Citation: YANG Hong, GUO Li-Jun. Syntheses, Characterization and Radical Scavenging Activity of Two Copper(Ⅱ) Complexes Containing Pyrazoles[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 1059-1064. doi: 10.11862/CJIC.2017.125 shu

Syntheses, Characterization and Radical Scavenging Activity of Two Copper(Ⅱ) Complexes Containing Pyrazoles

YANG Hong ^*,, ,
GUO Li-Jun

Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China

Corresponding author: YANG Hong, hmily820805@163.com
Received Date: 13 January 2017
Revised Date: 18 April 2017

Figures(4)

By using a tripodal ligand tris(3, 5-bimethyl-pyrazolylmethyl)amine (TMPzA) and a bridged ligand thiophenedicarboxylic acid (H₂TPDC), two binuclear copper(Ⅱ) complexes have been synthesized and characterized. It has been found that TMPzA lost an arm and coordinated to copper with di(3, 5-bimethyl-pyrazolylmethyl)amine(DMPzA) in complex [Cu₂(DMPzA)₂(TPDC)₂]ClO₄ (1). The structure presented a microcycle with the Cu(1)…Cu(1A) distance of 0.786 84 nm. The complex [Cu₂(TMPzA)₂(TPDC)(H₂O)₂](ClO₄)₂ (2) is a binuclear structure and with the TMPzA completely. The investigation in Feton system shows that complex 1 has better hydroxyl radicals scavenging property than that of complex 2. CCDC: 1411232, 1; 1411233, 2.
- binuclear copper(Ⅱ) complexes,
- Feton system,
- hydroxyl radicals scavenging
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沈阳化工大学材料科学与工程学院沈阳 110142