Citation: SHI Jie, CHENG Wei-Wei, ZHENG Lei, XU Yan. Formation of 2D Organic Templated Lanthanide Sulfates Induced by Second Structural Directing Agent[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2083-2094. doi: 10.11862/CJIC.2017.253 shu

Formation of 2D Organic Templated Lanthanide Sulfates Induced by Second Structural Directing Agent

SHI Jie ¹ ,
CHENG Wei-Wei ² ,
ZHENG Lei ¹ ,
XU Yan ^1,,

1.
College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China
2.
School of Chemistry and Bioengineering, Nanjing Normal University Taizhou College, Taizhou, Jiangsu 225300, China

Corresponding author: XU Yan, yanxu@njtech.edu.cn
Received Date: 1 June 2017
Revised Date: 11 September 2017

Figures(11)

Extra-large-pore and layered organically templated lanthanide sulfates have been prepared under solvothermal conditions. The extra-large-pore lanthanide sulfates, with the composition [(CH₃)₂NH₂]₉[Pr₅(SO₄)₁₂]·2H₂O (1), exhibit an interestingly intersecting 20-membered ring channels. The layered lanthanide sulfates, formulated as [H₃O]₃[(CH₃)₂NH₂]₃[Ln₂(SO₄)₆] (Ln=Pr for 2, Nd for 3), can be considered as combination of double-stranded chains and 8-membered rings. The synthesis of three compounds demonstrates that large organic amine (1, 3, 5-triazine-2, 4, 6-triamine) may be used as the second structural directing agent to prevent the formation of high dimensional inorganic framework as well as inducing crystal the growth of 2D layer structural lanthanide sulfates. The magnetic property of compounds 1 and 3 has been investigated through the magnetic measurement over the temperature range of 2~300 K.
- lanthanide sulfates,
- 20-membered ring channels,
- structural directing agent,
- magnetic property
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