Citation: XIE Jia-Ze, WANG Da-Peng, MA Jian-Ping, WANG Hai-Ying, ZUO Jing-Lin. Iron(Ⅱ) Complex Based on π-Conjugated 4-Tetrathiafulvalene-2, 6-di(pyrazin-2-yl)pyridine Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2045-2050. doi: 10.11862/CJIC.2017.246 shu

Iron(Ⅱ) Complex Based on π-Conjugated 4-Tetrathiafulvalene-2, 6-di(pyrazin-2-yl)pyridine Ligand

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China
2.
School of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China
3.
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao, Shandong 266590, China

Corresponding author: WANG Hai-Ying, haiyingqd@163.com
Received Date: 1 August 2017
Revised Date: 18 September 2017

Figures(6)

The tetrathiafulvalene (TTF) functionalized 2, 6-di(pyrazin-2-yl)pyridine derivative, 4-tetrathiafulvalene-2, 6-di(pyrazin-2-yl)pyridine (L), was designed and synthesized. Based on L, one electrochemically active TTF-containing Fe(Ⅱ) complex, namely, [Fe(Ⅱ)(L)₂](BF₄)₂·2.75CH₃CN·0.25CH₂Cl₂ (1), was synthesized and characterized by IR, elemental analysis, and X-ray single crystal diffraction. The complex 1 is formed by ligands and iron(Ⅱ) in a tridentate fashion. Complex 1 exhibits a discrete structure and features diverse nonclassical hydrogen bonding interactions, π…π and S…S interactions. In addition, magnetic, electrochemical, and spectroelectrochemistry properties for complex 1 have been studied.
- tetrathiafulvalene,
- Fe(Ⅱ) complex,
- multifunctional materials,
- crystal structure
1. [1]
  Mannini M, Pineider F, Danieli C, et al. Nature, 2010, 468 (7322):417-421 doi: 10.1038/nature09478
2. [2]
  Bogani L, Wernsdorfer W. Nat. Mater., 2008, 7(3):179-186 doi: 10.1038/nmat2133
3. [3]
  Wang G, Xue Z, Pan J, et al. CrystEngComm, 2016, 18(43): 8362-8365 doi: 10.1039/C6CE01954D
4. [4]
  Ma J P, Zhao C W, Wang S Q, et al. Chem. Commun., 2015, 51(78):14586-14589 doi: 10.1039/C5CC04268B
5. [5]
  Ma J P, Wang S Q, Zhao C W, et al. Chem. Mater., 2015, 27 (11):3805-3808 doi: 10.1021/acs.chemmater.5b00754
6. [6]
  Wang H Y, Cui L, Xie J Z, et al. Coord. Chem. Rev., 2017, 345:342-361 doi: 10.1016/j.ccr.2016.10.011
7. [7]
  Cui L, Zhu F, Leong C F, et al. Sci. China Ser. B: Chem., 2015, 58(4):650-657 doi: 10.1007/s11426-014-5177-9
8. [8]
  Yao M, Zheng Q, Gao F, et al. Sci. China Ser. B: Chem., 2012, 55(6):1022-1030 doi: 10.1007/s11426-012-4589-7
9. [9]
  Bousseksou A, Molnar G, Salmon L, et al. Chem. Soc. Rev., 2011, 40(6):3313-3335 doi: 10.1039/c1cs15042a
10. [10]
  Pointillart F, Liu X, Kepenekian M, et al. Dalton Trans., 2016, 45(28):11267-11271 doi: 10.1039/C6DT00920D
11. [11]
  Hu L, Liu W, Li C H, et al. Eur. J. Inorg. Chem., 2013, 2013 (35):6037-6048 doi: 10.1002/ejic.v2013.35
12. [12]
  SAINT-Plus, Version 6. 02, Bruker Analytical X-ray System, Madison, WI, 1999.
13. [13]
  Sheldrick G M. SADABS: An Empirical Absorption Correc-tion Program, Bruker Analytical X-ray Systems, Madison, WI, 1996.
14. [14]
  Sheldrick G M. Acta Crystallogr. Sect. A: Found. Crystallogr., 2008, A64:112-122
15. [15]
  Liu W T, Li J Y, Ni Z P, et al. Cryst. Growth Des., 2012, 12 (3):1482-1488 doi: 10.1021/cg201569m
16. [16]
  Iwahori F, Golhen S, Ouahab L, et al. Inorg. Chem., 2001, 40(26):6541-6542 doi: 10.1021/ic015550s
17. [17]
  Nishikawa H, Kitabatake R, Mitsumoto K, et al. Crystals, 2012, 2:935-945 doi: 10.3390/cryst2030935
18. [18]
  Shatruk M, Dragulescu-Andrasi A, Chambers K E, et al. J. Am. Chem. Soc., 2007, 129(19):6104-6116 doi: 10.1021/ja066273x
19. [19]
  Seredyuk M, Piñeiro-López L, Muñoz M C, et al. Inorg. Chem., 2015, 54(15):7424-7432 doi: 10.1021/acs.inorgchem.5b01001
1. [1]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
2. [2]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
3. [3]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
4. [4]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
5. [5]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
6. [6]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
7. [7]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
8. [8]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
9. [9]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
10. [10]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
11. [11]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
12. [12]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
13. [13]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
14. [14]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
15. [15]
  Zikang Hu , Hengjie Zhang , Zhengqiu Li , Tianbao Zhao , Zhipeng Gu , Qijuan Yuan , Baoshu Chen . Multifunctional photothermal hydrogels: Design principles, various functions, and promising biological applications. Chinese Chemical Letters, 2024, 35(10): 109527-. doi: 10.1016/j.cclet.2024.109527
16. [16]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
17. [17]
  Fengyun Li , Zerong Pei , Shuting Chen , Gen li , Mengyang Liu , Liqin Ding , Jingbo Liu , Feng Qiu . Multifunctional nano-herb based on tumor microenvironment for enhanced tumor therapy of gambogic acid. Chinese Chemical Letters, 2024, 35(5): 108752-. doi: 10.1016/j.cclet.2023.108752
18. [18]
  Yu Qin , Mingyang Huang , Chenlu Huang , Hannah L. Perry , Linhua Zhang , Dunwan Zhu . O₂-generating multifunctional polymeric micelles for highly efficient and selective photodynamic-photothermal therapy in melanoma. Chinese Chemical Letters, 2024, 35(7): 109171-. doi: 10.1016/j.cclet.2023.109171
19. [19]
  Kangmin Wang , Liqiu Wan , Jingyu Wang , Chunlin Zhou , Ke Yang , Liang Zhou , Bijin Li . Multifunctional 2-(2′-hydroxyphenyl)benzoxazoles: Ready synthesis, mechanochromism, fluorescence imaging, and OLEDs. Chinese Chemical Letters, 2024, 35(10): 109554-. doi: 10.1016/j.cclet.2024.109554
20. [20]
  Jun Lu , Jinrui Yan , Yaohao Guo , Junjie Qiu , Shuangliang Zhao , Bo Bao . Controlling solid form and crystal habit of triphenylmethanol by antisolvent crystallization in a microfluidic device. Chinese Chemical Letters, 2024, 35(4): 108876-. doi: 10.1016/j.cclet.2023.108876

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(381)
HTML views(52)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142