Citation: MA Zhi-Hong, LI Zhan-Wei, QIN Mei, LI Su-Zhen, HAN Zhan-Gang, ZHENG Xue-Zhong, LIN Jin. Syntheses, Crystal Structures and Catalytic Activity of Rhenium Carbonyl Complexes Containing Aryl-Substituted Tetramethylcyclopentadienyl Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 1074-1080. doi: 10.11862/CJIC.2017.117 shu

Syntheses, Crystal Structures and Catalytic Activity of Rhenium Carbonyl Complexes Containing Aryl-Substituted Tetramethylcyclopentadienyl Ligands

MA Zhi-Hong ^1,2 ,
LI Zhan-Wei ¹ ,
QIN Mei ^1,*,, ,
LI Su-Zhen ³ ,
HAN Zhan-Gang ¹ ,
ZHENG Xue-Zhong ¹ ,
LIN Jin ^1,*,,

1.
College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China
2.
College of Basic Medicine, Hebei Medical University, Shijiazhuang 050017, China
3.
Hebei College of Industry and Technology, Shijiazhuang 050091, China

Corresponding author: QIN Mei, qinmei2005@126.com LIN Jin, linjin64@126.com
Received Date: 10 February 2017
Revised Date: 22 March 2017

Figures(3)

Cyclopentadienes C₅HMe₄Ar (Ar=Ph, 4-CH₃Ph, 4-OCH₃Ph, 4-ClPh, 4-BrPh) reacted with Re₂(CO)₁₀ in refluxing xylene to give new aryl-substituted tetramethylcyclopentadienyl mononuclear metal carbonyl complexes [(η⁵-C₅Me₄Ar)Re(CO)₃] (Ar=Ph (1), 4-CH₃Ph (2), 4-OCH₃Ph (3), 4-ClPh (4), 4-BrPh (5)), respectively. The five new complexes were characterized by elemental analysis, IR, ¹H NMR and ¹³C NMR spectroscopy. The crystal structures of complexes 1~5 were determined by X-ray crystal diffraction analysis. All five of these complexes have significant catalytic activity in Friedel-Crafts reactions of aromatic compounds with alkylation reagents. CCDC: 1463217, 1; 1506704, 2; 1484954, 3; 1484955, 4; 1506705, 5.
- synthesis,
- mononuclear rhenium carbonyl complex,
- Friedel-Crafts alkylation reaction,
- catalysis
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