Crystal Structures and DNA Interaction Properties of Ni (Ⅱ) and Cd (Ⅱ) Complexes with a Semicarbazone Ligand Bearing Pyrazine Unit
- Corresponding author: ZHAO Xiao-Lei, zhaoxiaolei@hpu.edu.cn WU Wei-Na, wuwn08@hpu.edu.cn
Citation: MAO Pan-Dong, ZHAO Xiao-Lei, SHAO Zhi-Peng, LI Min, WU Wei-Na, WANG Yuan. Crystal Structures and DNA Interaction Properties of Ni (Ⅱ) and Cd (Ⅱ) Complexes with a Semicarbazone Ligand Bearing Pyrazine Unit[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(5): 890-896. doi: 10.11862/CJIC.2017.109
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H atoms are omitted for clarity in (a) and (b); Disordered water molecules are omitted in (c) and (d); Symmetry codes: ⅰ-x+2, -y, -z; ⅱ 1-x, 1-y, 1-z
Arrow shows the fluorescence intensities change of EB-DNA system upon increasing tested complex concentration; Inset: plot of I0/I versus r