Citation: XU Zhi-Hong, WU Wei-Na, LIU Shu-Yang, KOU Kai, WANG Yuan. Crystal Structures and Fluorescence Property of Zn(Ⅱ)/Cd(Ⅱ) Complexes Based on N-((quinolin-8-yl)methylene)acetohydrazide[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(2): 375-380. doi: 10.11862/CJIC.2018.032 shu

Crystal Structures and Fluorescence Property of Zn(Ⅱ)/Cd(Ⅱ) Complexes Based on N-((quinolin-8-yl)methylene)acetohydrazide

XU Zhi-Hong ¹ ,
WU Wei-Na ^2,, ,
LIU Shu-Yang ² ,
KOU Kai ² ,
WANG Yuan ^2,,

1.
Key Laboratory of Chemo/Biosensing and Detection, School of Chemistry and Chemical Engineering, Xuchang University, Xuchang, Henan 461000, China
2.
College of Chemistry and Chemical Engineering, Henan Key Laboratory of Coal Green Conversion, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: WU Wei-Na, wuwn08@hpu.edu.cn WANG Yuan, wangyuan08@hpu.edu.cn
Received Date: 21 July 2017
Revised Date: 11 November 2017

Figures(4)

Three complexes, namely {[Zn(HL)(H₂O)(SO₄)]·H₂O}_n (1), [Cd(HL)Cl₂] (2) and[Cd(HL)I₂] (3) (HL=N-((quinolin-8-yl)methylene)acetohydrazide) have been synthesized and characterized by single crystal X-ray diffraction, elemental analysis and IR spectroscopy. X-ray diffraction analysis results show that in complex 1, the Zn(Ⅱ) ion with a distorted octahedron coordination geometry is six-coordinated, involving one coordinated water molecule, one ONN donor set of an neutral ligand HL, and two O atoms from two independent μ₂-bridged sulfate anions, thus forming one dimension chain-like framework along b axis. However, the coordination geometry of the Cd(Ⅱ) ion in each of complexes 2 and 3 is a distorted square planar geometry with a tridentate acylhydrazone ligand and two halide anions (chloride for 2, while iodide for 3). In CH₃CN solution, the ligand HL and complex 3 exhibit almost none fluorescence emission, whilst complexes 1 and 2 show remarkable peaks at about 428 and 408 nm, respectively.
- acylhydrazone,
- Zn(Ⅱ) complex,
- Cd(Ⅱ) complex,
- quinoline,
- fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142