Citation: HUANG Ji-Chun, MEI Lin, MA Zheng, ZHU Xian-Yu, QUAN Jing-Bin, LI De-Cheng. Electrochemical Performance of Li-rich Layered Cathode Material 0.6Li[Li_1/3Mn_2/3]O₂·0.4LiNi_5/12Mn_5/12Co_1/6O₂ by ZrO₂ Coating[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(7): 1236-1242. doi: 10.11862/CJIC.2017.173 shu

Electrochemical Performance of Li-rich Layered Cathode Material 0.6Li[Li_1/3Mn_2/3]O₂·0.4LiNi_5/12Mn_5/12Co_1/6O₂ by ZrO₂ Coating

College of Physics, Optoelectronics and Energy & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215006, China

Received Date: 18 February 2017
Revised Date: 21 May 2017

Figures(9)

Lithium-rich layered oxide materials 0.6Li[Li_1/3Mn_2/3]O₂·0.4LiNi_5/12Mn_5/12Co_1/6O₂(named as LNMCO) have been prepared by spray-drying method and followed by high temperature annealed and surface coated with ZrO₂.The TEM results show that the ZrO₂ layer with nano size particles is located on the surface of the particles.The initial coulombic efficiencies and discharge capacities of the 0.6Li[Li_1/3Mn_2/3]O₂·0.4LiNi_5/12Mn_5/12Co_1/6O₂ lithium-rich layered oxide material are largely improved by ZrO₂ coating, and the value is 87.2%, 279.3 mAh·g^-1, compared to 75.1%, 224.1 mAh·g^-1, respectively, for the bare sample at the room temperature and at a current density of 20 mA·g^-1 in the voltage range of 2.0 to 4.8 V when the content of ZrO₂ is 1.5%.After 100 cycles, the 1.5% ZrO_2^-coated sample shows a high discharge capacity of 248.3 mAh·g^-1 with a capacity retention of 88.9%, while the bare LNMCO presents a lower discharge capacity of 195.9 mAh·g^-1 with a capacity retention of 87.4%.
- lithium-ion batteries,
- cathode material,
- lithium-rich layered oxide cathode,
- Zirconium oxide coating
1. [1]
  Islam M S, Fisher C A J. Chem. Soc. Rev., 2014, 43:85-204 doi: 10.1039/C3CS60210A
2. [2]
  Zhu J, Zhang G H, Yu X Z, et al. Nano Energy, 2014, 3:80-87 doi: 10.1016/j.nanoen.2013.10.009
3. [3]
  Zhang Q F, Xu C M, Lu B A. Electrochim. Acta, 2014, 132:180-185 doi: 10.1016/j.electacta.2014.03.111
4. [4]
  Zhang Q Y, Zhang C L, Li B, et al. Electrochim. Acta, 2013, 107:139-146 doi: 10.1016/j.electacta.2013.05.151
5. [5]
  Jeffrey W F. J. Power Sources, 2010, 195:939-954 doi: 10.1016/j.jpowsour.2009.09.001
6. [6]
  CHEN Bo-Tao. Chinese J. Inorg. Chem., 2010, 26(2):190-196
7. [7]
  Hu S K, Cheng G H, Cheng M Y, et al. J. Power Sources, 2009, 188:564-569 doi: 10.1016/j.jpowsour.2008.11.113
8. [8]
  Lim S, Cho J. Electrochem. Commun., 2008, 10:1478-1481 doi: 10.1016/j.elecom.2008.07.028
9. [9]
  Gong C, Xue Z G, Wen S, et al. J. Power Sources, 2016, 318:93-112 doi: 10.1016/j.jpowsour.2016.04.008
10. [10]
  Bommel A V, Krause L J, Dahn J R. J. Electrochem Soc., 2011, 158:A731-A735 doi: 10.1149/1.3579418
11. [11]
  Shojan J, Chitturi V R, Sole J, et al. J. Power Sources, 2015, 274:440-450 doi: 10.1016/j.jpowsour.2014.10.032
12. [12]
  Zheng J M, Xu P H, Gu M, et al. Chem. Mater., 2015, 27:1381-1390 doi: 10.1021/cm5045978
13. [13]
  Ma Z, Huang J C, Quan J B, et al. RSC Adv., 2016, 6:20522-20531 doi: 10.1039/C5RA22330J
14. [14]
  Huang Z, Li X, Liang Y, et al. Solid State Ionics, 2015, 282:88-94 doi: 10.1016/j.ssi.2015.10.005
15. [15]
  Liu X Y, Huang T, Yu A. Electrochim. Acta, 2014, 133:555-563 doi: 10.1016/j.electacta.2014.04.085
16. [16]
  Zang Y, Ding C X, Wang C, et al. Electrochim. Acta, 2015, 168:234-239 doi: 10.1016/j.electacta.2015.03.223
17. [17]
  Yu H J, Zhou H S. J. Mater. Chem., 2012, 22:15507-15510 doi: 10.1039/c2jm33484d
18. [18]
  Kiziltas-Yavuz N, Bhaskar A, Dixon D. J. Power Sources, 2014, 267:533-541 doi: 10.1016/j.jpowsour.2014.05.110
19. [19]
  Kang S H, Amine K. J. Power Sources, 2005, 146:654-657 doi: 10.1016/j.jpowsour.2005.03.152
20. [20]
  Jin X, Xu Q J, Liu M, et al. Electrochim. Acta, 2014, 136:19-26 doi: 10.1016/j.electacta.2014.05.043
21. [21]
  Akita T, Tabuchi M, Nabeshima Y, et al. J. Power Sources, 2014, 254:39-47 doi: 10.1016/j.jpowsour.2013.12.086
22. [22]
  Kang S F, Qin H F, Fang Y, et al. Electrochim. Acta, 2014, 144:22-30 doi: 10.1016/j.electacta.2014.06.155
23. [23]
  Shi S J, Tu J P, Tang Y Y, et al. Electrochim. Acta, 2013, 88:671-679 doi: 10.1016/j.electacta.2012.10.111
24. [24]
  Liu X Y, Huang T, Yu A. Electrochim. Acta, 2015, 163:82-92 doi: 10.1016/j.electacta.2015.02.155
25. [25]
  Thackeray M M, Kang S H, Johnson C S, et al. J. Mater. Chem., 2007, 17:3112 doi: 10.1039/b702425h
26. [26]
  Liu Z, Yu A, Lee J Y. J. Power Sources, 1999, 81-82:416-419 doi: 10.1016/S0378-7753(99)00221-9
27. [27]
  Ohzuku T, Nagayama M, Tsuji K, et al. J. Mater. Chem., 2011, 21:10179-10188 doi: 10.1039/c0jm04325g
28. [28]
  He W, Qian J, Cao Y, et al. RSC Adv., 2012, 2:3423-3429 doi: 10.1039/c2ra20122d
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Electrochemical Performance of Li-rich Layered Cathode Material 0.6Li[Li1/3Mn2/3]O2·0.4LiNi5/12Mn5/12Co1/6O2 by ZrO2 Coating

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通讯作者: 陈斌, bchen63@163.com

Electrochemical Performance of Li-rich Layered Cathode Material 0.6Li[Li_1/3Mn_2/3]O₂·0.4LiNi_5/12Mn_5/12Co_1/6O₂ by ZrO₂ Coating