Citation: WU Qi, SU Zhi, WANG Hong-Yan, DONG Yi-Li, HU Jiong-Sheng, LIU Dong-Ju, WU Chang, XU Yun, YING Ao, FANG Min, LIU Hong-Ke. Syntheses, Crystal Structures and Fluorescence of Cadmium(Ⅱ) and Zinc(Ⅱ) Complexes Based on Flexible Tripodal Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1889-1895. doi: 10.11862/CJIC.2017.196 shu

Syntheses, Crystal Structures and Fluorescence of Cadmium(Ⅱ) and Zinc(Ⅱ) Complexes Based on Flexible Tripodal Ligands

WU Qi ¹ ,
SU Zhi ¹ ,
WANG Hong-Yan ¹ ,
DONG Yi-Li ¹ ,
HU Jiong-Sheng ¹ ,
LIU Dong-Ju ¹ ,
WU Chang ¹ ,
XU Yun ¹ ,
YING Ao ¹ ,
FANG Min ^1,, ,
LIU Hong-Ke ^1,2,,

1.
College of Chemistry and Materials Science, Jiangsu Key Laboratory of Biofunctional Materials, Nanjing Normal University, Nanjing 210023, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: FANG Min, liuhongke@njnu.edu.cn LIU Hong-Ke, fangmin@njnu.edu.cn
Received Date: 2 May 2017
Revised Date: 8 June 2017

Figures(4)

