Citation: WANG Zi, YAN Wen-Fu, XU Ru-Ren. Initial-Gel-Composition-Dependence of Dipropylamine-Structure-Fine-Tuning Influence on the Crystallization Pathways of Aluminophosphate Molecular Sieve[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1595-1602. doi: 10.11862/CJIC.2017.208 shu

Initial-Gel-Composition-Dependence of Dipropylamine-Structure-Fine-Tuning Influence on the Crystallization Pathways of Aluminophosphate Molecular Sieve

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Corresponding author: YAN Wen-Fu, yanw@jlu.edu.cn
Received Date: 15 March 2017
Revised Date: 11 June 2017

Figures(8)

The structure-directing effect of dipropylamine isomers, i.e., di-n-propylamine (DPA) and diisopro-pylamine (D-iPA), was investigated. By heating the initial gels with certain composition at 200℃ for 24 h, highly crystalline aluminophosphate molecular sieve AlPO₄-11 was obtained. The crystallization processes were investigated using X-ray diffraction, elemental analysis and pH value measurement. For the crystallization process of the initial gel with n_AL₂O₃:n_P₂O₅:n_DPA/D-iPA:n_H₂O=1.0:1.0:1.2:75, no intermediate phase was formed when the DPA was used as the structure-directing agent, whereas intermediate phase of aluminophosphate molecular sieve AlPO₄-5 was observed when the D-iPA was used as the structure-directing agent. For the crystallization process of the initial gel with n_AL₂O₃:n_P₂O₅:n_DPA/D-iPA:n_H₂O=1.0:1.0:1.0:75, intermediate phase of aluminophosphate molecular sieve VPI-5 was formed when the DPA was used as the structure-directing agent, whereas intermediate phases of both VPI-5 and AlPO₄-5 were observed when the D-iPA was used as the structure-directing agent. Theoretical calculation showed that the charge on the N of the protonated DPA was different with that on the N of the protonated D-iPA. The results indicate that the structure-directing effect of amine can be affected by the composition of the initial gel and the fine-tuning of the structure of amine can influence its structure-directing effect. However, such influence is affected by the composition of the initial gel.
- zeolites,
- aluminophosphate,
- structure-directing effect,
- crystallization pathway,
- intermediate phase
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