Citation: ZHANG Fei-Fei, SHANG Hua, YANG Jing-Feng, OUYANG Kun, LI Jin-Ping. Ethylenediamine Modified Light Metal Aluminum-Metal-Organic Framework Material for CO₂/CH₄ Separation[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1611-1617. doi: 10.11862/CJIC.2017.206 shu

Ethylenediamine Modified Light Metal Aluminum-Metal-Organic Framework Material for CO₂/CH₄ Separation

College of Chemistry and Chemical Engineering, Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: YANG Jing-Feng, yangjiangfeng@tyut.edu.cn
Received Date: 18 April 2017
Revised Date: 19 June 2017

Figures(9)

Amine molecule plays a role of improving selectivity on the CO₂ capture. Small size ethylenediamine molecules were selected to modify the light metal Al-based metal-organic framework (MOFs) MIL-100Al with unsaturated metal sites in this work, the structure of the materials was characterized by XRD, N₂ adsorption and FT-IR. The adsorption properties of MIL-100Al modified with different concentrations of ethylenediamine on CO₂ and CH₄ were tested. Compared with the original MIL-100Al sample, the amount of CO₂ adsorbed by MIL-100Al modified with ethylenediamine is significantly improved, while CH₄ adsorption decreases. The CO₂/CH₄ adsorption selectivity of the material therefor is further improved, and the performance of adsorption separation is enhanced.
- light metal,
- modified,
- adsorption,
- CO₂,
- CH₄
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Ethylenediamine Modified Light Metal Aluminum-Metal-Organic Framework Material for CO2/CH4 Separation

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Ethylenediamine Modified Light Metal Aluminum-Metal-Organic Framework Material for CO₂/CH₄ Separation