Citation: WANG Gang, LIU Hong-Ming, JIANG Xing-Xing, YANG Lei, LIN Zhe-Shuai, HU Zhang-Gui, MENG Xiang-Gao, CHEN Xing-Guo, QIN Jin-Gui. Pb₇F₁₂Br₂: A Potential Mid-IR Nonlinear Optical Material with High Laser Damage Threshold[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2117-2123. doi: 10.11862/CJIC.2017.248 shu

Pb₇F₁₂Br₂: A Potential Mid-IR Nonlinear Optical Material with High Laser Damage Threshold

1.
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
2.
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
3.
College of Chemistry, Central China Normal University, Wuhan 430079, China

Corresponding author: LIN Zhe-Shuai, zslin@mail.ipc.ac.cn CHEN Xing-Guo, xgchen@whu.edu.cn
Received Date: 31 July 2017
Revised Date: 18 September 2017

Figures(9)

A Pb-containing mixed halide, Pb₇F₁₂Br₂, was synthesized and confirmed by single X-ray diffraction. Its nonlinear optical (NLO) and related properties have been studied systematically for the first time. It shows much wide energy band gap of 4.32 eV with large laser damage threshold (LDT) value of 25 MW·cm^-2 that is higher than that of the currently commercialized infrared (IR) NLO material AgGaS₂ measured at the same conditions ( < 5.2 MW·cm^-2). Second harmonic generation (SHG) effect test shows that its powders exhibit phase-matching SHG response of about 1.5 times as strong as that of KDP (KH₂PO₄). Its powders also show good transparence in the region of 0.3~14 μm and exhibit excellent thermal stability with the decomposition temperature up to 650 ℃. Thus, it shows good comprehensive properties.
- nonlinear optical material,
- laser damage threshold,
- Pb-containing mixed halide,
- mid-infrared region
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沈阳化工大学材料科学与工程学院沈阳 110142

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Pb₇F₁₂Br₂: A Potential Mid-IR Nonlinear Optical Material with High Laser Damage Threshold