Citation: MA Xiao-Hui, LI Fei-Fei, CEN Pei-Pei, LIU Xiang-Yu, ZHOU Hui-Liang, LUO Shu-Chang, WU Yue-Wei, ZHANG Cheng-Cheng, SONG Wei-Ming. One-Dimensional Cu(Ⅱ)Chain Compound with Simultaneous EO-Azido and Carboxylato Bridges Displaying Strong Ferromagnetic Coupling:Synthesis, Crystal Structure, Magnetic Properties with DFT Calculations[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1639-1648. doi: 10.11862/CJIC.2017.174 shu

One-Dimensional Cu(Ⅱ)Chain Compound with Simultaneous EO-Azido and Carboxylato Bridges Displaying Strong Ferromagnetic Coupling:Synthesis, Crystal Structure, Magnetic Properties with DFT Calculations

1.
College of Chemistry and Chemical Engineering, State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering, Ningxia University, Yinchuan 750021, China
2.
School of Chemical Engineering, Guizhou University of Engineering Science, Bijie, Guizhou 551700, China

Corresponding author: LIU Xiang-Yu, xiangyuliu432@126.com LUO Shu-Chang, luosc@gues.edu.cn SONG Wei-Ming, songwm@nxu.edu.cn
Received Date: 13 April 2017
Revised Date: 17 May 2017

Figures(5)

An azido-Cu(Ⅱ)compound with substituted benzoate derivative, [Cu(4-Fb)(N₃)(H₂O)]_n (1) (4-Fb=4-form-ylbenzoate), has been successfully synthesized, and then structurally and magnetically characterized. Single crystal structure analysis demonstrates that the asymmetric unit of compound 1 possesses one crystallographically independent Cu(Ⅱ)ion that exhibits distorted tetragonal pyramid geometry. Adjacent Cu(Ⅱ)ions are linked by alternating mixed-bridges of μ-1, 1(end-on, EO) azido and syn, syn-carboxylate, forming a linear 1D Cu(Ⅱ)chain-like motif. Magnetic measurements reveal that the dominant ferromagnetic coupling between adjacent Cu(Ⅱ)ions within each chain due to the counter-complementarity of the dual superexchange pathway is observed in the resulting compounds. However, the interesting plots of magnetic ordering and slow magnetic relaxation are absent in the compound. The critical structural parameter, Cu-N-Cu angle of 113.34°, is corresponding to that of known ferromangetic copper systems containing mixed carboxylate/EO-azido connectors. Magneto-structural correlations are also investigated. Moreover, density functional theory (DFT) calculations (using different methods and basis sets) have been performed on title compound to offer qualitatively theoretical explanation for the ferromagnetic coupling between two Cu(Ⅱ)centers.CCDC:1496426.
