Citation: YAN Juan-Zhi, LU Li-Ping. Syntheses, Crystal Structures and Luminescence Properties of Two Cu₄I₄ Coordination Polymers Based on 3, 5-Dialkyl-1, 2, 4-triazole[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(9): 1697-1704. doi: 10.11862/CJIC.2017.165 shu

Syntheses, Crystal Structures and Luminescence Properties of Two Cu₄I₄ Coordination Polymers Based on 3, 5-Dialkyl-1, 2, 4-triazole

YAN Juan-Zhi ^1,2 ,
LU Li-Ping ^1,,

1.
Institute of Molecular Science, Shanxi University, Taiyuan 030006, China
2.
Taiyuan University, Taiyuan 030032, China

Corresponding author: LU Li-Ping, luliping@sxu.edu.cn
Received Date: 8 April 2017
Revised Date: 15 May 2017

Figures(7)

Two Cu₄I₄ coordination polymers, {[Cu₂(aadmtrz)I₂]·CH₃CN}_n (1) and[Cu₂(dptrz)I]_n (2) (aadmtrz=4-((1-aminoethylidene)-amino)-3, 5-dimethyl-1, 2, 4-triazole, dptrz=3, 5-dipropyl-1, 2, 4-triazole), have been synthesized by the solvothermal reactions of CuI and 3, 5-dialkyl-4-amino-1, 2, 4-triazole ligands in mixed H₂O/MeCN solution and characterized using elemental analysis, IR, PXRD and single-crystal X-ray diffraction. The structures of the Cu₄I₄ units in the polymers are different. The Cu₄I₄ cluster in complex 1 is an inorganic 8-membered ring with a chair-chair conformation, while the one in complex 2 is a distorted cube. Complex 1 exhibits 2D 4, 4-connected rhombic-grid. Complex 2 is a (3, 4)-connected framework with 19.5% porosity. In addition, the luminescent properties of the complexes in the solid state were also investigated.CCDC:1437794,1;1437795,2.
- copper (I) iodide,
- 1, 2, 4-triazole,
- crystal structures,
- luminescence
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Syntheses, Crystal Structures and Luminescence Properties of Two Cu₄I₄ Coordination Polymers Based on 3, 5-Dialkyl-1, 2, 4-triazole