Citation: XING Chuan-Wang, LI Dong, LIU Cheng-Ben, KONG Xia, LI Xi-You, CHEN Yan-Li, JIANG Jian-Zhuang. Self-assembled Organic-Inorganic Hybrid Nanocomposites of Tetrakis(4-N, N-diethylaminophenyl)Porphyrin/Polyacid (Sodium Polyacid) and Highly Sensitive Responses toward NO₂[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(11): 2110-2116. doi: 10.11862/CJIC.2017.230 shu

Self-assembled Organic-Inorganic Hybrid Nanocomposites of Tetrakis(4-N, N-diethylaminophenyl)Porphyrin/Polyacid (Sodium Polyacid) and Highly Sensitive Responses toward NO₂

1.
China University of Petroleum (East China), School of Science, Qingdao 266580, China
2.
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry University of Science and Technology Beijing, Beijing 100083, China

Corresponding author: CHEN Yan-Li, yanlichen@upc.edu.cn JIANG Jian-Zhuang, jianzhuang@ustb.edu.cn
Received Date: 26 July 2017
Revised Date: 31 August 2017

Figures(7)

The novel H₂TNPP/TPA and H₂TNPP/NaTP organic-inorganic hybrid nanocomposites [H₂TNPP=tetrakis(4-N, N-diethylaminophenyl)porphyrin, TPA=the phosphotungstic acid and NaTP=sodium phosphotungstate] are fabricated by a simple QLS method. H-type molecular stacking mode with a tilted edge-on orientation of the H₂TNPP has been formed in the hybrid films. The intermolecular face-to-face π-π interaction and film microstructures are effectively improved by introducing inorganic TPA and NaTP within the organic H₂TNPP films, compared with the pure H₂TNPP film. In particular, good film-conductivity, smaller grain size and large specific surface area of H₂TNPP/NaTP hybrid film render it excellent sensing property for NO₂ gas with the lowest detection limit of 0.094 mg·m^-3 and highest sensitivity (43%) among the three kinds of films in room temperature, suggesting the great potential of semiconducting H₂TNPP/NaTP organic-inorganic hybrid nanocomposites in the field of chemical sensors. The present result provides a new strategy to obtain high performance room-temperature gas sensors by the construction of organic/inorganic hybrid structure combined with a low-cost solution-based method.
- porphyrin,
- polyacid,
- Self-Assombly,
- organic/inorganic composites,
- gas sensor,
- NO₂,
- room temperature response
1. [1]
  Baughman R H, Zakhidov A A, De Heer W A. Science, 2002, 297:787-792 doi: 10.1126/science.1060928
2. [2]
  Zampetti E, Macagnano A, Pantalei S, et al. Sens. Actuators, B, 2013, 179:69-73 doi: 10.1016/j.snb.2012.09.107
3. [3]
  LUO Yun, SHI Yong-Ping, YAO Gui-Ping, et al. Chinese J. Inorg. Chem., 2012, 28(6):1139-1144
4. [4]
  Liu Q Y, Yang Y T, Li H, et al. Biosens. Bioelectron., 2015, 64:147-153 doi: 10.1016/j.bios.2014.08.062
5. [5]
  Shirsat M D, Sarkar T, Kakoullis J Jr, et al. J. Phys. Chem. C, 2012, 116:3845-3850 doi: 10.1021/jp210582t
6. [6]
  Mosciano F, Magna G, Catini A, et al. Procedia Eng., 2015, 120:71-74 doi: 10.1016/j.proeng.2015.08.568
7. [7]
  ZHANG Li, ZHUO Xin, WANG Hong-Yan, et al. Chinese J. Inorg. Chem., 2007, 23(11):1988-1993 doi: 10.3321/j.issn:1001-4861.2007.11.026
8. [8]
  Kojima M, Oisaki K, Kanai M. Chem. Commun., 2015, 51 (47):9718-9721 doi: 10.1039/C5CC02349A
9. [9]
  Chen Y, Bouvet M, Sizun T, et al. Phys. Chem. Chem. Phys., 2010, 12:12851-12861 doi: 10.1039/c0cp00381f
10. [10]
  Wu Y, Ma P, Liu S, et al. New J. Chem., 2016, 40:3323-3329
11. [11]
  Kasha M, Rawls H R, Ashraf El-Bayoumi M. Pure Appl. Chem., 1965, 11:371-392 doi: 10.1039/C5NJ03021H
12. [12]
  Kasha M, Rawls H R, Ashraf El-Bayoumi M. Pure Appl. Chem., 1965,11:371-392
13. [13]
  Giri G, Verploegen E, Mannsfeld S C B, et al. Nature, 2011, 480:504-508 doi: 10.1038/nature10683
14. [14]
  Li D, Wang H, Kan J, et al. Org. Electron., 2013, 14:2582-2589 doi: 10.1016/j.orgel.2013.07.003
15. [15]
  Kong X, Zhang X, Gao D, et al. Chem. Sci., 2015, 6:1967-1972 doi: 10.1039/C4SC03492A
16. [16]
  Chen Y, Li D, Yuan N, et al. J. Mater. Chem., 2012, 22: 22142-22149 doi: 10.1039/c2jm35219b
17. [17]
  Yamamoto T, Kokubo H, Kobashi M, et al. Chem. Mater., 2004, 16:4616-4618 doi: 10.1021/cm049825o
18. [18]
  Yoneyama M, Sugi M, Saito M, et al. Jpn. J. Appl. Phys., 1986, 25:961-965 doi: 10.1143/JJAP.25.961
19. [19]
  Chen Y, Liu H G, Zhu P, et al. Langmuir, 2005, 21:11289-11295 doi: 10.1021/la051796o
20. [20]
  Gao Y M, Zhang X M, Ma C Q, et al. J. Am. Chem. Soc., 2008, 130:17044-17052 doi: 10.1021/ja8067337
21. [21]
  Kan J L, Chen Y L, Qi D D, et al. Adv. Mater., 2012, 24: 1755-1758 doi: 10.1002/adma.201200006
22. [22]
  Giri G, Verploegen E, Mannsfeld S C B, et al. Nature, 2011, 480:504-508 doi: 10.1038/nature10683
23. [23]
  HE Shu-Shen, ZHAO Bing-Tao, YU Zhi-Yuan. Environ. Monit. China, 2014 (4):50-55
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沈阳化工大学材料科学与工程学院沈阳 110142

Self-assembled Organic-Inorganic Hybrid Nanocomposites of Tetrakis(4-N, N-diethylaminophenyl)Porphyrin/Polyacid (Sodium Polyacid) and Highly Sensitive Responses toward NO2

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通讯作者: 陈斌, bchen63@163.com

Self-assembled Organic-Inorganic Hybrid Nanocomposites of Tetrakis(4-N, N-diethylaminophenyl)Porphyrin/Polyacid (Sodium Polyacid) and Highly Sensitive Responses toward NO₂