- azido-copper,
- benzoate,
- crystal structure,
- magnetic property,
- DFT calculation
1. [1]
  (a)Pei Y, Verdaguer M, Kahn O. J. Am. Chem. Soc. , 1986, 108: 7428-7430
  (b)Miller J S, Calabrese J C, Rommelmann H, et al. J. Am. Chem. Soc. , 1987, 109: 769-781
2. [2]
  (a)Wang X Y, Wang Z M, Gao S. Inorg. Chem. , 2008, 47: 5720-5726
  (b)Wang X Y, Wang L, Wang Z M, et al. J. Am. Chem. Soc. , 2006, 128: 674-675
  (c)Martín S, Barandika M G, Lezama L, et al. Inorg. Chem. , 2001, 40: 4109-4115
3. [3]
  (a)Ungur L, Lin S Y, Tang J K, et al. Chem. Soc. Rev. , 2014, 43: 6894-6905
  (b)Gatteschi D, Sessoli R. Angew. Chem. , Int. Ed. , 2003, 42: 268-297
  (c)Wernsdorfer W, Aliaga-Alcalde N, Hendrickson D N, et al. Nature, 2002, 416: 406-409
  (d)Woodruff D N, Winpenny R E, Layfield R A. Chem. Rev. , 2013, 113: 5110-5148
  (e)Leng J D, Liu J L, Zheng Y Z, et al. Chem. Commun. , 2013, 49: 158-160
  (f)Zhang P, Zhang L, Tang J K. Dalton Trans. , 2015, 44: 3923-3929
4. [4]
  (a)Caneschi A, Gatteschi D, Lalioti N, et al. Angew. Chem. Int. Ed. , 2001, 40: 1760-1763
  (b)Werner J, Rams M, Tomkowicz Z, et al. Inorg. Chem. , 2015, 54: 2893-2901
  (c)Vaz M G, Cassaro R A A, Akpinar H, et al. Chem. -Eur. J. , 2014, 20: 5460-5467
  (d)Wang Y Q, Cheng A L, Liu P P, et al. Chem. Commun. , 2013, 49: 6995-6997
  (e)Pardo E, Ruiz-García R, Lloret F, et al. Chem. -Eur. J. , 2007, 13: 2054-2066
  (f)Dhers S, Feltham H L, Brooker S. Coord. Chem. Rev. , 2015, 296: 24-44
5. [5]
  (a)Neville S M, Halder G J, Chapman K W, et al. J. Am. Chem. Soc. , 2008, 130: 2869-2076
  (b)Pardo E, Train C, Boubekeur K, et al. Inorg. Chem. , 2012, 51: 11582-11593
  (c)Liu X Y, Qu X N, Zhang S, et al. Inorg. Chem. , 2015, 54: 11520-11525
  (d)LI Hai-Qing(李海清), HUA Jing-Kun(华敬坤), ZHA Li-Qin(查丽琴), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015, 31(7): 1417-1424
6. [6]
  (a)Weng D F, Wang Z M, Gao S. Chem. Soc. Rev. , 2011, 40: 3157-3181
  (b)Ferbinteanu M, Miyasaka H, Wernsdorfer W, et al. J. Am. Chem. Soc. , 2005, 127: 3090-3099
  (c)Bogani L, Sangregorio C, Sessoli R, et al. Angew. Chem. Int. Ed. , 2005, 36: 5967-5971
  (d)Sessoli R, Powell A K. Coord. Chem. Rev. , 2009, 253: 2328-2341
  (e)Jeremies A, Gruschinski S, Meyer M, et al. Inorg. Chem. , 2016, 55: 1843-1853
  (f)Liu X Y, Cen P P, Li F F, et al. RSC Adv. , 2016, 6: 96103-96108
7. [7]
  (a)Ferlay S, Mallah T, Ouahes R, et al. Nature, 1995, 378: 701-703
  (b)Entley W R, Girolami G S. Science, 1995, 268: 397-400
  (c)Liu X Y, Sun L, Zhou H L, et al. Inorg. Chem. , 2015, 54: 8884-8886
  (d)Chen M, Zhao H, Saudo E C, et al. Inorg. Chem. , 2016, 55: 3715-3717
  (e)Liu X Y, Liu H X, Cen P P, et al. Inorg. Chim. Acta, 2016, 447: 12-17
8. [8]
  (a)Lescouzec R, Toma L M, Vaissermann J, et al. Coord. Chem. Rev. , 2005, 249: 2691-2729
  (b)Miyasaka H, Julve M, Yamashita M, et al. Inorg. Chem. , 2009, 48: 3420-3437
  (c)Bernot K, Luzon J, Sessoli R, et al. J. Am. Chem. Soc. , 2008, 130: 1619-1627
  (d)Ding M, Wang B, Wang Z, et al. Chem. -Eur. J. , 2012, 18: 915-924
  (e)Reger D L, Pascui A E, Smith M D, et al. Inorg. Chem. , 2015, 54: 1487-1500
  (f)SUN Lin(孙琳), LIU Huai-Xian(刘怀贤), ZHOU Hui-Liang (周惠良), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015, 31(6): 1207-1214
9. [9]
  Kahn O. Molecular Magnetism. New York:VCH, 1993.
