Citation: LIU Wei, LI Xia, LI Yin-Feng, ZHAO Jin-An, WU Ben-Lai, SONG Mao-Ping. Synthesis, Crystal Structure and Electrochemical Metal Cation Recognition Investigation of Fe (C₅H₄-CH₂-Trp-OMe)₂[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(7): 1243-1248. doi: 10.11862/CJIC.2017.127 shu

Synthesis, Crystal Structure and Electrochemical Metal Cation Recognition Investigation of Fe (C₅H₄-CH₂-Trp-OMe)₂

LIU Wei ¹ ,
LI Xia ^1,, ,
LI Yin-Feng ¹ ,
ZHAO Jin-An ¹ ,
WU Ben-Lai ² ,
SONG Mao-Ping ²

1.
College of Materials and Chemical Engineering, Henan University of Urban Construction, Pingdingshan, Henan 467044, China
2.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: LI Xia, lixia@hncj.edu.cn
Received Date: 10 March 2017
Revised Date: 19 April 2017

Figures(5)

A simple and efficient two-steps one-pot synthetic methodology for the preparation of Fe (C₅H₄-CH₂-Trp-OMe)₂(FcL) is described, and FcL was fully characterized by NMR spectroscopic techniques, mass spectrometry (HRMS) and IR.The crystal structure of FcL was determined by X-ray single crystal structure analysis.The cyclic voltammetric behavior of FcL showed one pair of well-defined and stable redox waves in potential range of 0.0~0.9 V at GC electrode, which attributed to the Fc/Fc⁺ redox process.Electrochemical investigations of FcL have demonstrated that addition of Zn²⁺ and Cu²⁺ results in large shifts of respective Fc/Fc⁺ redox couple to more positive potentials, 342 and 335 mV, respectively, and this suggests that FcL has good ability in recognizing of the vital Zn²⁺ and Cu²⁺.
- ferrocene,
- bioorganometalic chemistry,
- electrochemistry,
- metal cation sensing
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Synthesis, Crystal Structure and Electrochemical Metal Cation Recognition Investigation of Fe (C₅H₄-CH₂-Trp-OMe)₂