Citation: XIONG Jun, LÜ Shao-Fang, PENG Jun-Jun, LI Ming, LI Wei, YANG Shui-Bin. Two Inorganic-Organic Hybrid Crystals Based on Polyoxometallates and Supramolecular Cation:Syntheses and Crystal Structures[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1649-1655. doi: 10.11862/CJIC.2017.171 shu

Two Inorganic-Organic Hybrid Crystals Based on Polyoxometallates and Supramolecular Cation:Syntheses and Crystal Structures

XIONG Jun ^1,, ,
LÜ Shao-Fang ¹ ,
PENG Jun-Jun ¹ ,
LI Ming ¹ ,
LI Wei ¹ ,
YANG Shui-Bin ^2,,

1.
College of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan 430200, China
2.
College of Chemical Engineering, Huanggang Normal University, Huanggang, Hubei 438000, China

Corresponding author: XIONG Jun, jxiong@wtu.edu.cn; 2416975012@qq.com YANG Shui-Bin, 2416975012@qq.com
Received Date: 31 March 2017
Revised Date: 17 May 2017

Figures(5)

Two new inorganic-organic hybrids[(3-F-4-MeAnis)(DB[18]crown-6)]₂[Mo₆O₁₉]·2CH₃CN (1) and[(2-F-4-MeAnis)([18]crown-6)]₂[SMo₁₂O₄₀]·2CH₃CN (2) (3-F-4-MeAnis=3-fluoro-4-methylanilinium, DB[18]crown-6=dibenzo[18]crown-6, 2-F-4-MeAnis=2-fluoro-4-methylanilinium) have been synthesized and characterized by infrared spectrum (IR), elemental analysis (EA), thermosgravimetric analysis (TGA) and X-ray diffraction. Compounds 1 and 2 are constructed through noncovalent bonding interaction and the polyoxometalates (POMs) and supramolecular cation arrange alternately. Supramolecular cation forms through the N-H…O hydrogen bonding interaction between the nitrogen atom of anilinium and oxygen atoms of crown ether derivatives. In the crystals of 1 and 2, each polyoxoanion is surrounded by six supramolecular cations and forms hexagonal arrangement viewed along the a axis. Crystalline structure and TGA indicated that phenyl rings in DB[18]crown-6 plays an important role in maintaining the stability of compound 1.CCDC:1540103,1;1540105,2.
- inorganic-organic hybrids,
- supramolecular self-assembled,
- polyoxometallates,
- crown ether,
- supramolecular cation
1. [1]
  Kitagawa S, Kitaura R, Noro S. Angew. Chem. Int. Ed., 2004, 43:2334-2375 doi: 10.1002/(ISSN)1521-3773
2. [2]
  Perry Ⅳ J, Perman J, Zaworotko M. Chem. Soc. Rev., 2009, 38:1400-1417 doi: 10.1039/b807086p
3. [3]
  Zhao H, Li D, Ren X, et al. J. Am. Chem. Soc., 2010, 132(1):18-19 doi: 10.1021/ja907562m
4. [4]
  GU Wen-Jun, GU Jin-Zhong. Chinese J. Inorg. Chem., 2017, 33(2):227-236 doi: 10.11862/CJIC.2017.035
5. [5]
  Akutagawa T, Takeda S, Nakamura T, et al. J. Am. Chem. Soc., 2004, 126(1):18-19 doi: 10.1021/ja038951a
6. [6]
  Zhang Q, Wu F, Long L, et al. Angew. Chem. Int. Ed., 2013, 52:12602-12605 doi: 10.1002/anie.201306193
7. [7]
  Desiraju R. Acc. Chem. Res., 2002, 35:565-573 doi: 10.1021/ar010054t
8. [8]
  Hua Y, Flood H. Chem. Soc. Rev., 2010, 39:1262-1271 doi: 10.1039/b818033b
9. [9]
  Akutagawa T, Cronin L, Nakamura T, et al. Inorg Chem., 2011, 50:6711-6718 doi: 10.1021/ic200683e
10. [10]
  Du D, Su Z, Wang E, et al. Coord. Chem. Rev., 2013, 257:702-717 doi: 10.1016/j.ccr.2012.10.004
11. [11]
  Nie S, Hu H, Xue G, et al. J. Solid State Chem., 2010, 183:2957-2962 doi: 10.1016/j.jssc.2010.08.023
12. [12]
  Xiong J, Akutagawa T, Nakamura T. Cryst. Growth Des., 2016, 16:800-807 doi: 10.1021/acs.cgd.5b01388
13. [13]