10. [10]
  (a)Ribas J, Escuer A, Monfort M, et al. Coord. Chem. Rev. , 1999, 1027: 193-195
  (b)Zeng Y F, Hu X, Liu F C, et al. Chem. Soc. Rev. , 2009, 38: 469-480
  (c)Adhikary C, Koner S. Coord. Chem. Rev. , 2010, 254: 2933-2958
  (d)BAI Shi-Qiang(白士强), FANG Chen-Jie(房晨婕), YAN Chun-Hua(严纯华). Chinese J. Inorg. Chem. (无机化学学报), 2006, 22(12): 2123-2134
11. [11]
  (a)Hong C S, Do Y. Angew. Chem. , Int. Ed. , 1999, 38: 193-195
  (b)Liu T F, Fu D, Gao S, et al. J. Am. Chem. Soc. , 2003, 125: 13976-13977
12. [12]
  Gao E Q, Bai S Q, Wang Z M, et al. J. Am. Chem. Soc., 2003, 125:4984-4985 doi: 10.1021/ja034129v
13. [13]
  (a)Yoo H S, Kim I J, Yang N, et al. Inorg. Chem. , 2007, 46: 9054-9056
  (b)Escuer A, Aroms G. Eur. J. Inorg. Chem. , 2006, 23: 4721-4736
14. [14]
  (a)Cheng M, Ding Y S, Gao E Q, et al. Dalton Trans. , 2016, 45: 8028-8035
  (b)Schweinfurth D, Sommer M G, Atanasov M, et al. J. Am. Chem. Soc. , 2015, 137: 1993-2005
15. [15]
  (a)Liu J, Qin Y L, Qu M, et al. Dalton Trans. , 2013, 42: 11571-11575
  (b)Hu K L, Kurmoo M, Wang Z, et al. Chem. -Eur. J. , 2009, 15: 12050-12064
  (c)Li J R, Yu Q, Sanudo C, et al. Chem. Commun. , 2007, 25: 2602-2604
  (d)Liu X Y, Cen P P, Li H, et al. Inorg. Chem. , 2014, 53: 8088-8097
  (e)FAN Yan(范艳), WANG Chen-Min(汪晨敏), QU Zhi-Rong(瞿志荣). Chinese J. Inorg. Chem. (无机化学学报), 2016, 32(5): 864-870
16. [16]
  (a)Kahn O, Sikorav S, Gouteron J, et al. Inorg. Chem. , 1983, 22: 2877-2883
  (b)Cortes R, Urtiaga M K, Lezama L, et al. Dalton Trans. , 1993, 24: 3685-3694
  (c)Thompson L K, Tandon S S. Comments Inorg. Chem. , 1996, 18: 125-144
  (d)Zhang L, Zuo J L, Gao S, et al. Angew. Chem. Int. Ed. , 2000, 39: 3633-3635
17. [17]
  (a)Ruiz E, Cano J, Alvarez S, et al. J. Am. Chem. Soc. , 1998, 120: 11122-11129
  (b)Cabrero J, Graaf C, Bordas E, et al. Chem. -Eur. J. , 2003, 9: 2307-2315
  (c)Triki S, García C J G, Ruiz E et al. Inorg. Chem. , 2005, 44: 5501-5508
  (d)Mialane P, Dolbecq A, Marrot J, et al. Chem. -Eur. J. , 2005, 11: 1771-1778
  (e)Nanda P K, Aromí G, Ray D. Chem. Commun. , 2006, 30: 3181-3183
18. [18]
  (a)Shi W B, Cui A L, Kou H Z. ChemPlusChem, 2014, 79: 310-317
  (b)Zhang S M, Chen Y H, Wang L H, et al. J. Solid State Chem. , 2015, 226: 201-205
  (c)Wang Y Q, Tan Q H, Guo X Y, et al. RSC Adv. , 2016, 6: 72326-72332
19. [19]
  (a)Yang L, Zhang S, Liu X Y, et al. CrystEngComm, 2014, 16: 4194-4201
  (b)Stamatatos T C, Vlahopoulou G, Raptopoulou C P, et al. Eur. J. Inorg. Chem. , 2012, 19: 3121-3131
  (c)Tangoulis V, Panagoulis D, Raptopoulou C P, et al. Dalton Trans. , 2008, 5: 1752-1760
20. [20]
  (a)Thompson L K, Tandon S S, Lloret F, et al. Inorg. Chem. , 1997, 36: 3301-3306
  (b)Escuer A, Vicente R, Mautner F A, et al. Inorg. Chem. , 1997, 36: 1233-1236
21. [21]
  Sheldrick G M. SADABS, Program for Empirical Absorption Correction for Area Detector Data, University of Göttingen, Germany, 1996.
