Citation: HOU Bu-Wei, LI Kai. Cu(Ⅰ)/Cu(Ⅱ) Complexes Based on Tetrazole Derivative: Degradation of Organic Dye under Visible Light Irradiation[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(6): 1007-1014. doi: 10.11862/CJIC.2017.110 shu

Cu(Ⅰ)/Cu(Ⅱ) Complexes Based on Tetrazole Derivative: Degradation of Organic Dye under Visible Light Irradiation

HOU Bu-Wei ¹ ,
LI Kai ^2,*,,

1.
Zhengzhou Foreign Language School, Zhengzhou 450001, China
2.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: LI Kai, likai@zzu.edu.cn
Received Date: 6 January 2017
Revised Date: 16 February 2017

Figures(5)

Two Cu(Ⅰ)/Cu(Ⅱ) complexes, formulated as [Cu₂(TTB)_0.5(PPh₃)]_n(1) and {[Cu(TTB)_0.5(H₂O)₂]·H₂O}_n(2) (H₄TTB=1, 2, 4, 5-tetra-(2H-tetrazole-5-yl)-benzene, PPh₃=triphenyl phosphine) have been obtained by solvothermal/hydrothermal reactions for the exploration of efficient photocatalytic degradation of organic dye pollutants. The two complexes were characterized by IR, TG, PXRD and X-ray single crystal determination. Complex 1 exhibits a novel 2D structure with 12 coordination atoms in a TTB^4-, and complex 2 features an irregular 1D double chain structure. Moreover, under visible light, both complexes 1 and 2 display higher activation for the photocatalytic decomposition of rhodamine B (RhB) and methylene blue (MB). The degradation efficiency can reach 88% (RhB) and 93% (MB) for 1, and 78% (RhB) and 93% (MB) for 2. Clearly, the photocatalytic degradation efficiency of complex 1 is similar to that of complex 2.
- Cu(Ⅰ)/Cu(Ⅱ) complexes,
- degradation of organic dye,
- visible light irradiation
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沈阳化工大学材料科学与工程学院沈阳 110142