cg3018387
17. [17]
  WANG Da-Wei, WANG Tao, YAN Long, et al. Chinese J. Inorg. Chem., 2017, 33(8):1443-1449 doi: 10.11862/CJIC.2017.185
18. [18]
  LIANG Rui, WANG Yu-Ting, GUO Yong-Kang, et al. Chinese J. Inorg. Chem., 2017, 33(8):1465-1473 doi: 10.11862/CJIC.2017.154
19. [19]
  Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
20. [20]
  Chen X L, Zhang B, Hu H M, et al. Cryst. Growth Des., 2008, 8:3706-3712 doi: 10.1021/cg8003257
21. [21]
  Wang X L, Qin C, Wang E B, et al. Chem. Eur. J., 2006, 12:2680-2691 doi: 10.1002/(ISSN)1521-3765
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1.
沈阳化工大学材料科学与工程学院沈阳 110142