Citation: RU Ting-Ting, CHU Xue-Feng, SHI Ying-Yan, ZHENG Wen-Qi, GUO Yan, YANG Xiao-Tian, JIANG Kai. Shape-Controlled Synthesis of Pd Nanocrystals with Remarkable Enhanced Catalytic Performance[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(10): 1835-1842. doi: 10.11862/CJIC.2017.193 shu

Shape-Controlled Synthesis of Pd Nanocrystals with Remarkable Enhanced Catalytic Performance

1.
Department of Basic Science, Jilin Jianzhu University, Changchun 130118, China
2.
Jilin Provincial Key Laboratory of Architectural Electricity & Comprehensive Energy Saving, Jilin Jianzhu University, Changchun 130118, China
3.
Affiliated Hospital to Changchun University of Chinese Medicine, Changchun 130021, China

Corresponding author: YANG Xiao-Tian, hanyxt@163.com JIANG Kai, jiangkaitiamei@sina.com
Received Date: 21 March 2017
Revised Date: 19 July 2017

Figures(5)

A morphology-evolution of Pd nanocrystals was successfully triggered by using N, N-dimethyloctade-cylammonium bromide acetate sodium (OTAB-Na) as the capping agent. Uniform and monodisperse dendritic and concave Pd nanocrystals were synthesized by directly changing the pH value of the reaction solution. In the following catalytic test of liquid-phase reduction of 4-nitrophenol (4-NP) by ammonia-borane complex (AB), the as-obtained Pd nanocrystals exhibit a shape-dependent catalytic properties, in which the dendritic nanosphere is the better one.
- Pd,
- noble metal,
- nanoparticle,
- concave,
- dendritic
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沈阳化工大学材料科学与工程学院沈阳 110142