Citation: YIN Xiu-Ju, LIAO Bei-Ling, WU Han-Min, PANG Yi-Lin, LI Shi-Xiong. Syntheses, Structures and Magnetic Analysis of Co(Ⅱ), Ni(Ⅲ) Coordination Polymers Based on Pyridine-2, 4, 6-tricarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 1043-1050. doi: 10.11862/CJIC.2017.116 shu

Syntheses, Structures and Magnetic Analysis of Co(Ⅱ), Ni(Ⅲ) Coordination Polymers Based on Pyridine-2, 4, 6-tricarboxylic Acid

1.
College of Chemistry and Biological Engineering, Hechi University, Yizhou, Guangxi 546300, China
2.
School of Environment and Energy, South China University of Technology, Guangzhou 510006, China

Corresponding author: LI Shi-Xiong, lsx1324@163.com
Received Date: 28 December 2016
Revised Date: 15 April 2017

Figures(4)

The title coordination polymers of {[M₃(pyta)₂(H₂O)₈]·4H₂O}_n(M=Co(1), Ni(2)) based on H₃pyta (H₃pyta=pyridine-2, 4, 6-tricarboxylic acid) had been synthesized under hydrothermal synthesis conditions with same temperature, molar ratio and solvent, but different metal salts. X-ray diffraction analysis shows that these two polymers are hetero-isomorphic and belong to the monoclinic system, P2₁/c space group. The magnetic investigation shows that polymers 1 and 2 exhibit a ferromagnetic coupling between M(Ⅱ) ions. CCDC: 1524314, 1; 1000880, 2.
- coordination polymer,
- pyridine-2, 4, 6-tricarboxylic acid,
- magnetic
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沈阳化工大学材料科学与工程学院沈阳 110142