22. [22]
  Sheldrick G M. SHELXS-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
23. [23]
  (a)Ruiz E, Alemany P, Alvarez S, et al. J. Am. Chem. Soc. , 1997, 119: 1297-1303
  (b)Ruiz E, Rodríguez-Fortea A, Cano J, et al. J. Comput. Chem. , 2003, 24: 982-989
  (c)Ruiz E, Cano J, Alvarez S, et al. J. Comput. Chem. , 1999, 20: 1391-1400
  (d)Ruiz E. Struct. Bonding, 2004, 113: 71-102
24. [24]
  (a)Sarkar S, Datta A, Mondal A, et al. J. Phys. Chem. B, 2006, 110: 12-15
  (b)Cremades E, Ruiz E. Inorg. Chem. , 2010, 49: 9641-9648
  (c)Gole B, Chakrabarty R, Mukherjee S, et al. Dalton Trans. , 2010, 39: 9766-9778
25. [25]
  (a)Neese F. ORCA-an ab initio, Density Functional and Semiempirical Program Package, Ver. 3. 0. 1, University of Bonn, Bonn, Germany, 2013.
  (b)Neese F. WIREs Comput. Mol. Sci. , 2012, 2: 73-78
26. [26]
  Becke A D. Phys. Rev. A, 1988, 38:3098-3100 doi: 10.1103/PhysRevA.38.3098
27. [27]
  (a)Perdew J P. Phys. Rev. B, 1986, 33: 8822-8824
  (b)Becke A D. J. Chem. Phys. , 1993, 98: 5648-5652
28. [28]
  (a)Schäfer A, Horn H, Ahlrichs R. J. Chem. Phys. , 1992, 97: 2571-2577
  (b)Schfer A, Huber C, Ahlrichs R. J. Chem. Phys. , 1994, 100: 5829-5835
29. [29]
  Baker G A, Rushbrooke G S. Phys. Rev., 1964, 135:A1272 doi: 10.1103/PhysRev.135.A1272
30. [30]
  (a)Tandon S S, Thompson L K, Manuel M E, et al. Inorg. Chem. , 1994, 33: 5555-5570
  (b)Thompson L K, Tandon S S, Manuel M E. Inorg. Chem. , 1995, 34: 2356-2366
  (c)Sikorav S, Bkouche-Waksman I, Kahn O. Inorg. Chem. , 1984, 23: 490-495
31. [31]
  (a)Zhao J P, Hu B W, Saudo E C, et al. Inorg. Chem. , 2009, 48: 2482-2489
  (b)Escuer A, Vicente R, Mautner F A, et al. Inorg. Chem. , 1997, 36: 1233-1236
  (c)Zhang X M, Wang Y Q, Song Y, et al. Inorg. Chem. , 2011, 50: 7284-7294
32. [32]
  (a)Kostakis G E, Mondal K C, Abbas G, et al. CrystEngComm, 2009, 11: 2084-2088
  (b)Su Q J, Li S H, Wang L, et al. Inorg. Chem. Commun. , 2010, 13: 1210-1212
  (c)Sengupta O, Gole B, Mukherjee S, et al. Dalton Trans. , 2010, 39: 7451-7465
  (d)Li X B, Ma Y, Zhang X M, et al. Eur. J. Inorg. Chem. , 2011, 30: 4738-4744
  (e)Mukherjee S, Patil Y P, Mukherjee P S. Dalton Trans. , 2012, 41: 54-64
  (f)Mukherjee S, Mukherjee P S. Dalton Trans. , 2013, 42: 4019-4030
33. [33]
  (a)Zeng Y F, Liu F C, Zhao J P, et al. Chem. Commun. , 2006, 21: 2227-2229
  (b)Gu Z G, Song Y, Zuo J L, et al. Inorg. Chem. , 2007, 46: 9522-9524
  (c)Liu F C, Zeng Y F, Zhao J P, et al. Inorg. Chem. , 2007, 46: 7698-7700
  (d)Han Y F, Wang T W, Song Y, et al. Inorg. Chem. Commun. , 2008, 11: 207-209
34. [34]
  (a)Sun W W, Qian X B, Tian C Y, et al. Inorg. Chim. Acta, 2009, 362: 2744-2748