  WANG Lei, GU Xiao-Min, NI Liang, et al. Chinese J. Inorg. Chem., 2016, 32(4):691-698 doi: 10.11862/CJIC.2016.054
14. [14]
  Vu T, Bond M, Wedd G, et al. Inorg. Chem., 2001, 40:65-72
15. [15]
  Coronado E, Gómez-García C. Chem. Rev., 1998, 98:273-296 doi: 10.1021/cr970471c
16. [16]
  Xu H, Li Z, Xue G, et al. Cryst. Growth Des., 2010, 10:1096-1103 doi: 10.1021/cg900777g
17. [17]
  Akutagawa T, Endo D, Nakamura T, et al. Coord. Chem. Rev., 2007, 251:2547-2561 doi: 10.1016/j.ccr.2007.08.015
18. [18]
  Akutagawa T, Noro S, Nakamura T, et al. Inorg. Chem., 2008, 47:5951-5962 doi: 10.1021/ic800271m
19. [19]
  Horie M, Suzaki Y, Osakada K. J. Am. Chem. Soc., 2004, 126(12):3684-3685 doi: 10.1021/ja039899l
20. [20]
  Langford S, Lau V. Aust. J. Chem., 2004, 57:29-32 doi: 10.1071/CH03275
21. [21]
  Nishihara S, Akutagawa T, Nakamura T, et al. Chem. Asian J., 2007, 2:1083-1090 doi: 10.1002/(ISSN)1861-471X
22. [22]
  Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
23. [23]
  Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
24. [24]
  Xiong J, Akutagawa T, Nakamura T, et al. CrystEngComm, 2015, 17: 856-861 doi: 10.1039/C4CE01988A
25. [25]
  Niu Y, Ren X, Xue G, et al. J. Organomet. Chem., 2010, 695:1863-1868 doi: 10.1016/j.jorganchem.2010.04.033
1. [1]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
2. [2]
  Xingwen Cheng , Haoran Ren , Jiangshan Luo . Boosting the self-trapped exciton emission in vacancy-ordered double perovskites via supramolecular assembly. Chinese Journal of Structural Chemistry, 2024, 43(6): 100306-100306. doi: 10.1016/j.cjsc.2024.100306
3. [3]
  Yihao Zhang , Yang Jiao , Xianchao Jia , Qiaojia Guo , Chunying Duan . Highly effective self-assembled porphyrin MOCs nanomaterials for enhanced photodynamic therapy in tumor. Chinese Chemical Letters, 2024, 35(5): 108748-. doi: 10.1016/j.cclet.2023.108748
4. [4]
  Pu Zhang , Xiang Mao , Xuehua Dong , Ling Huang , Liling Cao , Daojiang Gao , Guohong Zou . Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions. Chinese Chemical Letters, 2024, 35(9): 109235-. doi: 10.1016/j.cclet.2023.109235
5. [5]
  Conghui Wang , Lei Xu , Zhenhua Jia , Teck-Peng Loh . Recent applications of macrocycles in supramolecular catalysis. Chinese Chemical Letters, 2024, 35(4): 109075-. doi: 10.1016/j.cclet.2023.109075
6. [6]
  Luyu Zhang , Zirong Dong , Shuai Yu , Guangyue Li , Weiwen Kong , Wenjuan Liu , Haisheng He , Yi Lu , Wei Wu , Jianping Qi . Ionic liquid-based in situ dynamically self-assembled cationic lipid nanocomplexes (CLNs) for enhanced intranasal siRNA delivery. Chinese Chemical Letters, 2024, 35(7): 109101-. doi: 10.1016/j.cclet.2023.109101
7. [7]
  Rui Wang , Yang Liang , Julius Rebek Jr. , Yang Yu . Stabilization and detection of labile reaction intermediates in supramolecular containers. Chinese Chemical Letters, 2024, 35(6): 109228-. doi: 10.1016/j.cclet.2023.109228
8. [8]
  Wenlong Li , Feishi Shan , Qingdong Bao , Qinghua Li , Hua Gao , Leyong Wang . Supramolecular assembly nanoparticle for trans-epithelial treatment of keratoconus. Chinese Chemical Letters, 2024, 35(10): 110060-. doi: 10.1016/j.cclet.2024.110060
9. [9]
  Hong-Jin Liao , Zhu Zhuo , Qing Li , Yoshihito Shiota , Jonathan P. Hill , Katsuhiko Ariga , Zi-Xiu Lu , Lu-Yao Liu , Zi-Ang Nan , Wei Wang , You-Gui Huang . A new class of crystalline X-ray induced photochromic materials assembled from anion-directed folding of a flexible cation. Chinese Chemical Letters, 2024, 35(8): 109052-. doi: 10.1016/j.cclet.2023.109052
