Citation: LIU Chao, LI Sha-Sha, YANG Min, BI Rong, YU Qing-Quan, ZHANG Li. Two Mononuclear Ni(Ⅱ) and Cu(Ⅱ) Complexes Containing a Bidentate Schiff Base Ligand:Syntheses, Structures and Antibacterial Activities[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1861-1868. doi: 10.11862/CJIC.2017.220 shu

Two Mononuclear Ni(Ⅱ) and Cu(Ⅱ) Complexes Containing a Bidentate Schiff Base Ligand:Syntheses, Structures and Antibacterial Activities

School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Anhui 234000, China

Corresponding author: LIU Chao, ahliuchao333@163.com
Received Date: 10 May 2017
Revised Date: 20 July 2017

Figures(4)

The title complexes, Ni(L)₂ (1) and Cu(L)₂ (2) based on HL (HL=N-(3-methylsalicylidene)tryptamine) have been synthesized under solvothermal conditions and characterized structurally by TGA, infrared spectra, elemental analysis and single-crystal X-ray diffraction. Complexes 1 and 2 both crystallize in monoclinic system, and the space groups are P2₁/n with the unit cell parameters for complex 1:a=1.481 6(7) nm, b=1.310 0(6) nm, c=1.668 7(7) nm, β=111.346(7)°, and for complex 2:a=1.479 7(2) nm, b=1.299 41(19) nm, c=1.667 6(2) nm, β=111.537(3)°. Complexes 1 and 2 possess the similar mononuclear structures, which are further extended into infinite 3D supramolecular frameworks by intramolecular C-H…O hydrogen bonds and intermolecular D-H…π hydrogen bonds, respectively. Furthermore, the complexes and the ligand have been investigated for their preliminary antibacterial activities in detail by agar diffusion method, and the results demonstrate that complexes 1 and 2 display more excellent inhibiting effects than the ligand.
- Ni(Ⅱ) complex,
- Cu(Ⅱ) complex,
- crystal structure,
- Schiff base,
- antibacterial activity
1. [1]
  Kargar H. Transition Met. Chem., 2014, 39:811-817 doi: 10.1007/s11243-014-9863-4
2. [2]
  毛盼东, 闫玲玲, 吴伟娜, 等.无机化学学报, 2016, 32(5):879-883
3. [3]
  Wang K, Chen Z L, Zou H H, et al. Transition Met. Chem., 2017, 42:17-23 doi: 10.1007/s11243-016-0101-0
4. [4]
  Luo W, Meng X, Xiang J, et al. Inorg. Chim. Acta, 2008, 361:2667-2676 doi: 10.1016/j.ica.2007.11.030
5. [5]
  Hegde D, Naik G N, Vadavi R S, et al. Inorg. Chim. Acta, 2017, 461:301-315 doi: 10.1016/j.ica.2017.02.034
6. [6]
  Alagesan M, Bhuvanesh N S, Dharmaraj N. Dalton Trans., 2013, 42:7210-7223 doi: 10.1039/c3dt50371b
7. [7]
  Patel R N, Singh A, Sondhiya V P, et al. J. Coord. Chem., 2012, 65:795-812 doi: 10.1080/00958972.2012.662592
8. [8]
  Sanyal R, Dash S K, Kundu P, et al. Inorg. Chim. Acta, 2016, 453:394-401 doi: 10.1016/j.ica.2016.08.047
9. [9]
  Fekri R, Salehi M, Asadi A, et al. Polyhedron, 2017, 128:175-187 doi: 10.1016/j.poly.2017.02.047
10. [10]
  Budige G, Puchakayala M R, Kongara S R, et al. Chem. Pharm. Bull., 2011, 59:166-171 doi: 10.1248/cpb.59.166
11. [11]
  Keypour H, Jamshidi A H, Rezaeivala M, et al. Polyhedron, 2013, 52:872-878 doi: 10.1016/j.poly.2012.07.027
12. [12]
  Creaven B S, Czeglédi E, Devereux M, et al. Dalton Trans., 2010, 39:10854-10865 doi: 10.1039/c0dt00068j
13. [13]
  Dong X, Li Y, Li Z, et al. J. Inorg. Biochem., 2012, 108:22-29 doi: 10.1016/j.jinorgbio.2011.12.006
14. [14]
  赵海燕, 杨晓东, 李娜.无机化学学报, 2017, 33(4):685-691
15. [15]
  刘超, 卓馨, 吴怡康, 等.宿州学院学报, 2011, 26(5):60-62
16. [16]
  Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
17. [17]
  Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
18. [18]
  Deng J Q, Liang H, Lu X C, et al. Chin. J. Struct. Chem., 2016, 35:559-565
19. [19]
  Zhao P S, Song J, Sun X J, et al. Chin. J. Struct. Chem., 2011, 30:346-353
1. [1]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
2. [2]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
3. [3]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
4. [4]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
5. [5]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
6. [6]
  Tao Yu , Vadim A. Soloshonok , Zhekai Xiao , Hong Liu , Jiang Wang . Probing the dynamic thermodynamic resolution and biological activity of Cu(Ⅱ) and Pd(Ⅱ) complexes with Schiff base ligand derived from proline. Chinese Chemical Letters, 2024, 35(4): 108901-. doi: 10.1016/j.cclet.2023.108901
7. [7]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
8. [8]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
9. [9]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
10. [10]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
11. [11]
  Chao Ma , Cong Lin , Jian Li . MicroED as a powerful technique for the structure determination of complex porous materials. Chinese Journal of Structural Chemistry, 2024, 43(3): 100209-100209. doi: 10.1016/j.cjsc.2023.100209
12. [12]
  Wenjuan Jin , Zelong Chen , Yi Wang , Jiaxuan Li , Jiahui Li , Yuxin Pei , Zhichao Pei . Nano metal-photosensitizer based on Aza-BODIPY-Cu complex for CDT-enhanced dual phototherapy. Chinese Chemical Letters, 2024, 35(7): 109328-. doi: 10.1016/j.cclet.2023.109328
13. [13]
  Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154
14. [14]
  Mengjuan Sun , Muye Zhou , Yifang Xiao , Hailei Tang , Jinhua Chen , Ruitao Zhang , Chunjiayu Li , Qi Ya , Qian Chen , Jiasheng Tu , Qiyue Wang , Chunmeng Sun . Reversibly size-switchable polyion complex micelles for antiangiogenic cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109110-. doi: 10.1016/j.cclet.2023.109110
15. [15]
  Yuanjin Chen , Xianghui Shi , Dajiang Huang , Junnian Wei , Zhenfeng Xi . Synthesis and reactivity of cobalt dinitrogen complex supported by nonsymmetrical pincer ligand. Chinese Chemical Letters, 2024, 35(7): 109292-. doi: 10.1016/j.cclet.2023.109292
16. [16]
  Jingwen Zhao , Jianpu Tang , Zhen Cui , Limin Liu , Dayong Yang , Chi Yao . A DNA micro-complex containing polyaptamer for exosome separation and wound healing. Chinese Chemical Letters, 2024, 35(9): 109303-. doi: 10.1016/j.cclet.2023.109303
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
19. [19]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
20. [20]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(261)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142