  (b)He Z, Wang Z M, Gao S, et al. Inorg. Chem. , 2006, 45: 6694-6705
  (c)Zeng Y F, Zhao J P, Hu B W, et al. Chem. -Eur. J. , 2007, 13: 9924-9930
  (d)Liu X Y, Chen S P, Grancha T, et al. Dalton Trans. , 2014, 43: 15359-15366
  (e)Chakrabarty P P, Giri S, Schollmeyer D, et al. Polyhedron, 2015, 89: 49-54
  (f)Setifi Z, Ghazzali M, Glidewell C, et al. Polyhedron, 2016, 117: 244-248
  (g)Liu X Y, Li F F, Ma X H, et al. Dalton Trans. , 2017, 46: 1207-1217
1. [1]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
2. [2]
  Dan-Ying Xing , Xiao-Dan Zhao , Chuan-Shu He , Bo Lai . Kinetic study and DFT calculation on the tetracycline abatement by peracetic acid. Chinese Chemical Letters, 2024, 35(9): 109436-. doi: 10.1016/j.cclet.2023.109436
3. [3]
  Haibin Yang , Duowen Ma , Yang Li , Qinghe Zhao , Feng Pan , Shisheng Zheng , Zirui Lou . Mo doped Ru-based cluster to promote alkaline hydrogen evolution with ultra-low Ru loading. Chinese Journal of Structural Chemistry, 2023, 42(11): 100031-100031. doi: 10.1016/j.cjsc.2023.100031
4. [4]
  Jing Wang , Zhongliao Wang , Jinfeng Zhang , Kai Dai . Single-layer crystalline triazine-based organic framework photocatalysts with different linking groups for H2O2 production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100202-100202. doi: 10.1016/j.cjsc.2023.100202
5. [5]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
6. [6]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
7. [7]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
8. [8]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
9. [9]
  Linshan Peng , Qihang Peng , Tianxiang Jin , Zhirong Liu , Yong Qian . Highly efficient capture of thorium ion by citric acid-modified chitosan gels from aqueous solution. Chinese Chemical Letters, 2024, 35(5): 108891-. doi: 10.1016/j.cclet.2023.108891
10. [10]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
11. [11]
  Lian Sun , Honglei Wang , Ming Ma , Tingting Cao , Leilei Zhang , Xingui Zhou . Shape and composition evolution of Pt and Pt₃M nanocrystals under HCl chemical etching. Chinese Chemical Letters, 2024, 35(9): 109188-. doi: 10.1016/j.cclet.2023.109188
12. [12]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
13. [13]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
14. [14]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
15. [15]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
16. [16]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
19. [19]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
20. [20]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(509)
HTML views(37)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142