Citation: YAO Zhong-Ping, CHEN Chang-Ju, WANG Jian-Kang, XIA Qi-Xing, LI Chun-Xiang, JIANG Zhao-Hua. Iron Oxide Coating Fenton-like Catalysts:Preparation and Degradation of Phenol[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1797-1804. doi: 10.11862/CJIC.2017.197 shu

Iron Oxide Coating Fenton-like Catalysts:Preparation and Degradation of Phenol

1.
State Key Laboratory of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
2.
Key Laboratory of Ultra-Light Materials and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin 150001, China

Corresponding author: YAO Zhong-Ping, yaozhongping@hit.edu.cn
Received Date: 31 May 2017
Revised Date: 7 July 2017

Figures(9)

The iron oxide coating Fenton-like catalyst on Ti alloy was successfully prepared in silicate electrolyte via micro-arc oxidation. The surface morphology, crystal structure and phase composition were studied by SEM, XRD and XPS. The results indicated that the as-prepared coating included the rutile TiO₂ (R-TiO₂), and amorphous Fe₃O₄ which was analyzed by XPS. The SEM images suggested that after the addition of K₃[Fe(CN)₆] in the electrolyte, the surface roughness and average pore size of the as-prepared coating were increased. The Fenton-like catalytic activity of as-prepared coating was investigated by degradation of phenol. What's more, the influences of K₃[Fe(CN)₆] content, phenol concentration, H₂O₂ dosage and pH value on phenol degradation were also studied and finally the optimal degradation condition was confirmed. Under pH 3.0, 30℃, H₂O₂ 6.0 mmol·L^-1, phenol 35 mg·L^-1 and K₃[Fe(CN)₆] 10 g·L^-1, 90% phenol could be removed. The effect of degradation temperature on degradation efficiency was also evaluated and the reaction kinetics under different temperature were also studied. The activation energy of Fenton-like degradation of phenol through Arrhenius equation is 96.9 kJ·mol^-1. Finally, the stability was studied and the stability degradation was also analyzed.
- iron oxide coatings,
- Fenton-like catalyst,
- Ti alloy,
- micro-arc oxidation,
- phenol
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1.
沈阳化工大学材料科学与工程学院沈阳 110142