Two new coordination polymers, {[Cd₃(SO₄)₄(TITMB)₂(H₂O)₄] [Cd(H₂O)₆]·2CH₃OH}_n (1) and {[Zn(TTTMB) (HCOO)₂]·CH₃OH}_n (2), based on the flexible tripodal ligands 1, 3, 5-tris(imidazol-1-ylmethyl)-2, 4, 6-trimethylbenzene (TITMB) and 1, 3, 5-tris(triazol-1-ylmethyl)-2, 4, 6-trimethylbenzene (TTTMB), have been synthesized and character-ized by single-crystal XRD analyses, IR spectra, solid state photoluminescence studies, thermogravimetric analyses, and elemental analyses. Single-crystal X-ray diffraction reveals that both complexes 1 and 2 are two-dimensional layers, and extended to three-dimensional structure by hydrogen bonds. In complex 1, inorganic chains constructed by SO₄^2- and Cd(Ⅱ) are linked by ligand TITMB to the 2D networks, where the[Cd(H₂O)₆]²⁺ units locate in the cavity between two adjacent 2D layers by hydrogen bonds to neutralize the charge. Complex 2 owns typical 6³ 2D topological networks. The thermal stability and photoluminescence property were also studied. Both complexes show high thermal stabilities and display blue fluorescent emissions in the solid state at room temperature.
- flexible tripodal ligand,
- coordination polymers,
- luminescence property
1. [1]
  Feng D W, Jiang H L, Chen Y P, et al. Inorg. Chem., 2013, 52:12661-12667 doi: 10.1021/ic4018536
2. [2]
  Zhou H C, Long J R, Yaghi O M. Chem. Rev., 2012, 112:673-674 doi: 10.1021/cr300014x
3. [3]
  Liu J, Thallapally P K, McGrail B P, et al. Chem. Soc. Rev., 2012, 41:2308-2322 doi: 10.1039/C1CS15221A
4. [4]
  Liu H K, Tan H Y, Liao S, et al. Chem. Commun., 2001:1008-1009
5. [5]
  Feng D W, Gu Z Y, Li J R, et al. Angew. Chem. Int. Ed., 2012, 51:10307-10310 doi: 10.1002/anie.201204475
6. [6]
  Jiang H L, Feng D W, Wang K C, et al. J. Am. Chem. Soc., 2013, 135:13934-13938 doi: 10.1021/ja406844r
7. [7]
  Chen Y, Lykourinou V, Carissa V, et al. J. Am. Chem. Soc., 2012, 134:13188-13191 doi: 10.1021/ja305144x
8. [8]
  Wiester M J, Ulmann P A, Mirkin C A. Angew. Chem. Int. Ed., 2011, 50:114-137 doi: 10.1002/anie.v50.1
9. [9]
  Chen Y, Lykourinou V, Hoang T, et al. Inorg. Chem., 2012, 51:9156-9158 doi: 10.1021/ic301280n
10. [10]
  Liu H K, Sun W Y, Zhu H L, et al. Inorg. Chim. Acta, 1999, 295:129-135 doi: 10.1016/S0020-1693(99)00332-1
11. [11]
  徐周庆, 何亚玲, 李慧军, 等.无机化学学报, 2017, 33(5):897-904
12. [12]
  Hiroyasu F, Felipe G, Zhang Y B, et al. J. Am. Chem. Soc., 2014, 136:4369-4381 doi: 10.1021/ja500330a
13. [13]
  Reinsch H, Marszalek B, Wack J, et al. Chem. Commun., 2012, 48:9486-9488 doi: 10.1039/c2cc34909d
14. [14]
  Yin X J, Zhou X H, Gu Z G, et al. Inorg. Chem. Commun., 2009, 12:548-551 doi: 10.1016/j.inoche.2009.04.012
15. [15]
  Henninger S K, Jeremias F, Kummer H, et al. Eur. J. Inorg. Chem., 2012, 16:2625-2634
16. [16]
  Fan J, Zhu H F, Okamura T, et al. Chem. Eur. J., 2003, 9:4724-4731 doi: 10.1002/chem.v9:19
17. [17]
  Fan J, Zhu H F, Okamura T, et al. Inorg. Chem., 2003, 42:158-162 doi: 10.1021/ic020461g
18. [18]
  Yan W, Han L J, Jia H L, et al. Inorg. Chem., 2016, 55:8816-8821 doi: 10.1021/acs.inorgchem.6b01328
19. [19]
  Nguyen J G, Cohen S M. J. Am. Chem. Soc., 2010, 132:4560-4561 doi: 10.1021/ja100900c
20. [20]
  Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution and Refinement, University of Göttingen, Germany, 1997.
21. [21]
  赵仑, 陈瑞战, 王子忱.无机化学学报, 2016, 32(7):1190-1198
22. [22]
  赵越, 翟玲玲, 孙为银.无机化学学报, 2014, 30(1):18-22
23. [23]
  Hu T P, Xue Z J, Zheng B H, et al. CrystEngComm, 2016, 18:5386-5392 doi: 10.1039/C6CE00674D
24. [24]
  Khatua S, Kang J, Huh J O, et al. Cryst. Growth Des., 2010, 10:327-334 doi: 10.1021/cg900917v
25. [25]
  Bach S, Panthöfer M, Bienert R, et al. Cryst. Growth Des., 2016, 16:4232-4239 doi: 10.1021/acs.cgd.6b00208
26. [26]
  Dong W W, Xia L, Peng Z, et al. J. Solid State Chem., 2016, 238:170-174 doi: 10.1016/j.jssc.2016.03.027
27. [27]
  Wang J, Zhang X, Wei Q L, et al. Nano Energy, 2016, 19:222-233 doi: 10.1016/j.nanoen.2015.10.036
28. [28]
  Sun D R, Sun F X, Deng X Y, et al. Inorg. Chem., 2015, 54:8639-8643 doi: 10.1021/acs.inorgchem.5b01278
29. [29]
  Sun D R, Ye L, Sun F X, et al. Inorg. Chem., 2017, 56:5203-5209 doi: 10.1021/acs.inorgchem.7b00333
1. [1]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
2. [2]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
3. [3]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
4. [4]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
5. [5]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
6. [6]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
7. [7]
  Jun Guo , Zhenbang Zhuang , Wanqiang Liu , Gang Huang . "Co-coordination force" assisted rigid-flexible coupling crystalline polymer for high-performance aqueous zinc-organic batteries. Chinese Chemical Letters, 2024, 35(9): 109803-. doi: 10.1016/j.cclet.2024.109803
8. [8]
  Zixu Xie , Pengfei Zhang , Ziyao Zhang , Chen Chen , Xing Wang . The choice of antimicrobial polymers: Hydrophilic or hydrophobic?. Chinese Chemical Letters, 2024, 35(9): 109768-. doi: 10.1016/j.cclet.2024.109768
9. [9]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
10. [10]
  Hao Cai , Xiaoyan Wu , Lei Jiang , Feng Yu , Yuxiang Yang , Yan Li , Xian Zhang , Jian Liu , Zijian Li , Hong Bi . Lysosome-targeted carbon dots with a light-controlled nitric oxide releasing property for enhanced photodynamic therapy. Chinese Chemical Letters, 2024, 35(4): 108946-. doi: 10.1016/j.cclet.2023.108946
11. [11]
  Shihong Wu , Ronghui Zhou , Hang Zhao , Peng Wu . Sonoafterglow luminescence for in vivo deep-tissue imaging. Chinese Chemical Letters, 2024, 35(10): 110026-. doi: 10.1016/j.cclet.2024.110026
12. [12]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
13. [13]
  Pengcheng Su , Shizheng Chen , Zhihong Yang , Ningning Zhong , Chenzi Jiang , Wanbin Li . Vapor-phase postsynthetic amination of hypercrosslinked polymers for efficient iodine capture. Chinese Chemical Letters, 2024, 35(9): 109357-. doi: 10.1016/j.cclet.2023.109357
14. [14]
  Kongchuan Wu , Dandan Lu , Jianbin Lin , Ting-Bin Wen , Wei Hao , Kai Tan , Hui-Jun Zhang . Elucidating ligand effects in rhodium(Ⅲ)-catalyzed arene–alkene coupling reactions. Chinese Chemical Letters, 2024, 35(5): 108906-. doi: 10.1016/j.cclet.2023.108906
15. [15]
  Yuanjin Chen , Xianghui Shi , Dajiang Huang , Junnian Wei , Zhenfeng Xi . Synthesis and reactivity of cobalt dinitrogen complex supported by nonsymmetrical pincer ligand. Chinese Chemical Letters, 2024, 35(7): 109292-. doi: 10.1016/j.cclet.2023.109292
16. [16]
  Huijie An , Chen Yang , Zhihui Jiang , Junjie Yuan , Zhongming Qiu , Longhao Chen , Xin Chen , Mutu Huang , Linlang Huang , Hongju Lin , Biao Cheng , Hongjiang Liu , Zhiqiang Yu . Luminescence-activated Pt(Ⅳ) prodrug for in situ triggerable cancer therapy. Chinese Chemical Letters, 2024, 35(7): 109134-. doi: 10.1016/j.cclet.2023.109134
17. [17]
  Jiqing Liu , Qi Dang , Liting Wang , Dejin Wang , Liang Tang . Applications of flexible electrochemical electrodes in wastewater treatment: A review. Chinese Chemical Letters, 2024, 35(8): 109277-. doi: 10.1016/j.cclet.2023.109277
18. [18]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
19. [19]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
20. [20]
  Fangzhou Wang , Wentong Gao , Chenghui Li . A weak but inert hindered urethane bond for high-performance dynamic polyurethane polymers. Chinese Chemical Letters, 2024, 35(5): 109305-. doi: 10.1016/j.cclet.2023.109305

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1085)
HTML views(54)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142