10. [10]
  Guoxing Liu , Yixin Li , Changming Tian , Yongmei Xiao , Lijie Liu , Zhanqi Cao , Song Jiang , Xin Zheng , Caoyuan Niu , Yun-Lai Ren , Liangru Yang , Xianfu Zheng , Yong Chen . Highly reversible photomodulated hydrosoluble stiff-stilbene supramolecular luminophor induced by cucurbituril. Chinese Chemical Letters, 2024, 35(8): 109403-. doi: 10.1016/j.cclet.2023.109403
11. [11]
  Gang Lang , Jing Feng , Bo Feng , Junlan Hu , Zhiling Ran , Zhiting Zhou , Zhenju Jiang , Yunxiang He , Junling Guo . Supramolecular phenolic network-engineered C–CeO₂ nanofibers for simultaneous determination of isoniazid and hydrazine in biological fluids. Chinese Chemical Letters, 2024, 35(6): 109113-. doi: 10.1016/j.cclet.2023.109113
12. [12]
  Lei Zhou , Youjun Zhou , Lizhen Fang , Yiqiao Bai , Yujia Meng , Liang Li , Jie Yang , Yong Yao . Pillar[5]arene based artificial light-harvesting supramolecular polymer for efficient and recyclable photocatalytic applications. Chinese Chemical Letters, 2024, 35(9): 109509-. doi: 10.1016/j.cclet.2024.109509
13. [13]
  Bingbing Shi , Yuchun Wang , Yi Zhou , Xing-Xing Zhao , Yizhou Li , Nuoqian Yan , Wen-Juan Qu , Qi Lin , Tai-Bao Wei . A supramolecular oligo[2]rotaxane constructed by orthogonal platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions. Chinese Chemical Letters, 2024, 35(10): 109540-. doi: 10.1016/j.cclet.2024.109540
14. [14]
  Ying Gao , Rong Zhou , Qiwen Wang , Shaolong Qi , Yuanyuan Lv , Shuang Liu , Jie Shen , Guocan Yu . Natural killer cell membrane doped supramolecular nanoplatform with immuno-modulatory functions for immuno-enhanced tumor phototherapy. Chinese Chemical Letters, 2024, 35(10): 109521-. doi: 10.1016/j.cclet.2024.109521
15. [15]
  Caixia Li , Yi Qiu , Yufeng Zhao , Wuliang Feng . Self assembled electron blocking and lithiophilic interface towards dendrite-free solid-state lithium battery. Chinese Chemical Letters, 2024, 35(4): 108846-. doi: 10.1016/j.cclet.2023.108846
16. [16]
  Yuan Dong , Mutian Ma , Zhenyang Jiao , Sheng Han , Likun Xiong , Zhao Deng , Yang Peng . Effect of electrolyte cation-mediated mechanism on electrocatalytic carbon dioxide reduction. Chinese Chemical Letters, 2024, 35(7): 109049-. doi: 10.1016/j.cclet.2023.109049
17. [17]
  Xiao Zhu , Yanbing Mo , Jiawei Chen , Gaopan Liu , Yonggang Wang , Xiaoli Dong . A weakly-solvated ether-based electrolyte for fast-charging graphite anode. Chinese Chemical Letters, 2024, 35(8): 109146-. doi: 10.1016/j.cclet.2023.109146
18. [18]
  Kangrong Yan , Ziqiu Shen , Yanchun Huang , Benfang Niu , Hongzheng Chen , Chang-Zhi Li . Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells. Chinese Chemical Letters, 2024, 35(6): 109516-. doi: 10.1016/j.cclet.2024.109516
19. [19]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
20. [20]
  Zhenyang Lin . A classification scheme for inorganic cluster compounds based on their electronic structures and bonding characteristics. Chinese Journal of Structural Chemistry, 2024, 43(5): 100254-100254. doi: 10.1016/j.cjsc.2024.100254

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(555)
HTML views(81)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142